清镇式铁矿矿石特征及加工技术性能探讨 ——以猫场铝土矿红花寨、白浪坝矿段铁矿床为例          下载免费PDF全文

杨明坤  张周位  杨国彬  李宏志  杨毕  苏亮广 《贵州地质》2019,36(1):95-100

贵州中部清镇、修文等地石炭系铝土矿底部的铁矿俗称为"清镇式铁矿",与黔中铝土矿共同赋存于下石炭统九架炉组之中。本文在实际勘探工作及通过勘探阶段在钻孔副样中采集的铁矿进行可选性试验基础上,以同类型的清镇市猫场铝土矿红花寨、白浪坝矿段铝土矿共生的铁矿为研究对象,指出该类型铁矿矿石自然类型为赤铁矿和褐铁矿;工业类型为需选铁矿石;矿石矿物主要为赤铁矿,部分赤铁矿水化为针柱状褐铁矿;脉石矿物则以白云石和方解石为主。矿石中可供利用的主要元素是铁,造渣组分主要是硅、铝,其次为钙、镁等。试验结果表明,该矿采用一粗一精一扫的强磁选试验可获得铁精矿TFe含量55. 58%,回收率80. 11%的良好指标,精矿中各元素含量达到H55-Ⅰ类赤铁精矿质量要求,在当前市场条件下采用推荐工艺处理该矿可获利。结论对黔中铝土矿资源的综合勘查开发具有借鉴意义。  相似文献   

Heating duration of igneous rim formation on a chondrule in the Northwest Africa 3118 CV3oxA carbonaceous chondrite inferred from micro-scale migration of the oxygen isotopes     

《Chemie der Erde / Geochemistry》2019,79(4):125524

Due to their common occurrence in various types of chondrites, igneous rims formed on pre-existing chondrules throughout chondrule-forming regions of the solar nebula. Although the peak temperatures are thought to reach similar values to those achieved during chondrule formation events, the heating duration in chondrule rim formation has not been well defined. We determined the two-dimensional chemical and oxygen isotopic distributions in an igneous rim of a chondrule within the Northwest Africa 3118 CV3_oxA chondrite with sub-micrometer resolution using secondary ion mass spectrometry and scanning electron microscopy. The igneous rim experienced aqueous alteration on the CV parent body. The aqueous alteration resulted in precipitation of the secondary FeO-rich olivine (Fa_40–49) and slightly disturbed the Fe-Mg distribution in the MgO-rich olivine phenocrysts (Fa_11–22) at about a 1 μm scale. However, no oxygen isotopic disturbances were observed at a scale greater than 100 nm. The MgO-rich olivine, a primary phase of igneous rim formation, has δ¹⁷O = −6 ± 3‰ and δ¹⁸O = −1 ± 4‰, and some grains contain extreme ¹⁶O-rich areas (δ¹⁷O, δ¹⁸O = ∼−30‰) nearly 10 μm across. We detected oxygen isotopic migration of approximately 1 μm at the boundaries of the extreme ¹⁶O-rich areas. Using oxygen self-diffusivity in olivine, the heating time of the igneous rim formation could have continued from several hours to several days at near liquidus temperatures (∼2000 K) in the solar nebula suggesting that the rim formed by a similar flash heating event that formed the chondrules.  相似文献   

Phosphate removal from water by naturally occurring shale,sandstone, and laterite: The role of iron oxides and of soluble species     

Dan Eude Kpannieu  Martine Mallet  Lacina Coulibaly  Mustapha Abdelmoula  Christian Ruby 《Comptes Rendus Geoscience》2019,351(1):37-47

Aqueous phosphate removal by three geomaterials from Ivory Coast was evaluated to determine their potential application as low-cost phosphate adsorbents in wastewater treatment. Batch experiments showed that phosphate uptake strongly depended on pH. Laterite and sandstone dissolution was less pronounced compared to shale. A correlation between concentrations of aqueous cation species released from shale and phosphate uptake was observed. The kinetics were well described using the pseudo-second-order model. Isotherms displayed a saturation level on shale, while phosphate uptake continuously increased for laterite and sandstone. The removal efficiency decreased in the following ranking order: laterite > sandstone > shale. Laterite was also the most efficient adsorbent in column experiments. The high phosphate removal efficiency of laterite (8.3 mg PO₄ g^?1) was attributed to the presence of superparamagnetic low grain sizes of goethite. Laterite is a particularly promising material for further investigation in wastewater treatment technology such as constructed wetlands.  相似文献   

东平-汶上铁成矿带西侧低缓磁异常区找矿前景分析          下载免费PDF全文

程龙  杨勇 《山东国土资源》2020,36(9)

梁山东丁庄铁矿位于东平-汶上铁成矿带西侧的低缓磁异常区,为区内新发现的沉积变质型铁矿床。通过1∶1万高精度磁法面积测量工作,在区内圈定3个磁异常,并进行钻探验证,证实其中2个为隐伏磁铁矿体引起,矿体赋存于泰山岩群山草峪组中。通过研究矿体的地质特征、磁异常特征,并与区域铁矿成矿条件对比分析,认为区内矿致磁异常特征一般表现为在数十纳特的平缓背景场基础上,突然升高至数百纳特的相对高值异常,具突变特征。该类异常一般呈NW走向,与东平-汶上铁成矿带走向基本一致,其形态一般呈规则的长条带状、椭圆状或串珠状。区域上存在较多与研究区具有相似特征的低缓磁异常,且具备有利的成矿地层条件,因此认为区域上低缓磁异常区具有较大的找矿潜力,找矿前景良好。  相似文献   

Geochemistry of Flooded Underground Mine Workings Influenced by Bacterial Sulfate Reduction     

Amber J. Roesler  Christopher H. Gammons  Gregory K. Druschel  Harry Oduro  Simon R. Poulson 《Aquatic Geochemistry》2007,13(3):211-235

Unlike the majority of the water in the flooded mine complex of Butte Montana, which includes the highly acidic Berkeley pit lake, groundwater in the flooded West Camp underground mine workings has a circum-neutral pH and contains at least 8 μM aqueous sulfide. This article examines the geochemistry and stable isotope composition of this unusual H₂S-rich mine water, and also discusses problems related to the colorimetric analysis of sulfide in waters that contain FeS_(aq) cluster compounds. The West Camp mine pool is maintained at a constant elevation by continuous pumping, with discharge water that contains elevated Mn (90 μM), Fe (16 μM), and As (1.3 μM) but otherwise low metal concentrations. Dissolved inorganic carbon in the mine water is in chemical and isotopic equilibrium with rhodochrosite in the mineralized veins. The mine water is under-saturated with mackinawite and amorphous FeS, but is supersaturated with Cu- and Zn-sulfides. However, voltammetry studies show that much of the dissolved sulfide and ferrous iron are present as FeS_(aq) cluster molecules: as a result, the free concentration of the West Camp water is poorly constrained. Concentrations of dissolved sulfide determined by colorimetry were lower than gravimetric assays obtained by AgNO₃ addition, implying that the FeS_(aq) clusters are not completely extracted by the Methylene Blue reagent. In contrast, the clusters are quantitatively extracted as Ag₂S after addition of AgNO₃. Isotopic analysis of co-existing aqueous sulfide and sulfate confirms that the sulfide was produced by sulfate-reducing bacteria (SRB). The H₂S-rich mine water is not confined to the immediate vicinity of the extraction well, but is also present in flooded mine shafts up to 3 km away, and in samples bailed from mine shafts at depths up to 300 m below static water level. This illustrates that SRB are well established throughout the southwestern portion of the extensive (>15 km³) Butte flooded mine complex.  相似文献   

海洋中铁的来源、形态和对初级生产力的限制作用   总被引：6，自引：0，他引：6  

秦延文  张曼平  周革非 《海洋科学进展》1998,(3)

在海洋中,铁和Ｎ、Ｐ等主营养盐一样,也是一种限制浮游植物初级生产力的重要因素。由于铁是一种化学活性较高的元素,所以海水中铁的存在形态、来源及沉降会直接影响其生物可利用性。目前人们一般采用预富集／原子吸收法（ＡＡＳ）或是借助于电分析技术（如催化极谱）来测定海水中的铁。  相似文献   

Organic Matter Diagenesis in Acidic Mine Lakes     

C. Blodau  A. Peine  S. Hoffmann  S. Peiffer 《洁净——土壤、空气、水》2000,28(3):123-135

The significance of organic matter origin for carbon oxidation via sulfate and iron reduction in the sediments of three acid mine lakes is analyzed. Carbon reactivity was estimated by fitting first‐order expressions to measured rates. Carbon oxidation rates via sulfate and ferric iron reduction ranged from 3.4 to 4.7 mmol m^–2 d^–1 and resembled those reported for freshwater lakes. The estimated reaction constants increased from about 10^–3 a^–1 at the interface to the former mine grounds to 0.05 to 0.2 a^–1 at the current sediment‐water interface. Aquatic organic matter accounted for an estimated 45...75% of total carbon oxidation rates while it amounted only to about 5...14% of the total organic matter that had been deposited. The results of this study suggest that in highly acidic mine lakes the reactivity of the deposited organic matter can rapidly increase after flooding, enhancing carbon oxidation and internal neutralization rates in the sediments.  相似文献   

A synthesis of iron deposits in the eastern Tianshan,NW China     

《地学前缘(英文版)》2020,11(4):1271-1287

The northern Xinjiang region is one of the most significant iron metallogenic provinces in China.Iron deposits are found mainly within three regions:the Altay,western Tianshan,and eastern Tianshan orogenic belts.Previous studies have elaborated on the genesis of Fe deposits in the Altay orogenic belt and western Tianshan.However,the geological characteristics and mineralization history of iron deposits in the eastern Tianshan are still poorly understood.In this paper I describe the geological characteristics of iron deposits in the eastern Tianshan,and discuss their genetic types as well as metallogenic-tectonic settings,Iron deposits are preferentially distributed in central and southern parts of the eastern Tianshan.The known iron deposits in the eastern Tianshan show characteristics of magmatic Fe-Ti-V(e.g.,Weiya and Niumaoquan),sedimentary-metamorphic type(e.g.,Tianhu),and iron skarn(e.g.,Hongyuntan).In addition to the abovementioned iron deposits,many iron deposits in the eastern Tianshan are hosted in submarine volcanic rocks with well-developed skarn mineral assemblages.Their geological characteristics and magnetite compositions suggest that they may belong to distal skarns.SIMS zircon U-Pb analyses suggest that the Fe-Ti oxide ores from Niumaoquan and Weiya deposits were formed at 307.7±1.3 Ma and 242.7±1.9 Ma,respectively.Combined with available isotopic age data,the timing of Fe mineralization in the eastern Tianshan can be divided into four broad intervals:Early Ordovician-Early Silurian(476-438 Ma),Carboniferous(335-303 Ma),Early Permian(295-282 Ma),and Triassic(ca.243 Ma).Each of these episodes corresponds to a period of subduction,post-collision,and intraplate tectonics during the Paleozoic and Mesozoic time.  相似文献   

Numerical modeling of water yield of mine in Yangzhuang Iron Mine,Anhui Province of China          下载免费PDF全文

YANG Yun  WU Jian-feng  LIU De-peng 《地下水科学与工程》2015,3(4):352-362

This study develops a three-dimensional heterogeneous numerical model to simulate the water inrush process and predict the water yield for mineral exploration in Yangzhuang Iron Mine in Anhui Province. To identify the hydrogeological parameters of the aquifer in the study area, the model was calibrated and validated using the observed heads through the integrated trial-and-error and automated techniques. Also, the sensitivity analysis of the model was performed to evaluate the uncertainty associated with the calibrated model. According to the mine construction plan at different mining levels of -500 m, -600 m, and -700 m, the calibrated model was then applied to predict the water yields dependent on the different mining levels. As indicated by the prediction results, the numerical simulation model can systematically describe the groundwater system in the mining area and determine the source of water inrush in this iron mine. In conclusion, numerical analyses carried out in this study can provide guidance to decision-makers in balancing the iron ore mining and mine dewatering in the future.  相似文献   

宁芜盆地钟姑矿田典型铁矿成矿岩体Hf-O同位素特征及地质意义   总被引：2，自引：2，他引：0  

孙维安  袁峰  邓宇峰  刘光贤  杨迪  李现锁  傅斌 《岩石学报》2017,33(11):3559-3580

钟姑矿田位于宁芜盆地南部,受矿田内格状构造控制产出一系列早白垩世(129~132Ma)闪长岩及二长岩类侵入体,与铁矿床的形成密切相关,而区域内成矿岩体的研究尤其是岩浆岩的起源和演化有待进一步探讨。本次工作以矿田内的姑山辉石闪长玢岩、龙山辉石闪长岩、白象山闪长岩、钟九闪长岩和太平山二长岩等与铁成矿有关的岩体为研究对象,开展LA-ICP-MS原位锆石Hf同位素和SHRIMP原位O同位素研究。结果显示,钟姑矿田各成矿岩体具有较一致的锆石Hf-O同位素组成,~(176)Hf/~(177)Hf值为0.282425~0.282695,εHf(t)值为-12.3~-3.9,tDM2范围在1.26~1.86Ga;锆石δ18O集中于3.34‰~8.05‰,捕获锆石的176Hf/177Hf比值为0.282324~0.282487,εHf(t)=-15.8~-10.1,锆石tDM2年龄在1.72~20.8Ga之间,锆石δ~(18)O相对集中于5.90‰~6.51‰。钟姑矿田岩浆岩起源于富集的岩石圈地幔,同位素特征指示其携带板块俯冲和蚀变洋壳信息,钟姑矿田的成岩成矿作用应与伸展背景下古太平洋板块俯冲有关。与长江中下游其他矿集区岩浆岩对比研究表明,包括宁芜在内的长江中下游地区岩浆岩具有相同的地幔源区,以铁矿床为主的宁芜和庐枞盆地岩浆岩源区成分以交代岩石圈地幔为主,而以铜陵、繁昌为代表的铜多金属成矿区的岩浆岩受长江中下游新元古代基底的更多影响。  相似文献