纯油条件下合成碳酸盐岩烃类包裹体及其捕获机制探讨   总被引：1，自引：0，他引：1       下载免费PDF全文

葛云锦  陈勇  周瑶琪  周振柱  王艳 《地质科学》2012,47(1):202-210

设计了在接近实际储层温压条件下,流体介质为纯原油时在冰洲石中合成烃类包裹体的实验。合成样品的显微观察及荧光分析证实实验成功合成了烃类包裹体,实验证明油气对晶体生长和包裹体的形成有抑制作用,但不会终止其形成,纯油条件晶体仍能生长捕获包裹体,水并不是矿物生长捕获烃类包裹体的必须条件。结合矿物润湿性实验及前人研究将碳酸盐岩烃类包裹体捕获机制归纳为3种情况:油水共存(水润湿)、油水共存(油润湿)及纯油条件。水润湿条件下由水溶液提供矿物质来源,较易形成包裹体; 油润湿条件下由水溶液和油中的极性组分共同提供矿物质来源; 纯油条件下由原油中的极性组分和裂解产生的有机酸提供物源,形成烃类包裹体较少,晶体生长受到抑制。  相似文献   

阿姆河盆地卡洛夫-牛津阶碳酸盐岩储层地球化学特征和成岩流体分析   总被引：2，自引：1，他引：1  

郑荣才  刘合年  吴蕾  陈仁金  史建南  李凤杰 《岩石学报》2012,28(3):961-970

卡洛夫-牛津阶碳酸盐岩为土库曼斯坦阿姆河盆地主力天然气产层,以储层岩石学分析为基础,结合Fe、Sr、Mn微量元素和C、O、Sr同位素及流体包裹体地球化学特征,分析了储层成因和成岩流体性质,得出以下几点认识:(1)由厚壳蛤壳体测定的87Sr/86Sr比值在全球锶同位素地层曲线上可标定的年龄为157.2Ma,储层发育层位属于卡洛夫-牛津阶;(2)卡洛夫-牛津阶为一持续海侵-海退旋回,持续海侵期是礁、滩相储层形成期,而持续海退期为致密盖层发育期;(3)较高的Fe和Sr及较低的Mn含量,以及伴随成岩强度加大δ13C变化不大而δ18O向负值方向偏移的演化趋势,证明成岩作用发生在缺乏大陆淡水影响和以温度为主控因素的还原性封闭系统中;(4)综合同位素地球化学与流体包裹体和镜质体反射率特征,可确定洛夫-牛津阶碳酸盐岩仍处在中成岩阶段;(5)礁、滩相灰岩的溶蚀、埋藏白云化和充填缝、洞的方解石是不同成岩阶段的水-岩反应产物,成岩流体主要来自于深部富Sr的地层热卤水。  相似文献   

中国海相油气地质理论新进展   总被引：9，自引：4，他引：5  

朱光有  杨海军  苏劲  韩剑发  朱永峰  王宇  顾礼敬  刘星旺 《岩石学报》2012,28(3):722-738

近年来中国海相油气勘探呈现出快速发展势头,一批大型海相油气田被发现,海相油气的地位也愈来愈受到重视。特别是在海相石油地质新理论的指导下,海相油气勘探将进入高速发展时期,这也将会极大缓解东部陆相盆地老油区的勘探开发压力。海相石油地质新理论包括三个方面:在成烃方面,研究认为中国海相不缺乏高有机质丰度的泥质烃源岩,纯碳酸盐岩生烃能力有限;深埋高温下原油裂解成气和高演化阶段的海陆过渡相煤系烃源岩是海相天然气的主力气源;在低地温梯度和晚期深埋条件下,原油的稳定性较高,塔里木盆地液相石油可以赋存在9000m以上的储集层中,因此,塔里木盆地深层石油的勘探潜力很大。在储层方面,TSR溶蚀改造储层在深部更强烈、层间岩溶和顺层岩溶不受埋深限制或影响不明显,将解放深部碳酸盐岩的勘探。在油气成藏方面,大面积、准层状、连续型、缝洞型等油气富集模式的提出,拓展油气勘探的范围、降低了勘探成本;一批古老油藏的发现,提高了在构造复杂区寻找原生型海相油藏的信心。研究认为,近期海相勘探,围绕隆起斜坡部位勘探为主,主体勘探深度可以下移至9000m。  相似文献   

塔河油田十二区奥陶系油气分布规律及控制因素     

阳生国  王顺玉  明爽  邵晓州  吴小华  丁勇  陈红 《海相油气地质》2012,17(1):17-22

塔河油田十二区奥陶系油藏为碳酸盐岩岩溶缝洞型油藏,油气水分布规律复杂。对原油的物理性质、平面及纵向上的分布特征、油水界面等的分析表明,区内主要为高黏度、含蜡、高含硫的超重质原油。平面上密度分布呈西部和东部低、中部高的特点;纵向上原油密度与深度关系不大。高产油区多沿主断裂带分布。油水界面不统一,但从东向西随中奥陶统顶面的降低而降低。认为该区油气分布不受现今构造位置高低的控制,而是受区域构造背景、断裂带的分布、储集层的发育程度、成藏演化过程以及不整合面等因素综合控制。  相似文献   

川北中三叠统沉积层序特征及陡坡封闭型镶边台地模式     

彭博  李国蓉  罗鹏  沈忠民  赵应权  姚尚胜 《海相油气地质》2012,(2):26-33

川北地区中三叠统层序地层学的对比研究表明,雷口坡组顶界面(T2/T1界面)和底界面(T3/T2界面)具有横向分异规律,由此识别出2个Ⅲ级层序,其上部SQ2层序普遍缺失高水位体系域。层序地层格架内的岩相古地理分析表明,该区中三叠世长期处于蒸发台地、局限台地环境,碳酸盐岩颗粒结构欠发育,可见少量藻屑颗粒灰岩和白云岩、细—中晶白云岩,缺少生物礁标志,藻席大量发育,白云石化作用强烈。识别出了工农镇剖面斜坡角砾,并对台地边缘位置进行了厘定。根据沉积及岩石学研究结果,得出了川北地区中三叠统典型的陡坡封闭型镶边台地模式。  相似文献   

Cotton Fiber/ZrO2, A New Material for Adsorption of Cr(VI) Ions in Water     

Alfredo Alberto Muxel  Sonia Maria Nobre Gimenez  Flaveli Aparecida de Souza Almeida  Rení Ventura da Silva Alfaya  Antonio Alberto da Silva Alfaya 《洁净——土壤、空气、水》2011,39(3):289-295

The natural cotton fiber was used to synthesize an anion exchange, containing ZrO₂ film on its surface, NCFZC (natural cotton fiber/ZrO₂ composite). This anion exchanger was produced by the reaction of the zirconium oxychloride and hydroxyl groups on surface of the natural cotton fiber. The material was used for Cr(VI) ions adsorption studies. Adsorption equilibrium time and optimum pH for Cr(VI) adsorption were found to be 6 h and 4.0, respectively. The Langmuir and Temkin isotherms were used to models adsorption equilibrium data. The adsorption capacity of NCFZC was found to be 1.33 mmol/g. Kinetic studies showed that the rate of adsorption of Cr(VI) on NCFZC obeyed a pseudo‐second‐order kinetic model.  相似文献   

复杂地区油气地球物理勘探技术集成   总被引：6，自引：0，他引：6       下载免费PDF全文

张春贺  乔德武  李世臻  张颖  杨辉  胡来东  尚应军  徐雷良  柴继堂  谭捍东  刘劲松 《地球物理学报》2011,54(2):374-387

随着我国油气勘探程度的不断提高,勘探难度不断加大.全国油气资源战略选区调查与评价项目历经六年,通过对深水海域、西部复杂山地、西藏高原、南方碳酸盐岩、火山岩覆盖区等几类典型地球物理勘探久攻不克的复杂地区开展地震、重磁电、综合地球物理勘探联合攻关,以及天然地震层析成像攻关实验,取得了长足进步,直接带动获得了一批有价值的油气...  相似文献   

Determination of arsenic concentration and distribution in the Floridan Aquifer System     

T. Pichler  R. Price  O. Lazareva  A. Dippold 《Journal of Geochemical Exploration》2011,111(3):84-96

Here we report on the different sampling strategies for almost seven years of sampling rocks/sediments for the determination of As within the Intermediate Aquifer System (IAS) and upper Floridan Aquifer System (FAS), a very large and productive limestone aquifer spanning from Georgia into Florida. In the FAS, As contamination has become a recurring problem during aquifer storage and recovery (ASR), particularly in central and south Florida.To investigate these phenomena, samples from solid drill cores and rock cuttings were collected from the Hawthorn Group, Suwannee Limestone, Ocala Limestone and Avon Park Formation. Samples were taken along drill cores and rock cuttings (referred to as ‘interval’ samples) or from particular drill core sections and rock cuttings (referred to as ‘targeted’ samples) likely to contain elevated concentrations of As as indicated by the presence of pyrite, hydrous ferric oxide, organic matter, clay minerals, fracture surfaces, and high permeable (moldic) zones.Arsenic was present in all of the stratigraphic units at low concentrations, close to the global average for As in limestone of 2.6 mg/kg. The highest As concentration was 69 mg/kg. In all units, however, the average bulk As concentration in the targeted samples was substantially higher than that in the interval samples. Based on direct spot measurements by electron microprobe and indirect calculations, pyrite was identified as the main source of As in the FAS. Concentrations in pyrite ranged from less than 100 mg/kg to more than 11,000 mg/kg. Because pyrite is heterogeneously distributed, both vertically and horizontally in the sampled stratigraphic units, the same was observed for the distribution of As. However, As concentrations generally decreased with depth, i.e., highest As values in the Hawthorn Group and lowest As values in the Ocala Limestone and Avon Park Formation. Compared to pyrite, other trace minerals contained much less As.The average As concentrations of the two types of sample media (solid cores and rock cuttings) were quite similar. These results indicate that if simply the average bulk rock As concentration of a geologic unit is the desired outcome of an investigation, either interval or targeted sampling of rock cuttings, seems to be sufficient. This is particularly important when time and money are a factor. This approach could work equally well for any other trace element. Structural sedimentary information, such as fractures, etc., is likely lost, however, when sampling rock cuttings. Thus, if this information is required, solid core samples need to be collected by hollow core diamond drilling.  相似文献   

碳酸盐岩成岩相研究方法及其应用——以扬子地块北缘飞仙关组鲕滩储层为例   总被引：1，自引：0，他引：1  

杨威  魏国齐  金惠  沈珏红 《岩石学报》2011,27(3):749-756

成岩相是研究成岩作用展布的重要方法和途径,其与沉积相不同,反映岩石在一定的成岩环境下发生的各种成岩作用的综合表现。在详细的成岩作用和成岩环境研究的基础上,划分了扬子地块北缘地区飞仙关组8类成岩相、7类成岩亚相,总结了各类成岩相(亚相)的识别标志,探索了成岩相与沉积相、测井相、地震相的关系,探索了成岩相在点、线、面上的分布,预测了有利成岩相区展布,取得了良好效果。形成了一套有效的成岩相研究方法,并将成岩相研究成果应用到勘探实践,具有较好的推广价值。  相似文献   

实验模拟碳酸盐岩储层包裹体对油气充注的响应   总被引：3，自引：0，他引：3  

葛云锦  陈勇  周瑶琪  周振柱 《地球科学进展》2011,26(10):1050-1056

设计了一系列不同油水比（3/7,5/5,7/39,/1）的实验,以冰洲石为主矿物合成了烃类包裹体,为探讨碳酸盐岩烃类流体包裹体的形成机制提供了一条有效途径。镜下观察及显微荧光分析发现：样品中合成的包裹体沿裂隙分布,表明微裂隙愈合过程中捕获包裹体,烃类和盐水包裹体既同时出现在同一裂隙中,又有分带出现的情况。样品中合成的烃...  相似文献