辽宁省积雪对自动气象站观测地气温差的影响     

朱玲  顾正强  龚强  晁华  李杨  徐红  周晓宇  沈历都  蔺娜 《冰川冻土》2019,41(2):293-303

利用1971—2016年辽宁省61个气象站气温、地表温度、积雪日数和积雪深度资料,分析了积雪的保温作用及其对地气温差的影响。结果表明：更换自动站前后地表温度观测方式的差异导致地气温差显著增大,地气温差的增大程度受所在区域积雪日数、积雪深度的影响显著。在积雪期较长、积雪较厚的地区,积雪引起反照率增大,使得雪面温度降低,导致雪气温差减小,而雪的保温作用使得地气温差显著增大。因此,更换自动站前地（雪）气温差与积雪日数呈显著负相关,而更换自动站后地气温差与积雪日数呈显著正相关。各台站之间地气温差随积雪深度的变化系数差异较大,为0.045~0.858 ℃?cm^-1,在年平均积雪日数＜40 d、年平均极端积雪深度＜10 cm的区域,积雪的保温作用随积雪深度增大而显著增大;在年平均积雪日数＞40 d、年平均极端积雪深度＞10 cm的区域,10 cm以下的积雪对土壤保温作用随积雪深度增大显著,当积雪深度＞10 cm后,其保温作用随积雪深度增大的幅度明显减小。  相似文献   

浅谈GPS在地质剖面测量中的应用及地质剖面绘制中的便捷方法     

张俭峰  李新鹏  杨文鹏  李成禄  邓昌州  赵瑞君 《世界地质》2019,(2):397-404

为提高森林沼泽景观浅覆盖区地质剖面测量的精度和效率,本文以黑龙江省呼玛县早侏罗世正长花岗岩剖面测量为例,探讨利用GPS测量技术进行地质剖面测量的方法和流程。结果表明,利用GPS工具,通过室内数据准备-野外GPS数据采集-室内数据处理-剖面图的生成等流程,并结合SECTION软件及EXCEL软件,可以避免视野通透性差、测量路线障碍物多、地形复杂等许多不利因素,以较小的误差较快的速度实现地质剖面测量。  相似文献   

‘Box‐Profile’ Ion Implants as Geochemical Reference Materials for Electron Probe Microanalysis and Secondary Ion Mass Spectrometry     

Haosheng Wu  Roman Bttger  Frdric Couffignal  Jens Gutzmer  Joachim Krause  Frans Munnik  Axel D. Renno  Ren Hübner  Michael Wiedenbeck  Ren Ziegenrücker 《Geostandards and Geoanalytical Research》2019,43(4):531-541

Although electron probe microanalysis and secondary ion mass spectrometry are widely used analytical techniques for geochemical and mineralogical applications, metrologically rigorous quantification remains a major challenge for these methods. Secondary ion mass spectrometry (SIMS) in particular is a matrix‐sensitive method, and the use of matrix‐matched reference materials (RMs) is essential to avoid significant analytical bias. A major problem is that the number of available RMs for SIMS is extremely small compared with the needs of analysts. One approach for the production of matrix‐specific RMs is the use of high‐energy ion implantation that introduces a known amount of a selected isotope into a material. We chose the more elaborate way of implanting a so‐called ‘box‐profile’ to generate a quasi‐homogeneous concentration of the implanted isotope in three dimensions, which allows RMs not only to be used for ion beam analysis but also makes them suitable for EPMA. For proof of concept, we used the thoroughly studied mineralogically and chemically ‘simple’ SiO₂ system. We implanted either ⁴⁷Ti or ⁴⁸Ti into synthetic, ultra‐high‐purity silica glass. Several ‘box‐profiles’ with mass fractions between 10 and 1000 μg g^?1 Ti and maximum depths of homogeneous Ti distribution between 200 nm and 3 μm were produced at the Institute of Ion Beam Physics and Materials Research of Helmholtz‐Zentrum Dresden‐Rossendorf. Multiple implantation steps using varying ion energies and ion doses were simulated with Stopping and Range of Ions in Matter (SRIM) software, optimising for the target concentrations, implantation depths and technical limits of the implanter. We characterised several implant test samples having different concentrations and maximum implantation depths by means of SIMS and other analytical techniques. The results show that the implant samples are suitable for use as reference materials for SIMS measurements. The multi‐energy ion implantation technique also appears to be a promising procedure for the production of EPMA‐suitable reference materials.  相似文献   

Basaltic and Solution Reference Materials for Iron,Copper and Zinc Isotope Measurements     

Jin Li  Suo‐han Tang  Xiang‐kun Zhu  Zhi‐hong Li  Shi‐Zhen Li  Bin Yan  Yue Wang  Jian Sun  Yao Shi  Aiguo Dong  Nick S. Belshaw  Xingchao Zhang  Sheng‐ao Liu  Ji‐hua Liu  Deli Wang  Shao‐yong Jiang  KeJun Hou  Anthony S. Cohen 《Geostandards and Geoanalytical Research》2019,43(1):163-175

Iron, Cu and Zn stable isotope systems are applied in constraining a variety of geochemical and environmental processes. Secondary reference materials have been developed by the Institute of Geology, Chinese Academy of Geological Sciences (CAGS), in collaboration with other participating laboratories, comprising three solutions (CAGS‐Fe, CAGS‐Cu and CAGS‐Zn) and one basalt (CAGS‐Basalt). These materials exhibit sufficient homogeneity and stability for application in Fe, Cu and Zn isotopic ratio determinations. Reference values were determined by inter‐laboratory analytical comparisons involving up to eight participating laboratories employing MC‐ICP‐MS techniques, based on the unweighted means of submitted results. Isotopic compositions are reported in per mil notation, based on reference materials IRMM‐014 for Fe, NIST SRM 976 for Cu and IRMM‐3702 for Zn. Respective reference values of CAGS‐Fe, CAGS‐Cu and CAGS‐Zn solutions are as follows: δ⁵⁶Fe = 0.83 ± 0.07 and δ⁵⁷Fe = 1.20 ± 0.13, δ⁶⁵Cu = 0.57 ± 0.06, and δ⁶⁶Zn = ?0.79 ± 0.12 and δ⁶⁸Zn = ?1.65 ± 0.24, respectively. Those of CAGS‐Basalt are δ⁵⁶Fe = 0.15 ± 0.07, δ⁵⁷Fe = 0.22 ± 0.10, δ⁶⁵Cu = 0.12 ± 0.08, δ⁶⁶Zn = 0.17 ± 0.13, and δ⁶⁸Zn = 0.34 ± 0.26 (2s).  相似文献   

High‐Precision Measurement of 187Os/188Os Isotope Ratios of Nanogram to Picogram Amounts of Os in Geological Samples by N‐TIMS using Faraday Cups Equipped with 1013 Ω Amplifiers     

Guiqin Wang  Hauke Vollstaedt  Jifeng Xu  Wengui Liu 《Geostandards and Geoanalytical Research》2019,43(3):419-433

N(¹⁸⁷Os)/N(¹⁸⁸Os) ratios of six geological reference materials were measured using static Faraday cups (FCs) with 10¹³ Ω amplifiers by N‐TIMS. Our results show that the repeatability precision was 2–3‰ (2 RSD, n = 3), when taking ~ 1 g of BHVO‐2 with 76 pg g^?1 of Os mass fraction and ~ 2 g of BCR‐2 with 21 pg g^?1 of Os mass fraction for each sample, whether measured by FCs or by secondary electron multiplier. The repeatability precision measured by FCs was 1–0.2‰ (2 RSD, n = 3) when taking ~ 1 g of BIR‐2 with 350 pg g^?1 of Os mass fraction, ~ 1 g of WGB‐1 with 493 pg g^?1 of Os mass fraction or ~ 0.5 g of WPR‐1 with 13.3 ng g^?1 of Os mass fraction for each sample, which is much better than those measured by secondary electron multiplier. Instead, when taking ~ 2 g of AGV‐2 with 4 pg g^?1 Os mass fraction, the repeatability precision measured by secondary electron multiplier is 3–4‰ (RSD, n = 3), which is better than those measured by FCs. Of the six reference materials analysed, WPR‐1 and BIR‐1a are the most homogeneous with regard to Os isotopic composition (2 RSD of 0.08% and 0.23%, respectively) when test portion masses are 0.5–1 g.  相似文献   

Comment on: Mass Fractions of Forty‐Six Major and Trace Elements,Including Rare Earth Elements,in Sediment and Soil Reference Materials Used in Environmental Studies. Fiket et al. (2017), Geostandards and Geoanalytical Research, 41, 123–135     

Vibor Roje 《Geostandards and Geoanalytical Research》2019,43(2):317-327

This paper is intended to be a constructive discussion of Fiket et al. (2017, Geostandards and Geoanalytical Research , 41 , 123–135), who dealt with the determination of major, trace and rare earth elements in several sediment and soil certified reference materials. In the present author's view, the paper by Fiket et al. (2017) suffers from a lack of reference to several publications in which somewhat similar results had already been reported. The present contribution therefore provides a comparison of previously published results with those of Fiket et al. for the CRMs soil NCS DC 77302 (GBW 07410), stream sediment NCS DC 73309 (GBW 07311), marine sediments MESS‐3 and NCS DC 75301 (GBW 07314) and estuarine sediment IAEA‐405. It is argued that this fuller consideration (a) allows critical evaluation of the quality of the results presented by Fiket et al. and (b) highlights the advantages of their work. Finally, attention is drawn to the (possible or real) problems that can arise during simultaneous determination of multiple trace elements.  相似文献   

Duluth Complex apatites: Age reference material for LA–ICP–MS‐based fission‐track dating     

Hideki Iwano  Tohru Danhara  Takashi Yuguchi  Takafumi Hirata  Masatsugu Ogasawara 《地学学报》2019,31(3):247-256

Anorthositic series apatites of the Duluth Complex, Minnesota, USA, have high spontaneous fission‐track densities of up to ~10⁷ cm^–2 and a homogeneous age of ~900 Ma, allowing high‐precision fission‐track dating based on LA–ICP–MS U analysis. Absolute fission‐track dating, track‐length measurement and chemical composition analysis were performed to evaluate a cooling history, which is essential for age reference materials. Preliminary inverse modelling for a sample with a shortened track‐length distribution yielded a monotonic cooling history from ~100°C at 925 Ma. The apatites incur an over‐etching problem when employing the commonly used etching protocol involving 5.5 M HNO₃.  相似文献   

区位因素影响下高铁站区产业结构特征——基于POI数据的实证分析     

王少剑  莫惠敏  吕慧妮  许佩瑶  殷海晴 《地理学报》2021,76(8):2016-2031

高铁站被视为拉动城市经济增长的新型空间,研究其周边产业结构对指导高铁站区的开发具有重要意义。本文选取了全国范围内9个不同区位、不同等级的高铁站为研究对象,以高铁站周边3000 m范围内10类产业的POI信息作为研究数据,通过Ripley's K函数、核密度估计和产业指数等方法探索不同区位下高铁站区的产业结构特征。研究发现：① 当高铁站的等级规模相同时,高铁站距离城市中心越远,站区内产业POI总数一般就越少。其中,购物服务、餐饮服务、生活服务和公司企业4类产业的POI数量显著高于其他产业。② 所有高铁站区的产业在1500 m的观测距离内均呈现出显著的集聚分布特征。其中,中心站产业集聚程度的变化较为平缓,城区站产业集聚程度最高,变化幅度也更大,而新城站的规律特征不明显。③ 中心站的产业集聚区域主要分布在高铁站周边0~2500 m的范围内,城区站的产业集聚现象在500~2500 m范围内较为明显,而新城站的产业集聚区域则集中在0~1500 m、2000~3000 m的范围以内。④ 基本服务产业和衍生服务产业主要集中于内圈层和中间圈层,相关服务产业则主要分布在中间圈层和外圈层,各圈层内产业复合特征明显,且高铁站越远离城市中心,其对产业的辐射作用越弱,产业衰减趋势也越明显。基于以上结论,本文认为未来高铁站区的产业开发更应关注土地开发集约化和产业发展复合化。  相似文献   

中国沿海海洋站GNSS坐标时间序列噪声模型的建立与分析     

金波文  王慧  刘玉龙  邓丽静  吕江华 《大地测量与地球动力学》2020,40(5):476-481

选取中国沿海海洋站中与验潮室并址的22个GNSS基准站近9 a的观测资料,利用最大似然估计法分析各站时间序列的噪声特性,建立最优噪声模型;然后顾及有色噪声,利用最优噪声模型估计测站速度,并与纯白噪声模型和GLOBK获取的速度及误差进行对比分析。结果表明：1）沿海海洋站的GNSS时间序列均含有有色噪声,各分量的噪声特性不完全一致,E方向和U分量均以白噪声+闪烁噪声为主,N分量以白噪声+闪烁噪声和白噪声+一阶马尔科夫噪声+随机漫步噪声为主。2）全国沿海3个海区N、E分量的白噪声和闪烁噪声基本呈现越往南噪声越大的规律,南海海区U分量的白噪声和闪烁噪声最大。3）顾及有色噪声的速度中误差是仅考虑白噪声和GLOBK估计的速度中误差估计值的5～10倍,这种差异比内陆观测站的要大。4）在对海洋站GNSS时间序列进行速度分析时,为获取正确的速度值,应该先准确判断噪声的类型,再顾及有色噪声的影响估计测站速度。  相似文献   

基于RegEM算法的GPS坐标时间序列插值应用分析     

王方超  吕志平  吕浩  邝英才 《大地测量与地球动力学》2020,40(1):45-50

将一种基于数据驱动的RegEM算法引入GPS坐标时间序列插值中,分别采用模拟不同比例连续缺失数据与实测含缺失数据,比较RegEM与拉格朗日方法、三次样条方法、正交多项式方法的插值效果与性能。结果表明,对于模拟不同比例连续缺失数据,RegEM算法插值效果均优于传统方法,且在大量数据连续缺失的情况下效果最优;对于实测含缺失数据,RegEM方法插值所得序列保留方差最大化效果最好,约为正交多项式方法的1.17倍、三次样条方法的1.38倍。  相似文献