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71.
Carbonyl products have been identified and their formation yields measured in experiments involving the gas phase reaction of ozone with 1,1-disubstituted alkenes at ambient T and p=1 atm. of air. Sufficient cyclohexane was added to scavenge the hydroxyl radical in order to minimize OH-alkene and OH-carbonyl reactions. Formation yields (carbonyl formed/ozone reacted) of primary carbonyls were close to the value of 1.0 that is consistent with the mechanism: O3+R1R2C=CH2 (HCHO+R1R2COO)+(1–)(R1COR2+H2COO) where formaldehyde and the ketone R1 COR2 are the primary carbonyls and R1R2COO and H2COO are the corresponding biradicals. Measured values of were 0.58–0.82 and indicate modest preferential formation of formaldehyde and the disubstituted biradical as compared to the ketone and the biradical H2COO. Carbonyls other than the primary carbonyls were identified. Their formation is discussed in terms of subsequent reactions of the disubstituted biradicals R1R2COO. Similarities and differences between disubstituted and monosubstituted biradicals are outlined. 相似文献
72.
73.
The scope of the present paper is to provide analytic solutions to the problem of the attitude evolution of a symmetric gyrostat about a fixed point in a central Newtonian force field when the potential function isV
(2).We assume that the center of mass and the gyrostatic moment are on the axis of symmetry and that the initial conditions are the following: (t
0)=0, (t
0)=0, (t
0)=(t
0)=0, 1(t
0)=0, 2(t
0)=0 and 3(t
0)=
3
0
.The problem is integrated when the third component of the total angular momentum is different from zero (B
1 0). There now appear equilibrium solutions that did not exist in the caseB
1=0, which can be determined in function of the value ofl
3
r
(the third component of the gyrostatic momentum).The possible types of solutions (elliptic, trigonometric, stationary) depend upon the nature of the roots of the functiong(u). The solutions for Euler angles are given in terms of functions of the timet. If we cancel the third component of the gyrostatic momentum (l
3
r
=0), the obtained solutions are valid for rigid bodies. 相似文献
74.
75.
目的:基于网络药理学与分子对接技术探讨青蛇方外用治疗湿疹的作用机制。方法:应用TCMSP和UniProt数据库平台查询青蛇方组方的有效活性成分及靶基因,与疾病靶基因取交集后构建蛋白质-蛋白质相互作用(PPI)网络;应用DAVID数据库,对潜在核心作用靶点基因进行基因本体(GO)功能、京都基因与基因组百科全书(KEGG)通路富集分析。利用分子对接原理论证青蛇方生物活性成分与核心靶点的分子结合能力。结果:筛选出青蛇方有效成分63种,作用靶点99个;主要有β-谷甾醇、2,4,7-三羟基-9,10-二氢菲、靛蓝素、豆甾醇、色氨酸等关键成分;转录因子AP-1(JUN)、肿瘤坏死因子(TNF)、原癌基因(RELA)、干扰素γ(IFNG)、转化生长因子-β1(TGF-β1)等核心基因。关键信号通路有癌症信号通路、恰加斯病通路、弓形体病通路、脂质和动脉粥样硬化通路等,分子对接结果显示活性成分与核心靶点基因结合能力较强。结论:青蛇方外用可以通过多种活性成分、多种通路有效抑制免疫炎症反应,促进免疫系统正常运行,从而达到治疗湿疹的目的。 相似文献
76.
Onthespatialcharacteristicoftheshort┐termandimminentanomaliesofundergroundwaterbehaviorsbeforestrongearthquakeXUE-BINDU(杜学彬)... 相似文献
77.
78.
洛安江水库灌溉工程是贵州黔北万亩以上骨干工程之一,中华人民共和国成立初期建成。1991年"7.5F"洪灾,连续大暴雨,河水暴涨,倒灌暗河,产生高静、动水压力作用。岸坡岩体受不利结构面组合,发生顺层岩质滑坡,破坏干渠,严重影响灌溉。本文根据滑坡破坏情况,对滑坡产生的地质环境、滑坡特征、滑坡形成机理(滑坡形式和破坏机理,各种稳定性分析与评价),以及产生滑坡原因进行了初步分析。 相似文献
79.
Makhlouf Amar 《Celestial Mechanics and Dynamical Astronomy》1991,52(4):397-406
We consider the Hill's equation: % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGGipm0dc9vqaqpepu0xbbG8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaWaaSaaaeaaca% WGKbWaaWbaaSqabeaacaaIYaaaaOGaeqOVdGhabaGaamizaiaadsha% daahaaWcbeqaaiaaikdaaaaaaOGaey4kaSYaaSaaaeaacaWGTbGaai% ikaiaad2gacqGHRaWkcaaIXaGaaiykaaqaaiaaikdaaaGaam4qamaa% CaaaleqabaGaaGOmaaaakiaacIcacaWG0bGaaiykaiabe67a4jabg2% da9iaaicdaaaa!4973!\[\frac{{d^2 \xi }}{{dt^2 }} + \frac{{m(m + 1)}}{2}C^2 (t)\xi = 0\]Where C(t) = Cn (t, {frbuilt|1/2}) is the elliptic function of Jacobi and m a given real number. It is a particular case of theame equation. By the change of variable from t to defined by: % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGGipm0dc9vqaqpepu0xbbG8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaqcaawaaOWaaiqaaq% aabeqaamaalaaajaaybaGaamizaGGaaiab-z6agbqaaiaadsgacaWG% 0baaaiabg2da9OWaaOaaaKaaGfaacaGGOaqcKbaG-laaigdajaaycq% GHsislkmaaleaajeaybaGaaGymaaqaaiaaikdaaaqcaaMaaeiiaiaa% bohacaqGPbGaaeOBaOWaaWbaaKqaGfqabaGaaeOmaaaajaaycqWFMo% GrcqWFPaqkaKqaGfqaaaqcaawaaiab-z6agjab-HcaOiab-bdaWiab% -LcaPiab-1da9iab-bdaWaaakiaawUhaaaaa!51F5!\[\left\{ \begin{array}{l}\frac{{d\Phi }}{{dt}} = \sqrt {(1 - {\textstyle{1 \over 2}}{\rm{ sin}}^{\rm{2}} \Phi )} \\\Phi (0) = 0 \\\end{array} \right.\]it is transformed to the Ince equation: (1 + · cos(2)) y + b · sin(2) · y + (c + d · cos(2)) y = 0 where % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGGipm0dc9vqaqpepu0xbbG8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaqcaawaaiaadggacq% GH9aqpcqGHsislcaWGIbGaeyypa0JcdaWcgaqaaiaaigdaaeaacaaI% ZaGaaiilaiaabccacaWGJbGaeyypa0Jaamizaiabg2da9aaacaqGGa% WaaSaaaKaaGfaacaWGTbGaaiikaiaad2gacqGHRaWkcaaIXaGaaiyk% aaqaaiaaiodaaaaaaa!4777!\[a = - b = {1 \mathord{\left/{\vphantom {1 {3,{\rm{ }}c = d = }}} \right.\kern-\nulldelimiterspace} {3,{\rm{ }}c = d = }}{\rm{ }}\frac{{m(m + 1)}}{3}\]In the neighbourhood of the poles, we give the expression of the solutions.The periodic solutions of the Equation (1) correspond to the periodic solutions of the Equation (3). Magnus and Winkler give us a theory of their existence. By comparing these results to those of our study in the case of the Hill's equation, we can find the development in Fourier series of periodic solutions in function of the variable and deduce the development of solutions of (1) in function of C(t). 相似文献
80.
J. Zahradník M. Antonini G. Grünthal J. Janský D. Procházková E. Schmedes A. Špičak J. Zedník 《Pure and Applied Geophysics》1990,133(1):53-71
The main shock of the West-Bohemian earthquake swarm, Czechoslovakia, (magnitudem=4.5, depthh=10 km) exhibits an irregular areal distribution of macroseismic intensities 6° to 7° MSK-64. Four lobes of the 6° isoseismal are found and the maximum observed intensity is located at a distance of 8 km from the instrumentally determined epicentre. This distribution can be explained by the energy flux of the directS wave generated by a circular source, the hypocentral location and focal mechanism of which are taken from independent instrumental studies. The theoretical intensity, which is assumed to be logarithmically proportional to the integrated squared ground-motion velocity (i.e.,I=const+log v
2
(t)dt), fits the observed intensity with an overall root-mean-square error less than 0.5°. It is important that the present intensity data can also be equally well explained by the isotropic source. The fit was attained by means of a horizontally layered model though large fault zones and an extended sedimentary basin suggest a significant lateral heterogeneity of the epicentral region. The results encourage a broader application of the simple modelling technique used. 相似文献