电感耦合等离子体质谱法同时测定地质样品中痕量碘溴硒砷的研究：Ⅱ.土壤及沉积物标准物质分析   总被引：11，自引：8，他引：11  

李冰  史世云等 《岩矿测试》2001,20(4):241-246

样品用碳酸钠和氧化锌混合熔剂半熔，热水提取，然后用强酸性阳离子交换树脂将阴离子形式存在的分析元素与溶液中大量钠、锌等阳离子分离，采用电感耦合等离子体质谱法直接同时测定溶液中的碘、溴、硒、砷。用0.07mol/L的氨水溶液清洗进样系统，有效减少了碘等元素的记忆效应和清洗时间。方法检出限（10σ，DF=100）溴、碘分别为0.15和0.028μg/g，砷、硒分别为0.04和0.004μg/g。用土壤和沉积物等地质标准物质分析验证了方法的准确度和精密度，绝大多数分析结果在标准值的允许误差范围之内。样品10次测定的RSD为0.8%～2.8%。  相似文献   

Self‐purification in Upland and Lowland Streams     

Ines Heidenwag  Uta Langheinrich  Volker Lüderitz 《洁净——土壤、空气、水》2001,29(1):22-33

Ecological investigations at four streams in Saxony‐Anhalt have shown that there are considerable differences between the self‐purification power of upland and lowland streams. This result is reflected in chemistry and in microbiology. The structure of the bottom substrate mainly influences the degree of self‐purification in connection with rate of flow and flow velocity. The results and differences are demonstrated using the example of Katzsohlbach in the landscape unit “Mittel‐ and Unterharz” and the stream Olbe in the landscape unit “Magdeburger Börde”.  相似文献   

Oxidation Experiment of Natural Megacrystal Clinopyroxene: Implications for Assignment of Mössbauer Spectra     

ZHI Xiachen  CHEN Peng  LIN Chengzhong  CHEN Shuqing  ZHANG Guilan  LI Yuzhi  LIN Lei 《《地质学报》英文版》2001,75(1):51-58

The Mössbauer spectra of natural megacrystal clinopyroxene are usually fitted by 4 sets of symmetric doublets, A‐A', B‐B', C‐C' and D‐D', respectively, in terms of increasing Qs value in literature. But the assignments of those doublets are quite different, except the D‐D' doublet assigned to Fe³⁺at the lattice site M***1 in previous papers. Particularly, the assignment and interpretation of the C‐C' doublet are diverse. The oxidation experiments of natural megacrystal clinopyroxene collected from the Hannuoba basalt, North China, were performed under controlled conditions of temperature at 1000°C and oxygen fugacity of FMQ buffer in 1, 2, ***3 and 5 days respectively. The oxidized samples were then measured by X‐ray diffraction spectrometry and Mössbauer spectrometry. The oxidation of clinopyroxene is characterized by Fe²⁺ → Fe³⁺at M1 under the subsolidus conditions, which is consistent with the increase of the area of the D‐D' doublet when the heating time increases. Accordingly, the area of the A‐A' and B‐B' doublets decreases with the increasing heating time. However, the area of C‐C' keeps almost constant. Therefore, the 4 sets of doublets can be assigned correctly as follows: A‐A' doublet to Fe⁺²at M1, B‐B' Fe²⁺at M1, C‐C' Fe²⁺at M2, and D‐D' Fe³⁺at M1. The M1 site splitting is due to the NNN (Next Nearest Neighbour) effect of the M2 site. The amount of Fe³⁺at the tetrohedral site of megacrystal clinopyroxene is negligible according to this study.  相似文献   

The use of sintered diamond anvils in the MA8 type high-pressure apparatus     

Tadashi Kondo  Hiroshi Sawamoto  Akira Yoneda  Manabu Kato  Akihito Matsumuro  Takehiko Yagi  Takumi Kikegawa 《Pure and Applied Geophysics》1993,141(2-4):601-611

A new multi-anvil type high-presure apparatus has been developed using sintered diamond anvils to generate pressures over 30 GPa and temperatures up to about 2000°C. A maximum sample volume of about 1 mm³ is available in this system. The pressure was confirmed by dissociation of forsterite into Mg-perovskite and periclase. The basic techniques and problems in utilizing sintered diamond in the MA8 type high-pressure apparatus are discussed with an emphasis on the future prospect of incorporating simultancous X-ray diffraction observation.  相似文献   

鲁甸乐马厂银矿床地质特征与成矿作用初探   总被引：1，自引：1，他引：0  

周云满 《矿床地质》1999,18(2):121-128

乐马厂银矿为地矿部“八五”重点普查项目,普查找矿取得了突破性进展,矿床达大型规模。该矿床类型独特,为国内、外少见的独立银矿床,因此对矿床地质特征和矿床赋存规律进行了较深入研究,取得了新的认识。文章在乐马厂银矿床地质背景基础上,着重研究了该矿床的地质特征及成矿地质作用,并论述了其为产于叠瓦状逆冲－推覆断裂破碎蚀变带中的独立银矿床,其矿化作用过程经历了古构造－沉积（矿源层形成）和构造－热液（充填交代富集）两个阶段,构造活动控制了银矿化作用和银矿体的最终定位。这对在滇东北地区寻找此类银、铅锌矿床具有指导意义。  相似文献   

利用MODIS资料遥感水体上空气溶胶粒子尺度的数值试验   总被引：4，自引：4，他引：4  

冯建东  黄艇  陈长和  张武 《高原气象》2006,25(1):110-115

利用卫星探测辐射的光谱依赖性来反演大气气溶胶粒子尺度分布,首先要建立反演算法并检验其可行性。本文参照文献[1]对暗的海洋上空MODIS资料的处理方法,针对大陆水库上空卫星探测MODIS辐射信号,利用6S(Second Simulation of the Satellite Signal in the Solar Spectrum)辐射模式建立一个查算表(Look-up table:LUT)来反演大气气溶胶粒子尺度分布;然后通过数值试验对所建立的查算表进行检验,讨论其方法的可行性。数值试验结果表明,查算表对大陆性气溶胶尺度分布有反演能力,但拟合误差sεl值随着气溶胶光学厚度的增加而增加。  相似文献   

沙尘气溶胶对西北地区植被遥感的影响分析     

张杰  郭铌  郝志毅 《高原气象》2006,25(1):116-122

选取扬沙—浮尘天气发生中、后的对地观测卫星EOS-MODIS数据,利用6S辐射传输模式对该卫星资料进行大气订正,分析了沙尘气溶胶对沙尘多发区的西北地区植被指数(VI)遥感的影响。结果表明,与晴空天气得到的反射率相比,沙尘使红光通道反射率ρ1、近红外通道反射率ρ2和蓝光通道反射率ρ3均增加,归一化植被指数NDVI有不同程度的降低,降低最大值为0.246。抗大气植被指数ARVI也有所降低,降低最大值为0.231。应用晴空天气条件下的资料,建立了西北干旱区ARVI与NDVI之间的线性关系,并证明了在沙尘天气条件下,利用ARVI计算NDVI的方法,所得的结果较好。  相似文献   

2005年11月26日九江--瑞昌5.7级地震浅析   总被引：6，自引：0，他引：6  

高建华  郑栋  李超 《气象与减灾研究》2006,29(1):56-60

2005年11月26日,在江西省九江县与瑞昌市交界处发生5.7级地震,震源深度10km。宏观震中在九江县港口乡。震中烈度Ⅶ度,极震区为北东向的椭圆,烈度分布受瑞昌盆地内地形地貌条件的控制;5.7级地震的最大余震为ML5.3级,序列类型为主震—余震型,余震较丰富,余震区长轴为北西向。此次地震经历了较长期的应力应变积累过程,发生在江西分宜—黄海北部北东向ML≥4.0级地震活动带和湖北西部—江西南昌ML≥3.0级地震活动带的交汇部位,与大区域地震活动性中长期异常相关。  相似文献   

利用IRS-P6卫星数据制作遥感影像地图     

张幼莹 《国土资源信息化》2006,29(1):30-32,5

本文介绍了以IRS-P6卫星数据作为信息源完成大兴安岭林区的遥感影像地图制作的方法, 通过试验初步认识到:利用IRS-P6卫星数据制作遥感影像地图,可以满足1:50000、 1:25000比例尺的平面制图精度要求,在一些专业和专题应用中可以放大到1:15000比例尺使用。  相似文献   

与澜沧大震可能相关的震磁效应——小波分析一例     

陈伯舫 《华南地震》2006,26(2):16-19

用小波法分析了与1988年澜沧大震相关的通海台地磁Z分量资料。小波分析结果显示地震前“日变幅差”ΔTg(24)存在可能的异常变化;异常为正异常,异常幅度很大,异常结束后立即发生了地震。  相似文献