波伏棱（Povlen）型羟基纤蛇纹石的谱学研究     

朱和宝  江绍英  邵涵如  吴卫芳 《岩石矿物学杂志》1989,8(1):43-53

波伏棱型羟基纤蛇纹石是波伏棱型纤蛇纹石矿物的新变种,本文报导它的吸收光谱、红外光谱、穆斯堡尔谱、电子顺磁共振谱和核磁共振谱。 研究表明,吸收光谱是Fe~(3 )和Fe~(2 )的晶场跃迁以及Fe~(2 )→Fe~(3 )的荷移跃迁引起的;红外光谱是OH和Si-O的伸缩振动、OH转动以及Mg-O和Si-O的弯曲振动引起的;穆斯堡尔谱是Fe~(2 )_(八面体)、Fe~(3 )_(八面体)和Fe~(3 )_(四面体)引起的;电子顺磁共振谱是Mn~(2 )_(八面体)、Fe~(3 )_(八面体)和Fe~(3 )_(四面体)引起的;核磁共振谱是管道水,镁八面体和硅氧四面体上的OH引起的;矿物加热到825℃时,结构开始破坏并出现镁橄榄石相。 此外,本文还解释了该蛇纹石颜色的本质,阐明了上述过渡金属离子和OH在该矿物中的结构环境。  相似文献   

新形势下测绘保密工作的思考     

王跃峰  于祝文 《地理信息世界》2001,(4)

在《中华人民共和国测绘成果管理规定》及其相关的管理规定中 ,对基础测绘成果保密等级的划分、调整和解密都作了详细的规定。但是在新形势下 ,现行保密法规的对象发生了变化 ,传统的保密管理方式已不适用 ,因此 ,应在保守国家核心机密的前提下 ,重新审定各种地理信息产品的密级 ,最大限度地扩大流通服务范围 ,使地理信息能更多更好地为国民经济建设服务  相似文献   

<Superscript>57</Superscript>Fe Mössbauer spectroscopy,X-ray single-crystal diffractometry,and electronic structure calculations on natural alexandrite     

Sven-Ulf Weber  Michael Grodzicki  Werner Lottermoser  Günther J. Redhammer  Gerold Tippelt  Johann Ponahlo  Georg Amthauer 《Physics and Chemistry of Minerals》2007,34(7):507-515

Natural alexandrite Al₂BeO₄:Cr from Malyshevo near Terem Tschanka, Sverdlovsk, Ural, Russia, has been characterized by ⁵⁷Fe Mössbauer spectroscopy, electron microprobe, X-ray single-crystal diffractometry and by electronic structure calculations in order to determine oxidation state and location of iron. The sample contains 0.3 wt% of total iron oxide. The ⁵⁷Fe Mössbauer spectrum can be resolved into three doublets. Two of them with hyperfine parameters typical for octahedrally coordinated high-spin Fe³⁺ and Fe²⁺, respectively, are assigned to iron substituting for Al in the octahedral M2-site. The third doublet is attributed to Fe³⁺ in hematite. Electronic structure calculations in the local spin density approximation are in reasonable agreement with experimental data provided that expansion and/or distortion of the coordination octahedra are presumed upon iron substitution. The calculated hyperfine parameters of Fe³⁺ are almost identical for the M1 and M2 positions, but the calculated ligand-field splitting is by far too large for high-spin Fe³⁺ on M1.  相似文献   

<Superscript>57</Superscript>Fe Mössbauer measurements and electronic structure calculations on natural lawsonites     

S.-U. Weber  M. Grodzicki  C. A. Geiger  W. Lottermoser  G. Tippelt  G. J. Redhammer  M. Bernroider  G. Amthauer 《Physics and Chemistry of Minerals》2007,34(1):1-9

Three natural lawsonites from Syke Rock, Mendocino Co., Reed Ranch, Marin Co., and Blake Gardens, Sonoma Co., all from the Coast Range Region in California, were studied by ⁵⁷Fe Mössbauer spectroscopy, electron microprobe analysis, and X-ray powder diffraction. The samples contain about 0.6, 1.0, and 1.4 wt% of total iron oxide, respectively. ⁵⁷Fe Mössbauer spectra are consistent with the assumption that high-spin Fe³⁺ substitutes for Al in the octahedrally coordinated site. The Mössbauer spectrum of lawsonite from Syke Rock exhibits a second doublet with ⁵⁷Fe hyperfine parameters typical for octahedrally coordinated high-spin Fe²⁺. Electronic structure calculations in the local spin density approximation yield quadrupole splittings for Fe³⁺ in quantitative agreement with experiment indicating, however, that substitution of Al by Fe³⁺ must be accompanied by local distortion around the octahedral site. Model calculations also reproduce the room temperature hyperfine parameters of ferrous high-spin iron assuming the substitution of Ca by Fe²⁺. However, it cannot be excluded that Fe²⁺ may occupy a more asymmetric site within the microstructural cavity occupied by Ca and a H₂O molecule.  相似文献   

A contribution to seismic shear design of R/C walls in dual structures     

Andreas J. Kappos  P. Antoniadis 《Bulletin of Earthquake Engineering》2007,5(3):443-466

The paper focuses on the seismic response of walls in dual (frame + wall) structures, with particular emphasis on shear behaviour. Although dual structures are widely used in earthquake-resistant medium-rise and high-rise buildings, the provisions of modern seismic codes regarding design of walls for shear are not fully satisfactory, particularly in the (common) case that walls of substantially different length form part of the same structure. Relevant provisions of the leading seismic codes are first summarised and their limitations discussed. Then an extensive parametric study is presented, involving two multistorey dual systems, one with identical walls, and one with walls with unequal length, designed to the provisions of Eurocode 8 for two different ductility classes (H and M). The walls of the same structures are also designed to other methods such as those used in New Zealand and Greece. The resulting different designs are then assessed by subjecting the structures to a suite of strong ground motions, carrying out inelastic time history analysis, and comparing the results against design action effects. It is found that although modern code procedures generally lead to satisfactory performance (differences among them do exist), the design of walls seems to be less appropriate in the case of unequal length walls. For this case a modified procedure is proposed, consisting of an additional factor to account for the relative contribution of walls of the same length to the total base and an improved envelope of wall shears along the height; this improved method seems to work better than the other procedures evaluated herein, but further calibration is clearly required.  相似文献   

1879年甘肃武都南8级地震新史料          下载免费PDF全文

张俊玲 《地震工程学报》2007,29(3):264-266

1985年在甘肃文县屯寨乡洋汤寨的天池庙的大樑上发现了一条新的关于1879年7月1日武都8级地震的新的历史记载。该记载表明武都8级地震在这里的地震烈度至少达到了Ⅹ度。  相似文献   

印尼苏门答腊MW9.0级地震对全球及中国大陆地震趋势影响研究的反思     

韩渭宾  蒋国芳 《四川地震》2007,(4):1-4

本文对2004年12月26日印尼苏门答腊以西发生MW9.0级地震后所做的地震趋势预测做了反思,指出:关于全球特大地震近年可能连发,特大地震对几年内世界7级以上地震年频度没有明显影响,但未来几年内7级以上强震可能集中在这次特大地震附近或相关构造上的预测意见是正确的;而有关近年中国大陆及川滇地区可能发生7级强震的预测是错误的;并认为,2001年昆仑山口西8.1级地震释放了已积累的应变可能是这次特大地震不能触发中国大陆及川滇地区发生强震的重要原因。  相似文献   

入世后测绘行业人才的培养和使用     

宁静慧  赵保萍 《测绘与空间地理信息》2002,25(2):45-47

加入世界贸易组织以后我国测绘人才工作面临的挑战是严峻的。形势要求我们必须更加重视人才队伍建设 ,抓紧培养和造就一批更能适应今后测绘事业发展需要的测绘人才队伍  相似文献   

2—（2，3，5—三氮唑偶氮）—1，8—二羟基—3，6—萘二磺酸与钴的显色反应及应用     

韩德满  蒋华江  叶巧云 《岩矿测试》2002,21(2):155-157

介绍了新水溶性显色剂 2 - ( 2 ,3,5 -三氮唑偶氮 ) - 1 ,8-二羟基 - 3,6-萘二磺酸与钴的显色反应及应用 ,建立了测定钴的新方法。在 pH 9.9的Na2 B4O7 NaOH缓冲液中该试剂与钴形成 1∶1蓝色稳定络合物 ,λmax为 5 88.8nm ,Co的质量浓度在 0～ 1 .0mg/L内符合比尔定律 ,表观摩尔吸光系数为 3.46× 1 0 4 L·mol- 1 ·cm- 1 。所拟方法用于环境水样及维生素B1 2 注射液中的微量钴测定 ,结果与原子吸收法相符 ,5次测定的RSD <1 %。  相似文献   

测绘行业贯彻ISO9000族标准的若干思考     

潘宝玉  张绍廷  姜道利 《测绘工程》2001,10(4):49-52

随着社会主义市场经济的日益完善和管理科学的不断发展，产品质量越来越引起各行各业的高度重视。为了促进测绘行业质量管理的科学化，程序化和标准化，逐步实现管理模式与国际接轨，提高测绘质量管理水平，增强市场竞争能力，在绘行业推行ISO9000族标准已势在必行。文中简要介绍了ISO9000族标准的基本概念，阐述了贯彻认证的意义，方法及步骤等。  相似文献