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This paper deals with the infrared spectra of " amino acid- clay , calcium carbonate and y-AlOOH" and " Cu (II )-clay-amino acid" model systems, and shows that the model of the ternary surface complex is M-OHLCu (L = amino acid) for marine solid particle-Cu (II)-amino acid. Study of the formation mechanism of the ternary surface complex shows that the specific surface area , and especially the intrinsic acidity constant, determine whether the ternary surface complex is easily formed, and that factor, FTSC,quantifies the relationship between the promoting effect of organics on Mt-marine solid particle ion exchange and the intrinsic acidity constant and specific surface area. 相似文献
3.
过硫酸铵氧化容量法测定矿石中锰方法的改进 总被引:5,自引:1,他引:5
采用过硫酸铵氧化容量法测定锰时,可在低酸度(0.18mol/LH2SO4、0.29mol/LH3PO4)和大体积(300mL)溶液中氧化Mn2 至Mn7 。所测得的结果十分稳定,回收率为100%。采用管理样分析验证方法,其结果与铋酸钠容量法结果一致。对于w(Mn)=11.36%的试样进行10次分析测定,RSD=0.33%。方法可测定w(Mn)≥0.01%的常见矿种样品。 相似文献
4.
No author 《Aquatic Sciences - Research Across Boundaries》2005,67(3):392-291
No Abstract. .The following two amendments concern the above mentioned article that appeared electronically Online First on June13, 2005 (this issue, pp. 274–291).1. the first name of the author Cooper is Philip (and not Phillip).2. the correct grant reference number is EVK1-CT-1999-00032 (instead of: EVK1-CT-2002-00121). 相似文献
5.
Diatoms were identified and enumerated from a surface sediment calibration set of 50 lakes in northwestern Québec. The relationship
between species composition and environmental variables was examined using canonical correspondence analysis (CCA). Forward
selection and Monte Carlo permutation tests in CCA indicated that diatom species distributions in the data set are most strongly
correlated to lakewater pH. A strong (r
2
boot = 0.83) weighted averaging calibration model, that includes bootstrapped error estimates, was developed for inferring past
lakewater pH. Using this model, temporal changes in pH were reconstructed for two kettle lakes, Lac de la Pépinière and Lac
Perron. Based on limnological data, both the study lakes were expected to have recently acidified due to increased acidic
precipitation and increases in anthropogenic metal loading. However, our long-term pH inference data indicate that these lakes
were naturally acidic during pre-industrial times. Nonetheless, the rate of acidification, particularly in Lac de la Pépinière,
has accelerated in the last ∼75 years. These long-term pH records developed for the dilute lakes in northwestern Québec suggest
that the region has received increased atmospheric pollutants from the nearby Horne smelter in Rouyn-Noranda. The pH inference
profiles are markedly different from many other paleolimnological studies in acid-sensitive regions of Canada that have become
acidic primarily as a result of industrial activities.
Electronic supplementary material The online version of this article (doi: ) contains supplementary material, which is available to authorized users. 相似文献
6.
A simulation was undertaken within a climatic chamber to investigate limestone dissolution under varied carbonic acid (H2CO3) strengths as a possible analogue for future increases in atmospheric CO2 arising from global warming. Twenty‐eight samples cut from a block of Bath (Box Hill) limestone from Somerville College, Oxford, which had been removed during restoration after 150 years in an urban environment, were weighed and placed in closed bottles of thin plastic containing varying concentrations of H2CO3. Half of the stone samples were derived from exposed surfaces of the stone block (weathered) while the others were obtained from the centre of the block on unexposed surfaces (unweathered). The purpose of this was to compare dissolution of previously weathered versus unweathered surfaces in strong (pH 4·73) versus weak (pH 6·43) solutions of H2CO3. A temperature of c. 19 °C was maintained within the chamber representing a plausible future temperature in Oxford for the year 2200 given current warming scenarios. The simulation lasted 25 days with a few stone samples being removed midway. Stone samples show reduced weight in all cases but one. There was greater dissolution of stone samples in a strong H2CO3 solution as conveyed by higher concentrations of total hardness and Ca2+ in the water samples as well as enhanced microscopic dissolution features identified using SEM. The simulation confirms that enhanced atmospheric CO2 under global warming, given adequate moisture, will accelerate dissolution rates particularly of newly replaced limestone building stones. However, previously weathered surfaces, such as those on historical stone exposed for a century or more, appear to be less susceptible to the effects of such increased rainfall acidity. Conservation techniques which remove weathered surfaces, such as stone cleaning, may accelerate future decay of historical limestone structures by increasing their susceptibility to dissolution. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
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8.
可变电荷土壤和恒电荷土壤与氢离子相互作用机理 总被引:2,自引:4,他引:2
研究了可变电荷土壤和恒电荷土壤与H相互作用的机理,并比较了它们之间的差别,研究结果表明,氢离子输入土壤后可以转化为表面正电荷,可溶性铝和可交换性酸,但是由于土壤的组成和性质不同,不同土壤中H+三种去向的贡献不同。H+转化为表面正电荷是由于土壤表面Fe-OH,Al-OH的质子化造成的,因此H+转化为表面正电荷的能力与土壤中氧化铁的含量密切相关,从而可变电荷土壤中H+转化为表面正电荷的贡献比恒电荷土壤中的大。H+转化为可溶性铝的能力与土教育部 的矿物组成密切相关,随着H+输入量的增加,土壤中可溶性铝的含量也增加。可变电荷土壤中可溶性铝增加的顺序为红壤>赤红壤>铁质砖红壤,在H+的加入量小于15mmol/kg时,黄棕壤的可溶性铝介于红壤和赤红壤之间,当H+的加入量大于约15mmol/kg时,黄棕壤的可溶性铝略小于赤红壤,棕壤的可溶性铝明显小于红壤和赤红壤,但比铁质砖红壤高,恒电荷土壤的可变性酸量明显大于可变电荷土壤,但从总的看来,H+加入量的变化对可交换性酸量的影响不大。 相似文献
9.
Covariations in oceanic dimethyl sulfide,its oxidation products and rain acidity at Amsterdam Island in the Southern Indian Ocean 总被引:5,自引:0,他引:5
B. C. Nguyen N. Mihalopoulos J. P. Putaud A. Gaudry L. Gallet W. C. Keene J. N. Galloway 《Journal of Atmospheric Chemistry》1992,15(1):39-53
Simultaneous measurements of rain acidity and dimethyl sulfide (DMS) at the ocean surface and in the atmosphere were performed at Amsterdam Island over a 4 year period. During the last 2 years, measurements of sulfur dioxide (SO2) in the atmosphere and of methane sulfonic acid (MSA) and non-sea-salt-sulfate (nss-SO4
2-) in rainwater were also performed. Covariations are observed between the oceanic and atmospheric DMS concentrations, atmospheric SO2 concentrations, wet deposition of MSA, nss-SO4
2-, and rain acidity. A comparable summer to winter ratio of DMS and SO2 in the atmosphere and MSA in precipitation were also observed. From the chemical composition of precipitation we estimate that DMS oxidation products contribute approximately 40% of the rain acidity. If we consider the acidity in excess, then DMS oxidation products contribute about 55%. 相似文献
10.
工业区与非工业区辐射雾水的化学组成 总被引:9,自引:0,他引:9
1988年冬季,你们对云南省安宁工业区和西双版纳非工业区雾水进行采集,工业区雾水混浊肮脏,含有大量固体颗粒,雾水中离子浓度值与附近工厂排向大气的污染物有关,但雾水酸度值并不高。非工业区雾水比较清洁,雾水中离子浓度值平均比工业区低一个数量级。本文还讨论了一个雾过程离子浓度变化与温度层结的关系。 相似文献