Kinetics of the Gas-Phase Reactions of OH Radicals, NO3 Radicals and O3 with Three C7-Carbonyls Formed From The Atmospheric Reactions of Myrcene, Ocimene and Terpinolene     

Jillian Baker  Janet Arey  Roger Atkinson 《Journal of Atmospheric Chemistry》2004,48(3):241-260

Rate constants for the gas-phase reactions of OH radicals, NO₃ radicals and O₃ with the C₇-carbonyl compounds 4-methylenehex-5-enal [CH₂=CHC(=CH₂)CH₂CH₂CHO], (3Z)- and (3E)-4-methylhexa-3,5-dienal [CH₂=CHC(CH₃)=CHCH₂CHO] and 4-methylcyclohex-3-en-1-one, which are products of the atmospheric degradations of myrcene, Z- and E-ocimene and terpinolene, respectively, have been measured at 296 ± 2 K and atmospheric pressure of air using relative rate methods. The rate constants obtained (in cm³ molecule^–1 s^–1 units) were: for 4-methylenehex-5-enal, (1.55 ± 0.15) × 10^–10, (4.75 ± 0.35) × 10^–13 and (1.46 ± 0.12) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; for (3Z)-4-methylhexa-3,5-dienal: (1.61 ± 0.35) × 10^–10, (2.17 ± 0.30) × 10^–12, and (4.13 ± 0.81) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; for (3E)-4-methylhexa-3,5-dienal: (2.52 ± 0.65) × 10^–10, (1.75 ± 0.27) × 10^–12, and (5.36 ± 0.28) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; and for 4-methylcyclohex-3-en-1-one: (1.10 ± 0.19) × 10^–10, (1.81 ± 0.35) × 10^–12, and (6.98 ± 0.40) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively. These carbonyl compounds are all reactive in the troposphere, with daytime reaction with the OH radical and nighttime reaction with the NO₃ radical being predicted to dominate as loss processes and with estimated lifetimes of about an hour or less.  相似文献   

Composition and Assemblage Characteristics of Magnetic Minerals in Layer S_(5-1) of Xifeng and Duanjiapo Sections     

贾蓉芬  彭先芝  周正  刘德汉  王冠鑫  王德强 《中国地球化学学报》2004,23(3)

Magneticmineralsintheloess paleosolseriesaccountforabout 1 % -2 %ofthetotal (LiuTungshengandZhangZhonghu ,1 962 ) .Duetotheiraerolianorigin ,themagneticmineralsarecomplicatedincomposition ,largeingrainsizerange ,andsignificantlydifferentincrystallinity .Asaresult,researchonthesemagneticmineralswouldbesetwithalotofdifficulties.Previousre searchersemployedopticalmicroscopic ,X raydiffractionandM ssbauerspectrometrictechniquestostudythemagneticmineralsintheloess paleosolseries,andchieflyontheb…  相似文献   

应用GMS5多通道云图估计降水技术的研究     

杨引明  姚祖庆 《气象》2004,30(11):8-13

对近两年来5～8月中国东部地区120多个测站雨量观测资料和对应4400多幅GMS-5四个通道云图的研究发现：红外亮温的时间、空间变率、红外和水汽通道亮温差等云图衍生资料对消除卷云，弥补夜间缺少可见光云图的不足起到明显作用。从而，应用双判据双重MOS多元回归法建立四通道云图因子、衍生因子与降水量之间的回归方程，进行6小时分级降水估计。为了进一步消除厚卷云和特殊地形的影响，提出使用逐日实时资料自动建立多元回归方程估计降水量，从而对双判据双重MOS多元回归法估计结果进行校正。上海中心气象台的业务使用表明，总体估计的准确率达70％左右。  相似文献   

98.7湖北特大暴雨的天气分析与降水模拟   总被引：10，自引：4，他引：10       下载免费PDF全文

齐艳军  程明虎  仪清菊 《气象》2004,30(3):12-16

1998年7月20～23日，湖北省南部发生了一次持续性特大暴雨过程，采用双向嵌套的非静力中尺度数值模式(MM5)对这次强暴雨过程进行初步模拟试验。结果表明，粗、细网格均能较好地模拟出雨带的走向和变动以及武汉地区的暴雨中心，尤其是嵌套域(细网格)模拟的降水强度比粗网格有明显改进，和实际观测结果更接近；另外，对引发这次特大暴雨的对流层低层的中尺度系统也能够很好地模拟出来。  相似文献   

2-[2-(6-氯苯并噻唑)偶氮]-5-二乙氨基苯甲酸与镍的显色反应     

樊学忠  张国防  范红杰 《岩矿测试》2004,23(1):40-43

研究了2-[2-(6-氯苯并噻唑)偶氮]-5-二乙氨基苯甲酸(6-Cl-BTAEB)与Ni2+的显色反应。结果表明:在pH4.5～7.6的HAc-NaAc缓冲溶液中及十二烷基硫酸钠存在下,试剂与Ni2+形成稳定的蓝紫色配合物,组成为n(Ni2+)∶n(6-Cl-BTAEB)=1∶2,最大吸收波长650nm,表观摩尔吸光系数为1.59×105L·mol-1·cm-1,Ni2+浓度在0～400μg/L内符合比尔定律。用铝合金和合金钢中的微量镍验证该分析方法,所得结果与推荐值相符,6次测定的RSD<2%。  相似文献   

The analysis of SPOT-5 characteristics on land cover Classification   总被引：1，自引：0，他引：1  

徐开明 《测绘科学》2004,29(Z1):108-116

<正>KnowledgeaboutlandcoverandlandusehasbecomeincreasinglyimportantastheNationplanstoovercometheproblemsofuncontrolleddevelopment,deterioratingenvironmentalquality,lossofprimeagriculturallandsetc.Landuseandlandcoverdataareneededintheanalysisofenvironmentalprocessesandproblemstoknowiflivingconditionsandstandardsaretobeimprovedormaintainedatcurrentlevels.  相似文献   

Upwelling plumes, superswells and true polar wander   总被引：1，自引：0，他引：1  

Marianne Greff-Lefftz 《Geophysical Journal International》2004,159(3):1125-1137

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Numerical Simulation of Wind and Temperature Fields over Beijing Area in Summer   总被引：4，自引：0，他引：4  

HU Xiaoming  LIU Shuhu  WANG Yingchun  LI Ju 《Acta Meteorologica Sinica》2005,19(1):120-127

1. IntroductionThe basic role of urban-rural boundary layer re-search is to study all kinds of physical process changesin the atmosphere boundary layer over urban and itssurrounding areas. Urban heat island (UHI) is a well-known feature of urban-rural climate. Attempts toincrease the understanding of the causes of the UHIand other urban-rural boundary layer phenomena haveused observational, theoretical and modelling methodssince long before. Seaman (1989) used a hydrostaticmodel, with real …  相似文献   

A Possible Detection of the 26 December 2004 Great Sumatra-Andaman Islands Earthquake with Solution Products of the International GNSS Service   总被引：1，自引：0，他引：1  

J. Kouba 《Studia Geophysica et Geodaetica》2005,49(4):463-483

The main goal of this work is to critically review the IGS solution products and Precise Point Positioning (PPP) in order to demonstrate their potential to contribute to studies of large earthquakes such as the one that devastated Southeast Asia on December 26th, 2004. In view of a possible detection of the Mw 9.0 Sumatra-Andaman Islands Earthquake of December 26, 2004, position solutions, ranging from intervals of years to one second, of four International GNSS Service (IGS) stations within 3000 km of the epicenter were examined. The IGS combined, cumulative solution product (IGS04P51), consisting of epoch and station velocity solutions and based on data spans of several years prior to the earthquake, was used as a reference. Four IGS combined weekly position solutions (igs04P1301-4), two weeks before and after the earthquake, were utilized for the weekly solution resolution. PPP static and kinematic solutions with IGS Final combined orbits and clocks were used for the mean daily and instantaneous 5-min and 1-sec epoch solutions, respectively. The most significant changes, detected by both weekly and daily solutions occurred in longitude. The nearest IGS station ntus, about 1000 km east of the epicenter, moved westward about 15 mm, while the more distant Indian station iisc (∼ 2300 km NW from the epicenter), shifted about 15 mm eastward. In spite of position errors caused by interpolation of the 5-min IGS clocks, the 1-sec solutions, based on separate data sets, available only for two stations (iisc, dgar), still showed seismic surface waves, in particular at the Indian station iisc. Precise daily IGS combined polar motion and length-of-day products, after correcting for the atmospheric effects, also likely detected, statistically significant, anomalistic excitations on December 26, 2004 that could be caused by this great earthquake.  相似文献   

Hydrological excitations of polar motion, 1993–2002     

J. L. Chen  C. R. Wilson 《Geophysical Journal International》2005,160(3):833-839

  相似文献