Estimation of dispersion in estuaries by a self-consistent method     

D.J. Gunn  O. Yenigun 《Estuarine, Coastal and Shelf Science》1985,21(2):257-272

Longitudinal and transverse dispersion in estuaries may be determined in principle by measuring the change in time of the concentration field of a water soluble dye. In practice, measurements may take the form of several sampling runs crossing the dye patch. The coefficients of dispersion are usually estimated from the second moments of the concentration field; the use of second moments, in particular, introduces errors because measurements at long times or distance are unduly emphasized.A self-consistent method, free of the disadvantages inherent in the use of higher moments, is described in which the distribution of concentration in space is related to the zeroth spatial moment of concentration. In this formulation, based upon sampling runs across the dye patch, the concentration field in the estuary may be directly and simply related to the dispersion coefficients in both the intercept and gradient of a linear graph.The methods are illustrated by the characterization of a series of experiments in the Inner Estuary of Milford Haven.  相似文献   

BACKGROUND STUDY ON NON-RESIDUAL PHASE OF ELEMENTS IN CHANGJIANG AND HUANGHE ESTUARINE SEDIMENTS     

刘新威  吴景阳  蔡月琴  林荣根  韩桂荣 《中国海洋湖沼学报》1996,14(3):282-290

Analysis of Zn, Cu, Pb, Co, Cr, Li, Ni, K, Al, Fe extracted by 1 mol/L HCl or 0.5 mol/LHCl/H_2O_2, showed concentrations of Zn, Cu, Pb, Co, Cr, Fe, Ni were significantly correlated with Li, Al,K, and clay. Two methods are used to indicate the background value of the non-residual phase of elementsin sediments, and are the same as the methods used to indicate the background value of totalconcentrations in sediments. The first method uses correlograms and regression equations,the second usesthe mean element concentrations normalized with grain size. Li, Al, K can be used as reference elements to determine the background value of Zn, Cu, Pb, Co,Cr, Ni, Fe, while the clay concentration's correlation with some extractable concentrations can be used tocalculate the background value of the non-residual phase of elements as a percentage of clay concentrationin the sediments. Based on this study, the concept of using the background value of the non-residualphase of elements to compare the pollution level in differ  相似文献   

THE CHARACTERISTIC OF MARINE ENVIRONMENT IN LINGDINGYANG ESTUARY     

CHEN Bing-lu  ZHANG Yun-ni  CHEN Xin-geng  WANG Zhi-gang  YANG Guang-xing 《中国地理科学(英文版)》2001,11(2):155-162

1 HYDROLOGIC FEATURES Lingdingyang Estuary, located at the middle south of Guangdong Province, is a bell-shaped estuary with a north-south direction. Its area is about 2100km2. The north of Qi′ao Island and Inner-Lingding Island, and the south of Humen are grouped as Neilingdingyang Estuary, having an area of 1041km2. Affected by topography, runoff and tide, its dynamic condition is very complicated. Different water areas have different hydrologic features. The topography under …  相似文献   

Anoxic nitrification: Evidence from Humber Estuary sediments (UK)   总被引：3，自引：0，他引：3  

Rebecca Bartlett  Robert J.G. Mortimer  Katherine Morris 《Chemical Geology》2008,250(1-4):29-39

Conventional understanding of the nitrogen cycle in marine sediments has changed in recent years with the discovery of an alternative pathway for ammonia oxidation via the reduction of manganese oxides (during anoxic nitrification). In anoxic sediments, the potential for manganese oxides to serve as oxidant for nitrification may be considerable yet previous work on manganese-rich sediments has suggested anoxic nitrification may not be significant. In this study, the potential for anoxic nitrification in a range of sediment types was investigated. Laboratory incubation of sediment from three sites on the Humber Estuary, a microbially diverse environment, showed anoxic accumulation of nitrate, nitrite and dinitrogen gas, with and without the addition of synthetic manganese oxides. Incubation experiments confirmed anoxic nitrification as microbially mediated, with heat-killed controls yielding negative results. The anoxic nitrification reaction significantly depleted ammonia concentrations, and occurred simultaneously with manganese-, iron- and sulphate reduction, and methanogenesis. Taken in conjunction with other studies, results suggest anoxic nitrification may not only be dependent on total manganese concentrations but on manganese dynamics. Anoxic nitrification may be explained as a non-steady state reaction, dependent on the recent stability of a sediment system. Physical perturbation of sediments may cause the redistribution and/or introduction of manganese oxides and promote anoxic nitrification. The significance and persistence of anoxic nitrification is likely to depend on the frequency and magnitude of sediment perturbation, which explains why the reaction varies so widely across studied sites, and why it may not occur in some manganese-rich sediment.  相似文献   

Modeling on adsorption–desorption of trace metals to suspended particle matter in the Changjiang Estuary     

Y. Y. Zhang  E. R. Zhang  J. Zhang 《Environmental Geology》2008,53(8):1751-1766

The uptake and release of trace metals (Cu, Ni, Zn, Cd, and Co) in estuaries are studied using river and sea end-member waters and suspended particulate matter (SPM) collected from the Changjiang Estuary, China. The kinetics of adsorption and desorption were studied in terms of environmental factors (pH, SPM loading, and salinity) and metal concentrations. The uptake of the metals studied onto SPM occurred mostly within 10 h and reached an asymptotic value within 40 h in the Changjiang Estuary. As low pH river water flows into the high pH seawater and the water become more alkaline as it approaches to the seaside of estuary, metals adsorb more on SPM in higher pH water, thus, particulate phase transport of metal become increasingly important in the seaward side of the estuary. The percentage of adsorption recovery and the distribution coefficients for trace metals remained to be relatively invariable and a significant reduction only occurred in very high concentrations of metals (>0.1 mg L⁻¹). The general effect of salinity on metal behavior was to decrease the degree of adsorption of Cu, Zn, Cd, Co, and Ni onto SPM but to increase their adsorption equilibrium pH. The adsorption–desorption kinetics of trace metals were further investigated using Kurbatov adsorption model. The model appears to be most useful for the metals showing the conservative behavior during mixing of river and seawater in the estuary. Our work demonstrates that dissolved concentration of trace metals in estuary can be modeled based on the metal concentration in SPM, pH and salinity using a Kurbatov adsorption model assuming the natural SPM as a simple surfaced molecule.  相似文献   

长江河口洪水造床作用   总被引：5，自引：0，他引：5  

巩彩兰  恽才兴 《海洋工程》2002,20(3):94-97

据多年实测资料统计 ,长江口年径流总量 92 4 0亿m3,年输沙量 4 .86亿t,洪季的径流量和输沙量分别占全年总量的71.7%和 87.2 %。如遇洪水年 ,当洪峰流量超过 6 0 0 0 0m3 s时 ,中、下游河道水位明显抬高而进入防汛警戒状态 ,河床有明显冲淤变化 ;洪峰流量超过 70 0 0 0m3 s时 ,新生汊道及切滩串沟频频出现 ,给河口治理及深水航道开发带来重要的影响。从长江河口河槽演变基本特征及南港、北槽底沙输移强度引证长江洪水在河口地区的造床作用  相似文献   

伶仃洋沉积动力特点的研究   总被引：7，自引：0，他引：7  

应秩甫 《热带海洋学报》1995,(2)

位于珠江三角洲东侧的伶仃洋，因径流下泄与潮流进退的流向不一，使它各分流口门的出口水道都有主槽和支槽之分，即都有主干水道和分汊水道。陆架高盐海水入侵又使伶仃洋内沉积动力过程在空间分布上发生差异，如沉积物分布有粗－细－稍粗之分；而水体中的密度、速度差异，常常产生锋带，对水下地形的发展有不可忽视的影响。因而全面认识发生在伶仃洋内的沉积动力作用，对深水航道的选线极为重要。  相似文献   

九龙江口红树林湿地与米草湿地的底栖生物   总被引：12，自引：0，他引：12  

洪荣标  吕小梅  陈岚  方少华 《台湾海峡》2005,24(2):189-194

2004年冬季,在厦门海沧青礁和海沧大道东侧潮间带进行红树林湿地、互花米草湿地和普通滩涂湿地的底栖生物生态调查.调查结果:定量样品普通滩涂出现的种类、生物量比互花米草区和红树林区多,互花米草区底栖动物的栖息密度、种类多样性、丰度比红树林区高.  相似文献   

远区台风“三巴”对长江口波浪动力场的作用机制     

任剑波  何青  沈健  徐凡  郭磊城  谢卫明  朱磊 《海洋科学》2020,44(5):12-23

针对远区台风对河口波浪动力场的影响问题,利用第三代波浪模式SWAN计算了远区台风"三巴"期间长江口波浪动力场分布,分析了陆架至河口区的波浪能量耗散和波致泥沙侵蚀的时空分布,发现波浪由外海向近岸传播过程中,波-波相互作用导致能量由高频向低频转换,周期和波长逐渐增大,近底层轨道流速增大,能量密度增高;阐明白帽破碎是维持深水区波浪能量平衡和限制波高成长的主要机制,底摩擦耗能和水深诱导的破碎耗能是长江口横沙东滩和崇明东滩邻近海域波高衰减的主要原因;提出波浪产生的底部切应力与相对水深有关,当波浪传播到浅水区时,波长和周期越大,波浪切应力越大。研究揭示了与河口相距数百公里的远区台风能够对长江口波浪动力场产生明显影响,河口水下三角洲前缘是最容易受到波浪侵蚀的区域,研究成果弥补了目前关于陆架远区台风对河口波浪动力场影响研究的不足,对深化认识远区台风对长江口动力环境、地貌演变、航运安全和滩涂保护等有重要科学意义。  相似文献   

Trace element diagenesis in pyrite-rich sediments of the Achterwasser lagoon, SW Baltic Sea     

Florian Scholz  Thomas Neumann 《Marine Chemistry》2007,107(4):516-532

The early diagenesis of trace elements (V, Cr, Co, Cu, Zn, As, Cd, Ba, U) in anoxic sediments of the Achterwasser, a shallow lagoon in the non-tidal Oder estuary in the Baltic Sea, was investigated in the context of pyrite formation. The dissolved major redox parameters show a two-tier distribution with transient signals in the occasionally re-suspended fluid mud layer (FM) and a permanently established diagenetic sequence in the sediment below. Intense microbial respiration leads to rapid depletion of O₂ within the uppermost mm of the FM. The reduction zones of Mn, Fe and sulfate overlap in the FM and in the permanently anoxic sediment section which appears to be a typical feature of estuarine sediments, under low-sulfate conditions. Degrees of pyritization (DOP) range from 50% in the FM to remarkably high values > 90% at 50 cm depth. Pyrite formation at the sediment surface is attributed to the reaction of Fe-monosulfides with intermediate sulfur species via the polysulfide pathway. By contrast, intense pyritization in the permanently anoxic sediment below is attributed to mineral growth via adsorption of aqueous Fe-sulfide complexes onto pyrite crystals which had originally formed in the surface layer.The studied trace elements show differential behavior patterns which are closely coupled to the diagenetic processes described above: (i) Zn, Cu and Cd are liberated from organic matter in the thin oxic layer of the sediment and diffuse both upwards across the sediment/water boundary and downwards to be trapped as monosulfides, (ii) V, Cr, Co and As are released during reductive dissolution of Mn- and Fe-oxyhydroxides, (iii) U removal from pore water occurs concomitantly to Fe reduction in the FM and is attributed to reduction of U(VI) to U(IV), (iv) the Ba distribution is controlled by reductive dissolution of authigenic barite in the sulfate reduction zone coupled with upward diffusion and re-precipitation. The incorporation of trace elements into pyrite is most intense for Co, Mn and As, intermediate for Cu and Cr and little to negligible for U, Zn, Cd, V and Ba. The observed trend is largely in agreement with previous studies and may be explained with differing rates for ligand exchange. Slow and fast ligand exchange and thus precipitation kinetics are also displayed by downcore increasing (Mn, Cr, Co and As) or constantly low (Zn, Cu, Cd) pore water concentrations. The downward increasing degrees of trace metal pyritization (DTMP) for Co, Cu, Zn and As are, in analogy to pyrite growth, assigned to adsorption of sulfide complexes or As oxyanions onto preexisting pyrite minerals.  相似文献