Measurements of tropospheric OH concentrations: A comparison of field data with model predictions     

D. Perner  U. Platt  M. Trainer  G. Hübler  J. Drummond  W. Junkermann  J. Rudolph  B. Schubert  A. Volz  D. H. Ehhalt  K. J. Rumpel  G. Helas 《Journal of Atmospheric Chemistry》1987,5(2):185-216

Using long path UV absorption spectroscopy we have measured OH concentrations close to the earth's surface. The OH values observed at two locations in Germany during 1980 through 1983 range from 0.7×10⁶ to 3.2×10⁶ cm^-3. Simultaneously we measured the concentrations of O₃, H₂O, NO, NO₂, CH₄, CO, and the light non methane hydrocarbons. We also determined the photolysis rates of O₃ and NO₂. This allows calculations of OH using a zero dimensional time depdendent model. The modelled OH concentrations significantly exceed the measured values for low NO _x concentrations. It is argued that additional, so far unidentified. HO _x loss reactions must be responsible for that discrepancy.  相似文献   

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定     

肖德明  甘璇玑  卜正才 《铀矿地质》1986,(4)

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

小秦岭石英脉（构造带）含金性评价的包裹体指标研究     

卿敏  白万成 《黄金地质》1995,1(3):54-60

选择了小秦岭含金石英脉脉石英的显微镜下特征、红外光谱及近脉（矿）围岩全岩爆裂温测等３种包裹体研究方法，对比研究了东闯金、铅矿区和杨砦峪矿区不同含金性石英脉、含矿脉中的富矿、贫矿地段及矿体不同部位的包裹体特征，提出出了石英脉含金性评价及差别矿体剥蚀程度的包裹体指标。  相似文献   

赤砂沸石对氮磷钾吸附与释放的研究     

胡预生  马友华  周自默 《安徽地质》1995,(4)

本文以安徽省繁昌县赤砂沸石为试验材料，以黄红壤为参照，研究了丝光沸石为主的天然沸石对ＮＨ、Ｈ＿２ＰＯ及Ｋ￣＋的吸附与释放，结果表明：赤砂沸石的吸铵量和吸磷量为黄红壤的３倍；其中易释放铵和可释放铵占总吸铵量８０％以上；易释放磷和可释放磷占７０％以上；赤砂沸石的速效钾含量为黄红壤的７倍左右，而钾位缓冲容量（ＰＢＣ￣Ｋ）则为黄红壤的３５倍左右。赤砂沸石用做肥料调理剂和土壤改良剂，将能够减少土壤中氮、磷、钾的流失，并提高肥料中养分的利用率。  相似文献   

Ultraviolet absorption spectra of some Br-containing haloalkanes     

V. L. Orkin  E. E. Kasimovskaya 《Journal of Atmospheric Chemistry》1995,21(1):1-11

The ultraviolet absorption cross sections were measured for CF₃Br, CF₂ClBr, CF₂Br-CF₂Br, CF₂Br₂, CHF₂Br, CHFBr-CF₃, CH₂Br-CF₃, CHClBr-CF₃ in the wavelength range 190–320 nm at 295 K. The photolysis is concluded to be the minor atmospheric sink for CHF₂Br, CHFBr-CF₃, CH₂Br-CF₃, CHClBr-CF₃.  相似文献   

大气中微量气体的红外吸收          下载免费PDF全文

王松皋  张广顺 《应用气象学报》1995,6(1):70-75

文章介绍了测定大气中微量气体CO2与CH4透过率的试验。所用的主要设备是FTIR分光计及可变光程吸收池。文中叙述了主要实验结果与数据处理方法，同时用FASCODE-2程序计算了对应实验条件下CO2与CH4的透过率，并与实验结果作了比较。  相似文献   

Coda waves: A review     

M. Herraiz  A. F. Espinosa 《Pure and Applied Geophysics》1987,125(4):499-577

The analysis and interpretation of coda waves have received increasing attention since the early seventies. In the past few years interest in this subject has spread worldwide, and the study of high-frequency seismic coda waves has become a very important seismological topic. As a conclusion of the studies accomplished in this time, coda waves are considered the result of scattering processes caused by heterogeneities acting on seismic waves.P andS waves play a particularly important role in this interaction. The process introduces an attenuation which, added to the intrinsic absorption, gives the observed apparent attenuation. Therefore, coda waves constitute a thumbprint left by the heterogeneities on the seismograms. Coda waves offer decisive information about the mechanism of how scattering and attenuation take place. This review describes coda waves in detail, and summarizes the work done in this subject to 1986. The relation between coda waves and attenuation in the context of research on seismic scattering problems is stressed. Particular attention has been given to the application of coda waves to estimate source and medium parameters. The state-of-the-art of the temporal variations of coda wave shape, and the possible use of these variations as an earthquake precursor also are presented. Care has been taken to introduce the statistical models used to deal with the heterogeneities responsible for scattering.  相似文献   

镉—5—Br—PADAP—溴化十六烷基三甲基铵—十八醇聚氧乙烯(20)醚显色体系的研究及应用     

周发连  周文 《华东地质学院学报》1987,(1)

本文研究了镉-5-Br-PADAP-溴化十六烷基三甲基铵-peregalo显色体系的光谱特征,显色条件,络合物的组成、干扰及其消除。实验证明该法灵敏度高,ε=1.3×10~5l·mol~(-1)·cm~(-1)。选择性较好,显色酸度范围较宽pH=8.0-9.5,络合物最大吸收波长为560nm,镉在0-10μg/25ml的含量范围内服从比尔定律。经标准水样、工业废水及生活用水验证,不经分离可测定水中PPb级的微量镉。  相似文献   

滇东-黔西地区晚二叠世煤岩及煤层气储层物性分析   总被引：3，自引：0，他引：3  

顾成亮 《贵州地质》2001,18(3):163-167,148

本文以丰富的地质资料对滇东－黔西地区晚二叠世煤岩分布的割理（裂隙）,吸附、孔隙溶积、镜质组含量、含气性、灰分产率等进行了较为系统的研究,初步建立了煤炭与煤层气储层物性的关系,提出了镜质组含量的煤炭类型有较好的煤层气储集物性条件。  相似文献   

IAP AGCM中短波辐射方案的改进研究II·短波辐射方案的改进     

张凤  曾庆存 《气候与环境研究》2005,(3)

在Version 2的基础上,对短波辐射方案进行进一步的改进:引入了新增非灰体气体吸收效应、冰晶粒子形状效应和尺度效应以及云的不均匀性效应(称为Version 3)。数值模拟试验结果表明:Version 3能更好地模拟出全球冬、夏季的降水场、海平面气压场及地表气温场的主要分布特征,并且能相当准确地反映出这几个场的季节性变化特征。Version 3对这3个场的模拟能力明显优于原版本(Version 1)。此外,它对东亚地区的季风降雨具有很好的模拟能力,能较好地反映东亚区域降水的季节性变化。可见,Version 3为进一步研究云-辐射相互作用提供了很好的模式基础。本工作还清楚地表明,模式的进一步发展必须进行对相关物理过程中各个因子的更精确刻画,只有这样,模式才能得到更好的模拟能力。  相似文献