Application of geochemical tracers for the investigations of groundwater resources in semi-arid region (Central-East Tunisia)     

Amal Gammoudi  Rim Trabelsi  Kamel Zouari 《水文研究》2024,38(2):e15076

Groundwater resources in Mahdia-Ksour Essef region, located in the central-eastern part of Tunisia, suffer from intensive exploitation and degradation of water quality. The assessment of groundwater vulnerability, the well-understanding of geochemical processes and the investigation of groundwater quality variations are of particular importance for water resources management in this semi-arid region. The results of this multi-disciplinary investigation show that groundwaters of Mahdia-Ksour Essef region are flowing from El Jem and Boumerdes regions in the South, towards the Mediterranean Sea and the sebkha of Moknine in the North. The groundwaters are classified as either Na-Cl or Ca-SO₄. Stable oxygen and hydrogen isotope compositions (δ¹⁸O and δ²H) confirm a recharge by rapid water infiltration, evaporate surface water and water-rock interaction processes in the salinity increase. The rock-water interaction processes of the mineralization of groundwaters include the cation-exchange reactions and the dissolution of carbonates and evaporate. The high values of the water quality index (WQI) and of the total dissolved solids (TDS) (3.7–11 g/L) of these groundwaters indicate their unsuitability for drinking purpose. Moreover, the combination of the WQI, TDS and nitrate results prove the vulnerability of the studied groundwater to the anthropogenic pollution linked to agriculture and domestic activities and to the salt water contamination.  相似文献   

The value of instream stable water isotope and nitrate concentration data for calibrating a travel time-based water quality model     

A. Borriero  A. Musolff  R. Kumar  J. H. Fleckenstein  S. R. Lutz  T. V. Nguyen 《水文研究》2024,38(5):e15154

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路基沉降监测中几种监测方法的应用     

贾亮  徐国双 《北京测绘》2010,(3):31-35

某高速公路工程是北京地区高速公路修建中地质条件复杂的工程之一,我们对本工程重点路段进行了施工期和工后变形监测。在整个工程监测中我们采用了横剖测试法、沉降板测量法和分层沉降法等几种监测方法进行了路基沉降监测。这几种监测方法也都体现出了不同的特点,下面对几种监测方法在工程应用中的区别、特点进行分析总结,希望对类似工程的方法选择和设计优化有所帮助。  相似文献   

地下水中铬的分离技术及其应用   总被引：1，自引：0，他引：1  

高永娟  马腾  刘存富 《地质科技情报》2006,25(4):79-81

提出了一种将地下水中的铬与其他基本离子分离的技术,用于固体离子源热电离质谱计(TIMS)测定铬同位素比值.利用铬的氧化态以阴离子形式存在的特点,采用阴离子交换色层分离法将Cr5 与干扰阳离子分离;利用铬的还原态以阳离子形式存在的特点,将Cr3 与硫酸根等干扰阴离子分离.该方法可以成功地应用于地下水中铬同位素信息的测定,在地下水铬污染研究中有着广阔的应用前景.  相似文献   

含水层中有机物对地下水水质的影响   总被引：1，自引：0，他引：1  

李海杰  吕斯濠  卢文喜 《地质科技情报》2006,25(4):82-85

化学热动力学和稳定碳同位素[δ(13C)]的研究表明浅层地下水中的碳源是地下含水层中有机物淋溶和降解作用的结果.根据天然有机物的降解规律以及CO2在水中的溶解平衡,采用CO2分压[p(CO2)]来表征有机物的影响,通过计算p(CO2)与地下水中部分化学指标的相关关系,讨论了有机物对地下水化学性质的影响.结果表明地下含水层中有机物的增加会导致地下水酸度的增大以及HCO-3、Na 和F-等质量浓度的增大;且由于地层中有机物含量较高,导致地下水中含氮物质总量升高,同时,由于大量有机物的存在而导致地下水处于还原性环境,促使地下水的氮组分更多地以NO-2-N的形式存在.  相似文献   

Composition and Origin of Shallow Biogenetic Gases in the Baise Basin, South China     

ZHU Yangming WENG Huanxin ZOU Huayao CAI Xunyu HUANG Shaofu LUO Yi 《《地质学报》英文版》2006,80(1):127-136

Based on the analytical data of over 30 gas samples, combined with geochemical and geological backgrounds, the composition and distribution characteristics of shallow biogenetic gases in the Baise Basin, a Tertiary residual basin in southern China, were extensively investigated, and the origin and formation mechanism tentatively approached. The shallow gases are primarily composed of gaseous hydrocarbons, generally accounting for over 90%. The abundances of methane and C2＋ homologues show a relatively wide range of variation, mainly 50%-100% and 0%-50%, respectively, depending on the mixing proportions between biogenetic and thermogenic gases. A highly negative carbon isotope is the significant signature for the shallow gases with δ^13C1 values of -55‰ to -75‰. According to molecular and isotopic compositions and light hydrocarbon parameters, the shallow gases in the basin can be classified into three types of origins： biogenetic gas, biogenetic/thermogenic mixed gas, and oii-biodegraded gas. They exhibit regular distribution both spatially and temporally, and are believed to be associated with the maturity of adjoining gas source rocks and biodegraded oil accumulation. The Baigang and Nadu source rocks can be considered to have experienced early and late gas generation during early burial and after basin uplift respectively. A late accumulation mechanism of multiple gas sources is put forward for the formation of the shallow gas reservoirs, which is responsible for the variations in chemical and isotopic composition of the gases in depth profile.  相似文献   

南海北部神狐海区的自生碳酸盐岩烟囱--海底富烃流体活动的记录   总被引：17，自引：0，他引：17  

陆红锋陈芳  刘坚廖志良  孙晓明苏新 《地质论评》2006,52(3):352-357

大陆边缘海的流体喷流活动或水合物分解都会导致自生碳酸盐岩的形成。南海北部神狐海区出现的自生碳酸盐岩主要为烟囱状,以铁白云石、文石、方解石碳酸盐矿物为主;稳定同位素研究显示,烟囱的δ^13CPDB值在-40．18‰～-38．69‰、δ^18OPDB值在3．75‰～4．31‰之间变化,显示了导源于甲烷厌氧氧化作用的特征,是海底富含甲烷的流体活动的最终产物。持续或间断的流体喷流活动,使神狐海区碳酸盐岩烟囱发生单阶段或多阶段沉淀。  相似文献   

辽河西部凹陷古潜山原油及其源岩的分子碳同位素地球化学   总被引：1，自引：1，他引：0  

王春江  傅家谟  盛国英 《地球化学》2006,35(1):68-80

以辽河西部凹陷潜山带原油及其源岩为例,系统研究了正构烷烃、异戊二烯烷烃、异构与反异构及藿烷系列化合物的碳同位素组成与分布特征,探讨了其相互关系及生源-环境因素的影响。各系列化合物的分子碳同位素组成的变化具有较好的相关性,反映了沉积体系中生源-环境因素的系统变化。应用各系列分子碳同位素组成相关分析有效地区分了不同潜山带原油的油源差异。原油正构烷烃较异戊二烯烷烃碳同位素偏正0.5‰～5.0‰、姥鲛烷较植烷偏正0.4‰～1.4‰,指示了甲烷生成菌对植烷的重要贡献;C21 长链异戊二烯烷烃较植烷系列碳同位素偏正0.5‰～2.0‰,表明其生源存在差异。异构及反异构烷烃与其他系列化合物碳同位素的对比显示了蓝细菌对这类化合物的重要贡献。C31 藿烷较C30藿烷富集13C达10‰～12‰,指示其生源不同,13C强烈损耗型C30藿烷(-61.2‰～-51.8‰)主要衍生于嗜甲烷菌,它们生存于Es4期强烈分层水体中的缺氧/有氧界面。Es3油源油中正构烷烃碳同位素特别偏正,且异构、反异构烷烃及藿烷碳同位素都明显偏正,综合反映了蓝细菌的重要贡献,而干酪根碳同位素明显偏正及4-甲基甾烷相对富集指示了沟鞭藻对沉积有机质的重要贡献。  相似文献   

乙烷稳定碳同位素动力学模拟及地质应用   总被引：6，自引：4，他引：2  

帅燕华  邹艳荣  彭平安  张水昌  熊永强  刘金钟 《地球化学》2006,35(2):151-156

详细介绍了限定体系下乙烷稳定碳同位素动力学模拟过程及煤成乙烷的同位素演化规律。地质模拟结果展示,煤成天然气乙烷演化规律与甲烷类似,低熟阶段存在一个下降的趋势,其最轻同位素值为-27.8‰,与我国常用的煤成气判别标准基本一致,对应有机质成熟度(Easy%Ro)为1.0。随后,乙烷稳定碳同位素逐渐变重,与Ro之间呈良好的线性关系。  相似文献   

中国东部一场罕见的大雾天气成因分析   总被引：5，自引：0，他引：5  

张新荣  刘治国  杨建才  刘新伟  程鹏 《干旱气象》2006,24(3):47-51

对2004年11月30日至12月4日入冬以来中国东部最大范围的大雾天气过程,从大气环流形势背景及其调整和演变,天气气候背景,大气层结条件,近地面水汽条件等方面进行了分析,结果表明:此次大雾是在大气低层暖平流、大气层结相对稳定和充沛的水汽条件下产生的,雾的消散需要雾区有冷空气入侵,出现大风降温天气。  相似文献