Determination of cadmium(II), copper(II), manganese(II) and nickel(II) species in Antarctic seawater with complexing resins   总被引：1，自引：0，他引：1  

Raffaela Biesuz  Giancarla Alberti  Girolamo D'Agostino  Emanuele Magi  Maria Pesavento 《Marine Chemistry》2006,101(3-4):180-189

The strong species of cadmium(II), copper(II), manganese(II) and nickel(II) in an Antarctic seawater sample are investigated by a method based on the sorption of metal ions on complexing resins. The resins compete with the ligands present in the sample to combine with the metal ions. Two resins with different adsorbing strengths were used. Very stable metal complexes were investigated with the strong sorbent Chelex 100 and weaker species with the less strong resin, Amberlite CG-50. Strong species were detected for three of the considered metal ions, but not for Mn(II). Cu(II) is completely linked to species with a side reaction coefficient as high as log α_M(I) = 11.6 at pH = 7.3. The ligand concentration was found to be similar to that of the metal ion, and the conditional stability constant was around 10²⁰ M^− 1. In the considered sample, only a fraction of the metal ions Cd(II) and Ni(II) is bound to the strong ligands, with side reaction coefficients equal to log α_M(I) = 5.5 and 6.5 at pH = 7.3 for Cd(II) and Ni(II), respectively. These findings were confirmed by the test with the weaker sorbent Amberlite CG-50. It can be calculated from the sorption equilibria that neither Mn(II) nor Ni(II) is adsorbed on Amberlite CG-50 under the considered conditions and, in fact, only a negligible fraction of Mn(II) and Ni(II) was adsorbed. A noticeable fraction of Cd(II) was adsorbed on Amberlite CG-50, meaning that cadmium(II) is partially linked to weak ligands, possibly chloride, while no copper(II) was adsorbed on this resin, confirming that copper(II) is only combined in strong species. These results are similar, but not identical, to those obtained for other seawater samples examined in previous investigations.  相似文献   

Modelling linear wave transformation induced by dissipative structures—Random waves     

R. Silva  M.A. Losada  P. Salles 《Ocean Engineering》2006,33(16):2174-2194

The relevant theory is presented and numerical results are compared with the analytical solution for the interaction of non-breaking waves with an array of vertical porous circular cylinders on a horizontal bed. The extension to the cases of unidirectional and multidirectional waves is obtained by means of a transfer function. The influence of the mechanical properties of porous structures and wave irregularity on wave transformation is analysed. Results for unidirectional and multidirectional wave spectra are compared to those obtained for regular waves. The model presented reproduces well the analytical results and provides a tool for analysing several engineering problems.  相似文献   

柴达木盆地新构造运动主要特征与成因机制   总被引：10，自引：0，他引：10  

杨明慧 《海洋地质与第四纪地质》1997,17(3):71-78

研究表明，在壳幔结构、地球物理背景、沉积物结构、多层关地幔和构造样式等方面，达木盆地与中国东部新生代裂谷类伸展盆地具有可比性，应该归属 展性盆 。盆地伸展和收缩作用相间进行，伸展起因于地幔底辟；而收缩受两人因素影响；（１）盆地伸展作用受相邻造山带反作用诱导的挤压应力；（２）板块碰撞传递的远程板内应力。在此基础邮新的构造期达木盆地演化的“双层模式”，即地幔上隆－地壳伸展；被动挤压＋板内应力－地壳收缩  相似文献   

Mean flow and variability in the southwestern East Sea     

Kyung-Il Chang  Nelson G. Hogg  Moon-Sik Suk  Sang-Kyung Byun  Young-Gyu Kim  Kuh Kim 《Deep Sea Research Part I: Oceanographic Research Papers》2002,49(12)

The Ulleung Basin is one of three deep basins that are contained within the East/Japan Sea. Current meter moorings have been maintained in this basin beginning in 1996. The data from these moorings are used to investigate the mean circulation pattern, variability of deep flows, and volume transports of major water masses in the Ulleung Basin with supporting hydrographic data and help from a high-resolution numerical model. The bottom water within the Ulleung Basin, which must enter through a constricted passage from the north, is found to circulate cyclonically—a pattern that seems prevalent throughout the East Sea. A strong current of about 6 cms⁻¹ on average flows southward over the continental slope off the Korean coast underlying the northward East Korean Warm Current as part of the mean abyssal cyclonic circulation. Volume transports of the northward East Korean Warm Current, and southward flowing East Sea Intermediate Water and East Sea Proper Water are estimated to be 1.4 Sv (1 Sv=10⁻⁶ m³ s⁻¹), 0.8 Sv, and 3.0–4.0 Sv, respectively. Deep flow variability involves a wide range of time scales with no apparent seasonal variations, whereas the deep currents in the northern East Sea are known to be strongly seasonal.  相似文献   

Circulation and currents in the southwestern East/Japan Sea: Overview and review     

K.-I. Chang  W.J. Teague  S.J. Lyu  H.T. Perkins  D.-K. Lee  D.R. Watts  Y.-B. Kim  D.A. Mitchell  C.M. Lee  K. Kim 《Progress in Oceanography》2004,61(2-4):105

A review is made of circulation and currents in the southwestern East/Japan Sea (the Ulleung Basin), and the Korea/Tsushima Strait which is a unique conduit for surface inflow into the Ulleung Basin. The review particularly concentrates on describing some preliminary results from recent extensive measurements made after 1996. Mean flow patterns are different in the upstream and downstream regions of the Korea/Tsushima Strait. A high velocity core occurs in the mid-section in the upstream region, and splits into two cores hugging the coasts of Korea and Japan, the downstream region, after passing around Tsushima Island located in the middle of the strait. Four-year mean transport into the East/Japan Sea through the Korea/Tsushima Strait based on submarine cable data calibrated by direct observations is 2.4 Sv (1 Sv = 10⁶ m³ s⁻¹). A wide range of variability occurs for the subtidal transport variation from subinertial (2–10 days) to interannual scales. While the subinertial variability is shown to arise from the atmospheric pressure disturbances, the longer period variation has been poorly understood.Mean upper circulation of the Ulleung Basin is characterized by the northward flowing East Korean Warm Current along the east coast of Korea and its meander eastward after the separation from the coast, the Offshore Branch along the coast of Japan, and the anticyclonic Ulleung Warm Eddy that forms from a meander of the East Korean Warm Current. Continuous acoustic travel-time measurements between June 1999 and June 2001 suggest five quasi-stable upper circulation patterns that persist for about 3–5 months with transitions between successive patterns occurring in a few months or days. Disappearance of the East Korean Warm Current is triggered by merging the Dok Cold Eddy, originating from the pinching-off of the meander trough, with the coastal cold water carried Southward by the North Korean Cold Current. The Ulleung Warm Eddy persisted for about 20 months in the middle of the Ulleung Basin with changes in its position and spatial scale associated with strengthening and weakening of the transport through the Korea/Tsushima Strait. The variability of upper circulation is partly related to the transport variation through the Korea/Tsushima Strait. Movements of the coastal cold water and the instability of the polar front also appear to be important factors affecting the variability.Deep circulation in the Ulleung Basin is primarily cyclonic and commonly consists of one or more cyclonic cells, and an anticyclonic cell centered near Ulleung Island. The cyclonic circulation is conjectured to be driven by a net inflow through the Ulleung Interplain Gap, which serves as a conduit for the exchange of deep waters between the Japan Basin in the northern East Sea and the Ulleung Basin. Deep currents are characterized by a short correlation scale and the predominance of mesoscale variability with periods of 20–40 days. Seasonality of deep currents is indistinct, and the coupling of upper and deep circulation has not been clarified yet.  相似文献   

Risk Assessment for Tuzla Naval Base Breakwater   总被引：5，自引：0，他引：5  

Can Elmar BALAS 《中国海洋工程》2003,17(3)

1 .IntroductionTurkeywasstruckbytwomajorearthquakeeventsonAugust 1 7thandNovember 1 2th ,1 999,namedIzmit (Mw=7.4 )andD櫣ｚｃｅ (Mw=7.2 )earthquakes,respectively .ThestationsoperatedbytheGeneralDirectorateofDisasterAffairs,theKandilliObservatoryandEarthquakeResearchInstituteofIstanbulTechnicalUniversitymeasuredatleast 2 7stronggroundmotionsfortheIzmitearthquakewithin 2 0 0kmofthefault.AsignificantsegmentofthefaultrupturedintheareabetweenthewestofGolcukandtheeastofLakeSapanca .Inthesou…  相似文献   

Applying an alternative method of echo-integration     

Aksland  Magnar 《ICES Journal of Marine Science》2006,63(8):1438-1452

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Time changes in fishing power in the Danish cod fisheries of the Baltic Sea     

Marchal  Paul; Nielsen  J. Rasmus; Hovgard  Holger; Lassen  Hans 《ICES Journal of Marine Science》2001,58(1):298-310

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对虾体内氯霉素含量测定方法的研究   总被引：1，自引：0，他引：1  

李兰生  王勇强 《中国海洋大学学报(自然科学版)》1995,(3)

应用ＨＰＬＣ技术建立常用药物氯霉素的虾体动力学研究方法。该方法的特点是：与微生物法、比色法、气相色谱法、荧光法及免疫法比较．测试准确、快速且灵敏度高。应用该方法可以从虾体内的血液、肌肉、肝胰脏、肠胃中分离出被虾吸收的氯霉素，并定量测定。在１—５０μｇ／ｍｌ范围内线性关系相关系数为０．９９９５。  相似文献   

Study on Key Technology of Using Shell Sand as Backfill for Sea Reclamation   总被引：1，自引：0，他引：1  

郦能惠瞿亦容  何文钦陈晖 《中国海洋工程》2005,19(4):647-658

1 .IntroductionEpicontinental sea or land could formfromcontinental shelf because of the decreasing sea levelduring Quaternary.There is a large-area shell sand deposit more than ten meters thick in the neriticzone of China .To use the abundant marine shell sandresource as engineering material for ocean engi-neering and port engineeringis veryimportant .Sand (Gred and Bjorn,1999) ,fine sand (Zhangetal .,2002) , mediumand coarse sand (Qiuet al .,1995) ,highly weathered stone ballast (Zhanetal…  相似文献