Modeling the Permeability Loss of Metallic Iron Water Filtration Systems     

Sabine Caré  Richard Crane  Paolo S. Calabrò  Antoine Ghauch  Emile Temgoua  Chicgoua Noubactep 《洁净——土壤、空气、水》2013,41(3):275-282

Over the past 30 years the literature has burgeoned with in situ approaches for groundwater remediation. Of the methods currently available, the use of metallic iron (Fe⁰) in permeable reactive barrier (PRB) systems is one of the most commonly applied. Despite such interest, an increasing amount of experimental and field observations have reported inconsistent Fe⁰ barrier operation compared to contemporary theory. In the current work, a critical review of the physical chemistry of aqueous Fe⁰ corrosion in porous media is presented. Subsequent implications for the design of Fe⁰ filtration systems are modeled. The results suggest that: (i) for the pH range of natural waters (>4.5), the high volumetric expansion of Fe⁰ during oxidation and precipitation dictates that Fe⁰ should be mixed with a non‐expansive material; (ii) naturally occurring solute precipitates have a negligible impact on permeability loss compared to Fe⁰ expansive corrosion; and (iii) the proliferation of H₂ metabolizing bacteria may contribute to alleviate permeability loss. As a consequence, it is suggested that more emphasis must be placed on future work with regard to considering the Fe⁰ PRB system as a physical (size‐exclusion) water filter device.  相似文献   

Ecological Risk Assessment of Benzo[a]pyrene in Yellow River Delta     

Qin Jin  Qunou Jiang  Feng Wu  Xing Li  Xiangzheng Deng 《洁净——土壤、空气、水》2013,41(4):370-376

Ecological risk assessment is of great significance to promoting the rational management effectively for the oil‐polluted areas. A comprehensive evaluation method of ecological risk, including probabilistic risk assessment and regional ecological risk assessment, is developed through employing the contaminant benzo[a]pyrene as an indicator to assess ecological risk of five oil mining plots, respectively in Yellow River Delta. In this study, firstly we evaluate the ecological risk probability of five oil mining plots using overlapping area of probabilistic curves, and the results show that local ecological risk varies between the maximum 0.4 and the minimum 0.01. Then we overlay boundaries of five administrative divisions in Yellow River Delta and the spatial distribution patterns of ecosystems to generate new risk receptor plaques, and calculate the integrated value of 30 specifically classified plaques for comprehensive evaluation of ecological risk. The results, fluctuating within the range of 0.00005 and 0.25, indicate that local government should be vigilant to ecological risk of benzo[a]pyrene to some extent, although the current situation is not severe in whole.  相似文献   

济南市土壤重金属污染现状及其土壤生物学表征   总被引：2，自引：0，他引：2       下载免费PDF全文

王存龙董志成  夏学齐郭卫华蒋文惠  季顺乐 《中国地质》2012,39(3):818-826

以济南市区及郊区农田土壤为对象,研究土壤中重金属污染的特征,结果表明,土壤重金属污染不仅引起了生态环境的恶化,而且影响土壤生物多样性,降低了土壤活性。济南市土壤动物各类群的数量与土壤重金属元素含量的相关性统计结果显示:土壤原生动物数量与Co、Ni含量呈明显负相关;土壤线虫数量与Cu、Mo含量呈显著负相关;旱生土壤动物数量与Cu含量呈显著负相关;说明重金属元素对土壤动物多样性具有不利影响,土壤线虫是耐污种类,旱生动物多为不耐污种类,土壤线虫与旱生动物密度之比可以作为土壤重金属污染程度的生物学指标。通过对土壤地球化学元素含量与土壤生物学参数的相关性分析,找到了重金属的敏感生物指标:Pb污染的生物学指标为土壤线虫;As污染的生物学指标是真菌PLFA含量等,用土壤生物作为敏感、快速的重金属污染生物毒性的指示物,具有广阔的应用前景。  相似文献   

湖南株洲地区Cd、Pb污染土壤的修复实验     

廖立兵  姜浩  梁树平  龙梅  王军玲  杜高翔  何茂乾 《矿物学报》2012,32(1):151-155

以海泡石、膨润土和生石灰为修复材料,对湖南株洲地区重金属元素Cd、Pb污染农田土壤进行了室内修复实验。盆栽小白菜的正交实验结果表明,对于Cd含量为1.23 mg/kg、Pb含量为136.7 mg/kg的土壤,当每10 kg土壤添加膨润土60 g、海泡石20 g、石灰6 g时,种植的小白菜中Cd含量为0.154 mg/kg,Pb含量为0.141mg/kg。与未修复土壤的实验结果对比,小白菜中Cd含量降低61%,Pb含量降低46%。  相似文献   

济南破损山体概况及生态修复技术研究     

赵入臻  赵鹏  赵环金 《山东地质》2012,(9):31-36

城市破损山体不仅造成了大量陡坡岩面裸露,恶化了城市自然生态环境,而且还带来了坍塌、滑坡等安全隐患,是城市建设发展中亟待解决的问题。该文首先对济南城市破损山体现状及修复情况进行了调查分析,结合破损山体具体的生态修复工程实例,较详细总结研究了破损山体生态修复的技术和方法。经过几年的生态修复建设与养护管理,济南破损山体的生态景观功能得到了极大的恢复提升,该文筛选总结出的台地续坡式等治理方式及挂网喷播等生态修复技术,可为类似破损山体的生态修复提供借鉴。  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987111001320   总被引：1，自引：1，他引：0  

Weiguo Hou  Bin Lian  Hailiang Dong  Hongchen Jiang  Xingliang Wu 《地学前缘(英文版)》2012,3(3):351-356

Ectomycorrhizal fungi,a group of widcspread symbiotic fungi with plant,obtain carbon source from trees and improve plant mineral nutrient uptake with their widespread hyphal network.Ectomycorrhizal fun...  相似文献   

Ecological quality assessment of small estuaries from the Portuguese coast based on fish assemblages indices     

Cardoso I  Pais MP  Henriques S  da Fonseca LC  Cabral HN 《Marine pollution bulletin》2011,62(5):992-1001

The importance of establishing the ecological quality of estuarine systems has been widely acknowledged and led to the development of several fish community-based multimetric indices. Nevertheless, a question rose about the accuracy of these tools when natural disturbance is acting upon the organization of the systems’ communities. Four multimetric indices were used to examine their ability to differentiate the ecological status of five small estuarine systems (southern Portugal), and also to test if they reflected the level of anthropogenic pressures. Fish assemblages from Mira, Odeceixe and Aljezur (in the Southwest coast), Gilão and Bensafrim (in the South coast) estuaries were sampled seasonally for one year, and anthropogenic sources of pressure were identified and quantified. We found that although the applied indices provided information on ecological condition differentiation among systems, they are unable to explain different classes of ecological status in systems with equivalent pressure levels.  相似文献   

Critical appraisal on the identification of Reference Conditions for the evaluation of ecological quality status along the Emilia-Romagna coast (Italy) using M-AMBI   总被引：1，自引：0，他引：1  

Paganelli D  Forni G  Marchini A  Mazziotti C  Occhipinti-Ambrogi A 《Marine pollution bulletin》2011,62(8):1725-256

According to the European Water Framework Directive, the ecological status (ES) of a water body is determined by comparing observation data with undisturbed Reference Conditions (RCs). Defining RCs is crucial when evaluating the ES of a water body as it strongly affects the final outcome of any index application. Identifying RCs by observing real sites is not feasible in many marine environments, such as the Emilia-Romagna coast (Italy, N-Adriatic Sea). We used a statistical approach on a large dataset to derive RCs for the application of the benthic index M-AMBI in this area. We then applied M-AMBI to samples collected along a gradient of presumed environmental disturbance. The results put 14.8% of the Emilia-Romagna samples in “High” ES, 60.2% in “Good”, 23.0% in “Moderate” and 2.0% in “Poor”, showing a spatial gradient of improving quality. These results are in agreement with the extensive ecological knowledge available for this area.  相似文献   

Modeling discrete gas bubble formation and mobilization during subsurface heating of contaminated zones     

Magdalena M. Krol 《Advances in water resources》2011,34(4):537-549

During thermal remediation the increase in subsurface temperature can lead to bubble formation and mobilization. In order to investigate the effect of gas formation on resulting aqueous concentrations, a 2D finite difference flow and mass transport model was developed which incorporates a macroscopic invasion percolation (MIP) model to simulate bubble expansion and movement. The model was used to simulate three soil scenarios with different permeabilities and entry pressures at various operating temperatures and groundwater velocities. It was observed that discrete bubble formation occurred in all three soils, upward mobility being limited by lower temperatures and higher entry pressures. Bubble mobilization resulted in a different aqueous mass distribution than if no discrete gas formation was modeled, especially at higher temperatures. This was a result of bubbles moving upwards to cooler areas, then collapsing, and contaminating previously clean zones. The cooling effect also led to possible non-aqueous phase liquid (NAPL) formation which was not predicted using a model without discrete bubble formation.  相似文献