锡的地球化学性质与华南晚白垩世锡矿成因     

隋清霖  祝红丽  孙赛军  陈登辉  赵晓健  王钊飞 《岩石学报》2020,36(1):23-34

锡在地质过程中表现出亲氧、亲硫和亲铁三重特性。在地幔岩浆过程中,锡是一种中等不相容的金属元素。锡成矿主要与酸性岩浆活动有关,其地球化学性质决定了其成矿主要受源区性质、氧逸度以及挥发分含量、岩浆结晶分异等因素控制。高度结晶分异可使锡在岩浆中进一步富集,是锡成矿相关花岗岩的普遍特征;锡为变价元素,岩浆体系氧逸度影响源区中锡的迁移能力和分离结晶过程中锡的元素行为,还原性岩浆体系有利于锡富集成矿。富含F、Cl和B等挥发组分对锡元素的迁移和富集起积极的作用。全球锡矿床分布与俯冲带关系密切,特提斯和环太平洋构造域是主要蕴藏区。重要的锡成矿事件表现出区域性和阶段性的特征。结合锡的地球化学特性以及锡矿分布特征,我们认为最有利锡成矿的动力学机制是俯冲板片后撤机制。俯冲板片后撤引发深部软流圈地幔上涌,导致强烈的壳幔相互作用,形成低氧逸度、富F、Cl和B等花岗岩,有利于锡成矿。对于华南晚白垩世锡成矿事件,新特提斯洋俯冲板片发生后撤是其成矿地球动力学背景。  相似文献   

青藏高原地区能量水分循环：地表能量平衡和湍流热通量   总被引：2，自引：0，他引：2  

苏中波  张廷  马耀明  贾立  文军 《地球科学进展》2006,21(12):1224-1236

文章给出了青藏高原能量水分循环研究的概况和总结，着重估计了能量平衡各分项和湍流热通量等。在能量平衡的计算基础上，尽管能量不平衡的原因解释仍有争论并且没有解决，但我们揭示了GAME/Tibet试验观测资料中能量不平衡现象。我们发现估算的潜热通量比实际观测的要高许多。然而，根据能量平衡假设的计算结果和SEBS的估算一致性很好。在此基础上可以归纳出差异主要由GAME/Tibet试验观测资料中能量不平衡引起，潜热通量的实际观测可能偏小。  相似文献   

长白山区图们江流域新生代火山岩的岩石化学研究   总被引：5，自引：3，他引：5  

王团华  樊祺诚孙谦  谌宏伟李霓 《岩石学报》2006,22(6):1481-1490

图们江流域新生代火山岩以溢流式喷发为特征，其主要岩石类型以拉斑玄武岩为主，含少量玄武质粗安岩、碱性玄武岩、玄武质安山岩和粗面玄武岩。根据图们江流域火山岩的Mg#（Mg#=100Mg^2＋／（Mg^2＋＋Fe^2＋））值多数≤60，Ni含量〈100μg／g和主、微量元素地球化学特征综合表明，形成火山岩的岩浆不是原始岩浆，它们是原始岩浆在上地幔经历了橄榄石、辉石分离结晶作用后形成的以拉斑玄武岩为主，包括碱性玄武岩和粗面玄武岩等演化岩浆，结晶分异作用是岩浆演化过程的主要控制因素。拉斑玄武质岩浆在上升过程中发生了不同程度的壳源物质同化混染作用，发生在上地壳遭受较大程度混染的岩浆K2O含量明显偏高（〉2．6％），形成玄武质粗安岩。  相似文献   

Modeling studies of the upper ocean response to a tropical cyclone     

Steven L. Morey  Mark A. Bourassa  Dmitry S. Dukhovskoy  James J. O’Brien 《Ocean Dynamics》2006,56(5-6):594-606

A coupled ocean and boundary layer flux numerical modeling system is used to study the upper ocean response to surface heat and momentum fluxes associated with a major hurricane, namely, Hurricane Dennis (July 2005) in the Gulf of Mexico. A suite of experiments is run using this modeling system, constructed by coupling a Navy Coastal Ocean Model simulation of the Gulf of Mexico to an atmospheric flux model. The modeling system is forced by wind fields produced from satellite scatterometer and atmospheric model wind data, and by numerical weather prediction air temperature data. The experiments are initialized from a data assimilative hindcast model run and then forced by surface fluxes with no assimilation for the time during which Hurricane Dennis impacted the region. Four experiments are run to aid in the analysis: one is forced by heat and momentum fluxes, one by only momentum fluxes, one by only heat fluxes, and one with no surface forcing. An equation describing the change in the upper ocean hurricane heat potential due to the storm is developed. Analysis of the model results show that surface heat fluxes are primarily responsible for widespread reduction (0.5°–1.5°C) of sea surface temperature over the inner West Florida Shelf 100–300 km away from the storm center. Momentum fluxes are responsible for stronger surface cooling (2°C) near the center of the storm. The upper ocean heat loss near the storm center of more than 200 MJ/m² is primarily due to the vertical flux of thermal energy between the surface layer and deep ocean. Heat loss to the atmosphere during the storm’s passage is approximately 100–150 MJ/m². The upper ocean cooling is enhanced where the preexisting mixed layer is shallow, e.g., within a cyclonic circulation feature, although the heat flux to the atmosphere in these locations is markedly reduced.  相似文献   

Evaporation over a Heterogeneous Land Surface: EVA_GRIPS and the LITFASS-2003 Experiment—An Overview     

Frank Beyrich  Heinz-Theo Mengelkamp 《Boundary-Layer Meteorology》2006,121(1):5-32

The Evaporation at Grid/Pixel Scale (EVA_GRIPS) project was realised in order to determine the area-averaged evaporation over a heterogeneous land surface at the scale of a grid box of a regional numerical weather prediction or climate model, and at the scale of a pixel of a satellite image. EVA_GRIPS combined surface-based and airborne measurements, satellite data analysis, and numerical modelling activities. A mesoscale field experiment, LITFASS-2003, was carried out in the heterogeneous landscape around the Meteorological Observatory Lindenberg (MOL) of the German Meteorological Service in May and June, 2003. The experiment was embedded in the comprehensive, operational measurement program of the MOL. Experimental determination of surface fluxes on a variety of spatial scales was achieved by employing micrometeorological flux stations, scintillometers, a combination of ground-based remote sensing instruments, and the Helipod, a turbulence probe carried by a helicopter. Surface energy fluxes were also derived from satellite data. Modelling work included the use of different Soil–Vegetation–Atmosphere Transfer schemes, a large-eddy simulation model and three mesoscale atmospheric models. The paper gives an overview on the background of EVA_GRIPS, and on the measurements and meteorological conditions during LITFASS-2003. A few general results are discussed.  相似文献   

Processing and quality control of flux data during LITFASS-2003   总被引：1，自引：0，他引：1  

Matthias Mauder  Claudia Liebethal  Mathias Göckede  Jens-Peter Leps  Frank Beyrich  Thomas Foken 《Boundary-Layer Meteorology》2006,121(1):67-88

Different aspects of the quality assurance and quality control (QA/QC) of micrometeorological measurements were combined to create a comprehensive algorithm which was then applied to experimental data from LITFASS-2003 (Lindenberg Inhomogeneous Terrain—Fluxes between Atmosphere and Surface: a long term Study). Eddy-covariance measurements of the latent heat flux were the main focus of the QA/QC efforts. The results of a turbulence sensor intercomparison experiment showed deviations between the different eddy-covariance systems on the order of 15%, or less than 30 W m⁻², for the latent heat flux and 5%, or less than 10 W m⁻², for the sensible heat flux. In order to avoid uncertainties due to the post-processing of turbulence data, a comprehensive software package was used for the analysis of experimental data from LITFASS-2003, including all necessary procedures for corrections and quality control. An overview of the quality test results shows that for most of the days more than 80% of the available latent heat flux data are of high quality so long as there are no instrumental problems. The representativeness of a flux value for the target land-use type was analysed using a stochastic footprint model. Different methods to calculate soil heat fluxes at the surface are discussed and a sensitivity analysis is conducted to select the most robust method for LITFASS-2003. The lack of energy balance closure, which was found for LITFASS-2003, can probably be attributed to the presence of low-frequency flux contributions that cannot be resolved with an averaging time of 30 min. Though the QA/QC system has been developed for the requirements of LITFASS-2003, it can also be applied to other experiments dealing with similar objectives.  相似文献   

Improved Representation of Land-surface Heterogeneity in a Non-hydrostatic Numerical Weather Prediction Model   总被引：2，自引：1，他引：2  

Felix Ament  Clemens Simmer 《Boundary-Layer Meteorology》2006,121(1):153-174

This study focuses on the relevance of accurate surface parameters, in particular soil moisture, and of parameterizations for heterogeneous land surfaces, for the prediction of sensible and latent heat fluxes by a mesoscale weather forecast model with horizontal grid resolution of 7 km. The analysis is based on model integrations for a 30-day period, which are compared both to flux measurements obtained from the LITFASS-2003 field experiment and to high-resolution-model (1-km grid spacing) results. At first, the relevance of improved parameter sets and input data compared to usual operational practice for an accurate prediction of near-surface fluxes is shown and discussed. It is demonstrated that an observation-based land-surface assimilation scheme leads to an improved soil moisture analysis, which is shown to be essential for the realistic simulation of surface fluxes. Secondly, the implementation of two efficient parameterization strategies for subgrid-scale variability of the surface, the mosaic and the tile approach, is presented. Using these methods, the simulations are in better agreement with measurements than simulations with simple aggregation methods that use effective surface parameters. Integrations with the mosaic approach reproduce high resolution simulations very well and more accurately than simulations with the tile method. Finally, the high resolution simulations are analyzed to justify and discuss the approximations underlying both methods.  相似文献   

The effect of mountainous topography on moisture exchange between the “surface” and the free atmosphere   总被引：1，自引：0，他引：1  

Andreas P. Weigel  Fotini K. Chow  Mathias W. Rotach 《Boundary-Layer Meteorology》2007,125(2):227-244

Typical numerical weather and climate prediction models apply parameterizations to describe the subgrid-scale exchange of moisture, heat and momentum between the surface and the free atmosphere. To a large degree, the underlying assumptions are based on empirical knowledge obtained from measurements in the atmospheric boundary layer over flat and homogeneous topography. It is, however, still unclear what happens if the topography is complex and steep. Not only is the applicability of classical turbulence schemes questionable in principle over such terrain, but mountains additionally induce vertical fluxes on the meso-γ scale. Examples are thermally or mechanically driven valley winds, which are neither resolved nor parameterized by climate models but nevertheless contribute to vertical exchange. Attempts to quantify these processes and to evaluate their impact on climate simulations have so far been scarce. Here, results from a case study in the Riviera Valley in southern Switzerland are presented. In previous work, measurements from the MAP-Riviera field campaign have been used to evaluate and configure a high-resolution large-eddy simulation code (ARPS). This model is here applied with a horizontal grid spacing of 350 m to detect and quantify the relevant exchange processes between the valley atmosphere (i.e. the ground “surface” in a coarse model) and the free atmosphere aloft. As an example, vertical export of moisture is evaluated for three fair-weather summer days. The simulations show that moisture exchange with the free atmosphere is indeed no longer governed by turbulent motions alone. Other mechanisms become important, such as mass export due to topographic narrowing or the interaction of thermally driven cross-valley circulations. Under certain atmospheric conditions, these topographical-related mechanisms exceed the “classical” turbulent contributions a coarse model would see by several times. The study shows that conventional subgrid-scale parameterizations can indeed be far off from reality if applied over complex topography, and that large-eddy simulations could provide a helpful tool for their improvement.  相似文献   

塔里木板块东北部柳园粗面玄武岩带：软流圈地幔减压熔融的产物   总被引：4，自引：6，他引：4  

姜常义  夏明哲余旭 逯东霞魏巍  叶书锋 《岩石学报》2007,23(7):1765-1778

在塔里木东北部,甘肃省西部敦煌市柳园镇南侧,有一条近东西向展布的粗面玄武岩带,长度约150km,宽度达10km,厚度为1900m。这条粗面石玄武岩带属下二叠统哲斯群,岩浆喷发方式以裂隙式溢流为主,枕状构造特别发育。在玄武岩层间夹有很薄的酸性凝灰岩和沉凝灰岩层,属典型的双峰式火山岩组合。按照岩石化学组成的 TAS 分类命名,主要岩石类型为玄武岩、夏威夷岩和橄榄粗安岩。主要造岩矿物为钠长石(Ab 91～100)和普通辉石。普通辉石斑晶、钠长石斑晶和部分基质中的钠长石具有中空结构,并被层状硅酸盐微晶充填。这些岩石基本属碱性玄武岩系列和过渡型系列,大部分属演化的岩浆。演化程度较低的样品具有轻稀土元素亏损型配分曲线,微量元素地球化学具有 MORB 亲和性,ε_(Nd)(t)= 10.14～10.89。玄武质岩浆与陆壳物质之间有较轻的同化混染作用。普通辉石、铁钛氧化物的分离结晶作用是岩浆演化的主要机制。玄武质岩浆源区属于软流圈地幔,部分熔融发生于尖晶石稳定域,是软流圈地幔减压(上涌)熔融的产物。  相似文献   

Bulk-rock geochemistry and plagioclase zoning in lavas exposed along the northern flank of the Western Blanco Depression (Northeast Pacific): Insight into open-system magma chamber processes   总被引：1，自引：0，他引：1  

Carole Cordier  Martial Caroff  Thierry Juteau  Corinne Fleutelot  Christophe Hmond  Marion Drouin  Joseph Cotten  Claire Bollinger 《Lithos》2007,99(3-4):289-311

The present study is based on a set of lavas and crosscutting dikes collected by dives along detailed vertical transects on the northern flank of the western part of the Blanco Transform Fault, Northeast Pacific. The studied area consists of a small basin, the Western Blanco Depression (WBD), extending from the southern end of the Juan de Fuca ridge to a pseudofault trace 60 km eastward. The Northern Scarp of the WBD comprises a volcanic unit overlying a sheeted-dike complex. Major and trace element data, coupled with Sr–Nd isotope ratios, reveal a two-component mantle source, composed by an isotopically depleted matrix variably veined by more enriched material. One chemical group (NS2), indistinguishable from the other Northern Scarp samples on the basis of trace element data, has an unusually depleted isotopic composition typical of a nearly pure mantle end-member. Some cogenetic samples of the Northern Scarp have been used to constrain the differentiation modalities. Anorthite and MgO content profiles in plagioclase xenocrysts and phenocrysts reveal (i) the existence of H₂O-bearing evolved melts in the mushy zones and (ii) the occurrence of mixing process between these melts and anhydrous mafic liquids. The hydration is supported by other petrographic features such as high magmatic fO₂ values, calculated from Fe–Ti oxide pairs, and the presence of pyroxene inclusions in plagioclase phenocrysts. Mixing, consistent with the existence of Ni-rich ferrobasalts, is interpreted to be the consequence of the reservoir refilling by mafic liquids (Mg# = 70). These petrological and geochemical evidences are combined with the evolution of Mg# with depth to suggest a periodic open-system magma chamber evolution beneath the southern end of the Juan de Fuca ridge.  相似文献