Mineralogical and geochemical alteration of low-grade metamorphic black slates due to oxidative weathering   总被引：1，自引：0，他引：1  

Cornelius Fischer  Christian Schmidt  Reinhard Gaupp 《Chemie der Erde / Geochemistry》2009,69(2):127-183

Low-grade metamorphic black slates of Silurian and Lower Devonian ages (from the Thüringisches Schiefergebirge in Germany) were investigated to identify mineralogical and geochemical alterations that occur during the oxidative weathering black slates.The slates exhibit an intense total organic carbon decrease (>90 wt%) due to oxidative weathering. The organic matter in black slate consists mainly of non-pyrolysable material with only minor portions of pyrolysable material. In contrast to the non-pyrolysable organic matter, the concentration of pyrolysable organic matter is not decreased during weathering. Heating experiments have yielded information about a potential protection of pyrolysable organic matter against weathering, which is probably caused by a structural configuration or the intergrowth of organic matter and illite.The slates consist mainly of illite. Iron oxide (goethite) and phosphate encrustations were formed on slate surfaces as a result of oxidative and acid weathering of both iron sulfide and monazite. Kaolinite often occurs as an older encrustation beneath the iron oxide encrustations. Encrustations of iron oxide and phosphate are major sinks for trace elements, released during oxidative weathering.  相似文献   

青海都兰地区前泥盆纪古陆块的物质组成和重大地质事件   总被引：5，自引：0，他引：5  

郝国杰  陆松年  辛后田  王惠初 《吉林大学学报(地球科学版)》2004,34(4):495-501,516

通过对青海都兰地区前泥盆纪地块的地质、地球化学和同位素年代学研究,将其由北向南划分为欧龙布鲁克微陆块、沙柳河超高压碰撞带和柴达木陆块三个构造单元.基本查明了欧龙布鲁克古陆块主要由德令哈片麻岩、莫河片麻岩、达肯大坂岩群、万洞沟群和全吉群组成,柴达木盆地北缘高压碰撞带主要为中新元古代沙柳河岩群、花岗闪长质片麻岩、英云闪长质片麻岩、钾长花岗片麻岩、榴辉岩、滩间山群和蛇绿岩,柴达木古陆块主要由古元古代金水口岩群和夕线堇青花岗片麻岩组成.详细厘定了本区前泥盆纪重要地质事件,特别是与Rodinia超大陆有关的汇聚与裂解事件.同时,利用先进的同位素地质年代学手段,确定了本区重要地质事件的地质时代和序列,为研究我国中-新元古代古陆块汇聚与裂解关系,以及它们在整个超大陆中的位置提供了证据.  相似文献   

A depositional model for deep‐lacustrine,partially confined,turbidite fans: Early Cretaceous,North Falkland Basin     

Thomas J. H. Dodd  Dave J. McCarthy  Philip C. Richards 《Sedimentology》2019,66(1):53-80

This paper presents a model of facies distribution within a set of early Cretaceous, deep‐lacustrine, partially confined turbidite fans (Sea Lion Fan, Sea Lion North Fan and Otter Fan) in the North Falkland Basin, South Atlantic. As a whole, ancient deep‐lacustrine turbidite systems are under‐represented in the literature when compared with those documented in marine basins. Lacustrine turbidite systems can form extensive, good quality hydrocarbon reservoirs, making the understanding of such systems crucial to exploration within lacustrine basins. An integrated analysis of seismic cross‐sections, seismic amplitude extraction maps and 455 m of core has enabled the identification of a series of turbidite fans. The deposits of these fans have been separated into lobe axis, lobe fringe and lobe distal fringe settings. Seismic architectures, observed in the seismic amplitude extraction maps, are interpreted to represent geologically associated heterogeneities, including: feeder systems, terminal mouth lobes, flow deflection, sinuous lobe axis deposits, flow constriction and stranded lobe fringe areas. When found in combination, these architectures suggest ‘partial confinement’ of a system, something that appears to be a key feature in the lacustrine turbidite setting of the North Falkland Basin. Partial confinement of a system occurs when depositionally generated topography controls the flow‐pathway and deposition of subsequent turbidite fan deposits. The term ‘partial confinement’ provides an expression for categorising a system whose depositional boundaries are unconfined by the margins of the basin, yet exhibit evidence of internal confinement, primarily controlled by depositional topography. Understanding the controls that dictate partial confinement; and the resultant distribution of sand‐prone facies within deep‐lacustrine turbidite fans, is important, particularly considering their recent rise as hydrocarbon reservoirs in rift and failed‐rift settings.  相似文献   

Heritage stone in South Australia     

B. J. Cooper 《Australian Journal of Earth Sciences》2019,66(6):947-953

South Australia has the greatest utilisation of heritage or building stone in Australia because of its lack of timber resources. Consequently, natural stone was intensively used from the beginning of European colonisation. Building stones in South Australia, notable for their variety given the State’s diverse geology, can be challenging to designate as to their international importance. However, dimension stone in South Australia can also be designated as having national, regional, local or prospective importance. Commonly, stone in South Australia is restricted in use to a specific town, or even a single construction, and has only local significance except where use involves special stone characteristics, unusual stone masonry or use in a building with significant heritage. For instance, the town of Second Valley has a localised use of marble, likely the earliest use (1849) of this rock type in the State. Another example, ‘Adelaide Black Granite’, quarried since 1958, should probably be recognised internationally as a ‘Global Heritage Stone Resource’, as it has had intensive monumental use around Australia, utilisation as cladding in modern buildings, as well as paving and walling in Australia’s National Parliament in Canberra. It has also been exported, notably used for the Australian Embassy in Japan and for a major War Memorial at Le Hamel, France. South Australian slate quarries also provide significant heritage stone. For example, the Willunga Slate quarry south of Adelaide has been sourced for roofing slate and walling since 1840 and is arguably the longest continuous mining operation in Australia; this resource has obvious national significance given a period of quarrying extending to the present, coupled with national distribution of its products. Probably the most widespread stone sourced in South Australia is the surface limestone or calcrete, quarried in the Adelaide area until the 1850s and used for general construction. The stone continues to be used in rural areas. While arguably only of local significance, it could be considered to have national importance because of its extensive use in churches, public building, hotels, houses and simple walling across a vast area of South Australia. Additional research is needed to clarify the heritage status of many building stones used in South Australia.  相似文献   

Significance of graphite inclusion occurrence in the minerals of the San Miguel skarn for the Palaeoproterozoic basement of Tandilia Belt (Argentina) and for the Río de la Plata Craton     

《Journal of South American Earth Sciences》2019

Graphite in Archaean-Palaeoproterozoic rocks has been a subject of interest since it could represent an evidence of early life on Earth. In the Palaeoproterozoic basement of the Tandilia Belt, graphite was found both in fluid inclusions (FI) hosted in the San Miguel skarn calc-silicate minerals, and as solid inclusions in calcite crystals from the protolithic marble (a¹³C enriched carbonate from the “Lomagundi-Jatuli event”). FI microthermometry and oxygen stable isotope ratios indicated the skarn minerals formation within the range of 630–650 °C (at ∼5 kbars) and ∼642–654 °C, respectively. Also, the characterisation of the metasomatic fluid (of a low salinity <7 wt% NaCl eq. NaClH₂O/NaClKClH₂O aqueous system) pointed out that the zonal crystallisation pattern shown by the skarn minerals (wollastonite-vesuvianite, grossular-diopside-calcite and diopside-calcite zones in the exoskarn, and grossular-diopside and diopside-calcic plagioclase zones in the endoskarn) responds to the increase of the involved cation activity gradients (Ca²⁺-Si⁴⁺-Mg²⁺-Fe^2+/3+-Al³⁺) and not to significant changes in the temperature or concentration of CO₂ in the system. Variation in the crystallinity degree of the graphite hosted in the skarn minerals and in marble calcite, shown by Raman spectroscopy, would indicate that the graphite could have been formed from the ripening of organic matter present in the sedimentary rocks during the metamorphic-metasomatic event (Transamazonian Orogeny). In this sense, the increase of the organic carbon productivity in the oceans during the Palaeoproterozoic, represented by the “Lomagundi-Jatuli event”, would support this graphite origin and also the possible existence of a marine sedimentary basin in the previous stages of the Río de la Plata amalgamation (Siderian-Rhyacian), in the San Miguel area of the Tandilia Belt.  相似文献   

一种顾及坡度因子与极值的地表面积计算法     

程传录  蒋光伟  田晓静  马新莹  王文利 《测绘通报》2017,(1):126-129

针对局部地形的非线性变化与图形的极值信息对地表面积计算结果的影响,提出了一种顾及坡度因子与图形极值的地表面积计算法,分析了地表面积计算理论与误差。最后以中国西部具有典型地貌特征的两县数据为例进行试验分析。试验结果表明,该方法在一定程度上对局部地形逼近具有一定的改进,宏观上与规格格网交叉对角划线法具有一定的相似度。文中推导的三角网面积传递误差可初步表明考虑局部地形坡度因子与极值的地表面积计算结果可靠性更高。  相似文献   

A laser ablation inductively coupled plasma mass spectrometry study of the distribution of chalcophile elements among sulfide phases in sedimentary and magmatic rocks of the Duluth Complex,Minnesota, USA     

《Ore Geology Reviews》2017

Nickel-copper sulfide deposits occur in the basal unit of the Partridge River Intrusion, Duluth Complex (Minnesota, USA). Many lines of evidence suggest that these sulfides are formed after assimilation of the proterozoic S-rich black shales, known as the Bedded Pyrrhotite Unit. In addition to S, black shales are enriched in Te, As, Bi, Sb and Sn (TABS) and the basaltic magma of the intrusion is contaminated by the partial melt of the black shales. The TABS are chalcophile and together with the platinum-group elements, Ni and Cu partitioned into the magmatic sulfide liquid that segregated from the Duluth magma. The TABS are important for the formation of platinum-group minerals (PGM) thus their role during crystallization of the base metal sulfide minerals could affect the distribution of the PGE. However, the concentrations of TABS in magmatic Ni-Cu-PGE deposits and their distribution among base metal sulfide minerals are poorly documented. In order to investigate whether the base metal sulfide minerals host TABS in magmatic Ni-Cu-PGE deposits, a petrographic and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) study has been carried out on base metal sulfide and silicate phases of the Partridge River Intrusion, Duluth Complex.Petrographic observations showed that the proportions of the base metal sulfide minerals vary with rock type. The sulfide assemblage of the least metamorphosed Bedded Pyrrhotite Unit from outside the contact metamorphic aureole consists of pyrite with minor pyrrhotite plus chalcopyrite (<5%), whereas within the contact aureole the sulfide assemblage of the Bedded Pyrrhotite Unit rocks consists dominantly of pyrrhotite (>95%) with small amount of chalcopyrite (<2%). The sulfide mineral assemblage in the xenoliths of the Bedded Pyrrhotite Unit and in the mafic rocks of the basal unit contains two additional sulfides, pentlandite and cubanite.Our LA-ICP-MS study shows that sulfides of the Bedded Pyrrhotite Unit are rich in TABS; consistent with these S-rich black shales being the source of TABS that contaminated the mafic magma. Most of the TABS are associated with sulfides and platinum-group minerals in the rocks of the Bedded Pyrrhotite Unit from the contact aureole, the Bedded Pyrrhotite Unit xenoliths and the mafic rocks of the Duluth Complex. In addition to these phases the laser maps show that silicate phases, i.e., orthopyroxene and plagioclase contain Sn and Pb respectively. In contrast, in the least metamorphosed samples of the Bedded Pyrrhotite Unit from outside the contact aureole although the pyrite contains some TABS mass balance calculations indicates that most the TABS are contained in other phases. In these rocks, galena hosts significant amounts of Te, Bi, Sb, Sn and Ag and few very small grains of Sb-rich phases were also observed. The host phases for As were not established but possibly organic compounds may have contributed.  相似文献   

柴北缘HP-UHP变质带多期构造热事件的再厘定:鱼卡地区高压变泥质岩锆石和独居石U-Pb定年   总被引：3，自引：3，他引：0  

周桂生  张建新  李云帅  于胜尧  喻星星  毛小红  路增龙 《岩石学报》2017,33(12):3801-3814

柴北缘高压-超高压变质带西段鱼卡地区变泥质岩中夹有榴辉岩透镜体,已有的研究显示变泥质岩的变质程度也达到了榴辉岩相,并与榴辉岩一起经历了高压-超高压变质作用,是柴北缘曾经历早古生代大陆深俯冲作用的直接证据,也是研究柴北缘大陆深俯冲过程重要的岩石"探针"。本文选择柴北缘西段鱼卡超高压变质单元中的3件蓝晶石榴白云母石英片岩HP变泥质岩样品分别进行了SHRIMP、LA-ICP-MS锆石和原位独居石U-Pb定年。样品Q06-1-2的锆石给出了920±18Ma(MSWD=1.3)的加权平均年龄,其CL图像特征和极低的Th/U比显示其为变质年龄,代表了与罗迪尼亚超大陆碰撞拼合相关的变质事件。样品A03-11-2.2的锆石给出了450±7Ma(MSWD=0.2)的年龄,认为其代表变泥质岩的榴辉岩相变质年龄。样品A03-14-11的薄片原位独居石定年给出了439±8Ma(MSWD=0.072)的加权平均年龄,结合岩相学观察,认为其可能为榴辉岩相峰期之后的早期退变质年龄。这些资料显示柴北缘鱼卡地区早古生代大陆深俯冲的时限为440~450Ma。结合已有研究资料,鱼卡高压变泥质岩记录了新元古代早期和早古生代两期变质事件,进一步证明了柴北缘地区经历了格林威尔期和早古生代两期造山事件  相似文献   

Deepwater Turbidite Lobe Deposits: A Review of the Research Frontiers     

ZHANG Leifu  PAN Mao  WANG Hongliang 《《地质学报》英文版》2017,91(1):283-300

Deepwater/deep-marine turbidite lobes are the most distal part of a siliciclastic depositional system and hold the largest sediment accumulation on the seafloor. As many giant hydrocarbon provinces have been discovered within deepwater lobe deposits, they represent one of the most promising exploration targets for hydrocarbon industry. Deepwater exploration is characterized by high cost, high risk but insufficient data because of the deep/ultra–deepwater depth. A thorough understanding of the deepwater turbidite lobe architecture, hierarchy, stacking pattern and internal facies distribution is thus vital. Recently, detailed outcrop characterizations and high–resolution seismic studies have both revealed that the deepwater lobe deposits are characterized into four–fold hierarchical arrangements from "beds", to "lobe elements", to "lobes" and to "lobe complex". Quantitative compilations have shown that hierarchical components of lobe deposits have similar length to width ratios but different width to thickness ratios depending on different turbidite systems. At all hierarchical scales, sand–prone hierarchical lobe units are always separated by mud–prone bounding units except when the bounding units are eroded by their overlying lobe units thus giving rise to vertical amalgamation and connectivity. Amalgamations often occur at more proximal regions suggesting high flow energy. A mixed flow behavior may occur towards more distal regions, resulting in deposition of "hybrid event beds". These synthesized findings could(1) help understand the lobe reservoir distribution and compartmentalization therefore benefit the exploration and development of turbidite lobes within the deep marine basins(e.g. South China Sea) and(2) provide rules and quantitative constraints on reservoir modeling. In addition, the findings associated with deepwater turbidite lobes might be a good starting point to understand the sedimentology, architecture and hierarchy of turbidites in deep lacustrine environment.  相似文献   

Population ecology of the snail Melampus bidentatus in changing salt marsh landscapes          下载免费PDF全文

Roman Zajac  Erin Kelly  Danielle Perry  Ivana Espinosa 《Marine Ecology》2017,38(2)

We studied the population ecology of the snail Melampus bidentatus in relation to patch composition and landscape structure across several salt marsh systems in Connecticut, USA. These marshes have changed significantly over the past 40–50 years including loss of total area, increased areas of short Spartina alterniflora, and decreased areas and fragmentation of Spartina patens. These changes are consistent with tidal inundation patterns that indicate frequent flooding of high marsh areas. Melampus bidentatus densities were highly variable, both among different salt marsh systems and locations within specific marshes, but were generally similar among short Sp. alterniflora and Sp. patens patches within locations. Densities were lowest where the marsh was regularly inundated at high tide and only remnant Sp. patens patches remained. Almost no snails were found in bare patches. Areas that had large Sp. patens patches adjacent to short Sp. alterniflora supported the highest M. bidentatus densities. Population size‐structure varied significantly among patch types, with higher proportions of large individuals in short Sp. alterniflora and hummocked Sp. patens patches than in large and remnant Sp. patens patches. This was likely due to size‐selective predation and/or higher snail growth rates due to better food resource conditions in short Sp. alterniflora patches. Egg mass densities and the number of eggs per egg mass were highest in short Sp. alterniflora. Our results indicate that M. bidentatus is resilient to the level and patterns of salt marsh change evident at our study sites. Indeed, snail densities were significantly higher than reported in other field studies, suggesting that increased patch areas of short Sp. alterniflora and associated environmental conditions at our study sites may provide more favorable habitats than previously when marshes were dominated by extensive Sp. patens meadows. However, there may be threshold conditions that could overwhelm the ability of M. bidentatus to maintain itself within salt marsh systems where changes in hydrology, sedimentation and other factors lead to increased numbers of bare patches and ponds and loss of short Sp. alterniflora and Sp. patens. Studies of the responses of resident and transient fauna to salt marsh change are critically needed in order to better understand the implications for salt marsh ecosystem dynamics and services.  相似文献