江西德兴铜矿区水系的Cu同位素地球化学特征及其地质意义     

陈丹丹  宋世明  Mathur Ryan  郭坤一  康文凯  李双喜  赵晓丹  张飞 《地质通报》2016,35(1):188-195

江西德兴铜矿水系样的δ65Cu值具有极大的变化范围(-5.8‰~+24.4‰),是迄今为止已报道发现的最大的Cu同位素分馏值。水体中铜的来源可分为黄铜矿源和黄铁矿源,二者具有明显不同的Cu同位素特征。根据水体的Cu同位素值分布特征,圈出了流经矿体(矿体上方)水、矿体外围水和尾矿库水3个源区。水体中的Cu主要以离子态和微粒态存在,二者具有明显不同的65Cu特征,尾矿库中黄铁矿65Cu对水体的Cu同位素组成具有较大的影响作用。Cu同位素在示踪找矿及地质环境监测方面具有良好的应用潜力。  相似文献   

钙同位素地球化学研究新进展及其在碳酸岩-共生硅酸盐研究中的应用     

向蜜  龚迎莉  刘涛  田世洪 《地质学报》2021,95(12):3937-3960

作为"非传统稳定同位素"家族成员,钙同位素正受到国际地学界日益广泛的关注.钙是主要的造岩元素,也是生物必需的元素.钙在地球各圈层广泛分布,研究钙同位素的地球化学行为将有助于提高我们对各种生物过程和地质过程的认识.钙同位素测定主要采用热电离质谱仪(TIMS)和多接收电感耦合等离子体质谱仪(MC-ICP-MS),分别表示为δ44/40 Ca和δ44/42Ca.目前自然界可观测到的δ44/40Ca变化范围为-2.0‰～6.75‰,约8.7‰.本文系统介绍了近年来钙同位素分析中样品溶解、化学分离、质谱测定以及高温地质过程中的钙同位素分馏及其地质应用等方面的研究成果,尤其对钙同位素在碳酸岩-共生硅酸盐岩研究中的意义、钙同位素组成以及取得的主要认识作了较为全面的介绍.阐述了放射成因40 Ca、部分熔融作用/分离结晶作用、地壳同化作用、古俯冲碳酸盐循环、热液蚀变作用、岩浆起源深度等对碳酸岩、硅酸盐岩的钙同位素组成造成的影响.最后,通过系统对比碳酸岩-共生硅酸盐岩的锂、镁、钙同位素研究成果,认为应该开展多元同位素体系的联合示踪.由于不同同位素体系存在相似性和差异性,而多元同位索体系相结合能有效地加强优势互补,将是同位素地球化学研究发展的一种必然趋势.  相似文献   

卡里马塔海峡贯穿流与印尼贯穿流的相互作用     

李淑江  徐腾飞  孙俊川  杨丽娜  滕飞  王冠琳  王永刚 《海洋科学进展》2021,39(2):197-209

卡里马塔海峡贯穿流将中国南海的低盐水输运到爪哇海,与印度尼西亚贯穿流(印尼贯穿流)携带的西太平洋高盐水在印度尼西亚海(印尼海)交汇,二者通过混合、浮力强迫等过程相互作用.这改变了印度尼西亚海的水体热盐性质,影响局地海气交换和热带太平洋-印度洋之间的热盐交换.依据卡里马塔海峡、龙目海峡和望加锡海峡的实测表层海流数据,采用...  相似文献   

Wintertime rates of net primary production and nitrate and ammonium uptake in the southern Benguela upwelling system     

RF Flynn  JM Burger  K Pillay 《African Journal of Marine Science》2018,40(3):253-266

The elevated levels of primary productivity associated with eastern boundary currents are driven by nutrient- rich waters upwelled from depth, such that these regions are typically characterised by high rates of nitrate-fuelled phytoplankton growth. Production studies from the southern Benguela upwelling system (SBUS) tend to be biased towards the summer upwelling season, yet winter data are required to compute annual budgets and understand seasonal variability. Net primary production (NPP) and nitrate and ammonium uptake were measured concurrently at six stations in the SBUS in early winter. While euphotic zone NPP was highest at the stations nearest to the coast and declined with distance from the shore, a greater proportion was potentially exportable from open-ocean surface waters, as indicated by the higher specific nitrate uptake rates and f-ratios (ratio of nitrate uptake to total nitrogen consumption) at the stations located off the continental shelf. Near the coast, phytoplankton growth was predominantly supported by ammonium despite the high ambient nitrate concentrations. Along with ammonium concentrations as high as 3.6 µmol l^–1, this strongly suggests that nitrate uptake in the inshore SBUS, and by extension carbon drawdown, is inhibited by ammonium, at least in winter, although this has also been hypothesised for the summer.  相似文献   

The impact of physical processes on pollutant transport in Hangzhou Bay     

李宁  毛志华  张庆河 《中国海洋湖沼学报》2009,27(2):266-276

A Lagrangian tracer model is set up for Hangzhou Bay based on Coupled Hydrodynamical Ecological model for Regional Shelf Sea (COHERENS). The study area is divided into eight subdomains to identify the dominant physical processes, and the studied periods are March (the dry season) and July (the wet season). The model performance has been first verified by sea-surface elevation and tidal current observations at several stations. Eight tracer experiments are designed and Lagrangian particle tracking is simulated to examine the impact of physical processes (tide, wind and river runoff) on the transport of passive tracer released within the surface layer. Numerical simulations and analysis indicate that: (1) wind does not change the tracer distribution after 30 days except for those released from the south area of the bay during the wet season; (2) the tide and the Qiantang River runoff are important for particle transport in the head area of the bay; (3) the Changjiang River runoff affects the tracer transport at the mouth of the bay, and its impact is smaller in the dry season than in the wet season. Supported by the Natural Science Foundation of China (No.40576080); National High Technology Research and Development Program of China (863 Program, No. 2007AA12Z182)  相似文献   

A comparison of fibre‐optic distributed temperature sensing to traditional methods of evaluating groundwater inflow to streams     

Martin A. Briggs  Laura K. Lautz  Jeffrey M. McKenzie 《水文研究》2012,26(9):1277-1290

There are several methods for determining the spatial distribution and magnitude of groundwater inputs to streams. We compared the results of conventional methods [dye dilution gauging, acoustic Doppler velocimeter (ADV) differential gauging, and geochemical end‐member mixing] to distributed temperature sensing (DTS) using a fibre‐optic cable installed along 900 m of Ninemile Creek in Syracuse, New York, USA, during low‐flow conditions (discharge of 1·4 m³ s^?1). With the exception of differential gauging, all methods identified a focused, contaminated groundwater inflow and produced similar groundwater discharge estimates for that point, with a mean of 66·8 l s^?1 between all methods although the precision of these estimates varied. ADV discharge measurement accuracy was reduced by non‐ideal conditions and failed to identify, much less quantify, the modest groundwater input, which was only 5% of total stream flow. These results indicate ambient tracers, such as heat and geochemical mixing, can yield spatially and quantitatively refined estimates of relatively modest groundwater inflow even in large rivers. DTS heat tracing, in particular, provided the finest spatial characterization of groundwater inflow, and may be more universally applicable than geochemical methods, for which a distinct and consistent groundwater end member may be more difficult to identify. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

A critical analysis of processes governing the nutrient profiles in the ocean     

R Ramesh  D Lal 《Journal of Earth System Science》1994,103(1):1-15

We have theoretically considered the problem of interpretation of nutrient profiles in the upper ocean (100–2000m). We compare the experimental depth profiles of nonconservative tracers, both stable and radioactive, with solutions of one-dimensional steady state transport equations of increasing complexity including situations not encountered in the real oceans. Apart from gaining insight into the nutrient transport processes, this analysis is useful in offering a way to obtain operational estimates of depth dependent/independent eddy diffusivity and dissolution fluxes in the ocean. These parameters are essential for estimating new production, total production and burial of carbon in the sediments.  相似文献   

Tracer methods used to verify the hypothesis of Cvijić about the underground connection between Prespa and Ohrid Lake     

Sokrat Amataj  Todor Anovski  Ralf Benischke  Romeo Eftimi  Laurence L. Gourcy  Liliana Kola  Ioannis Leontiadis  Eftim Micevski  Alqiviadis Stamos  Jovan Zoto 《Environmental Geology》2007,51(5):749-753

Prespa Lake and Ohrid Lake constitute a hydraulic system shared between Albania, FYR of Macedonia and Greece. Karst rocks separate both lakes. The elevation of Prespa Lake is about 150 m higher than that of Ohrid Lake. Considering these facts, Cvijić formulated in 1906 the hypothesis that Prespa Lake recharges the St. Naum and Tushemisht springs at Ohrid lakeside. Environmental isotopes demonstrated that Prespa Lake recharges about 37–42 and 52–54% of water emerging in St. Naum, and Tushemisht springs, respectively. An artificial tracer experiment carried out in 2002 physically demonstrated the underground connection between both lakes. This experiment confirmed the supposed underground connection and brought important information about the groundwater velocity, transit time, and karst water conduits development.  相似文献   

511铀矿床区域水文地质综合评价中的同位素技术研究   总被引：2，自引：0，他引：2  

左家和  王志明  李森 《铀矿地质》2002,18(2):104-109,117

本文在资料调研的基础上，探讨了地下水埋深的影响因素，介绍了应用同位素水文技术，水化学和水中微量元素分析及同位素单孔示踪技术等综合评价方法研究地下水成因及运移的控制因素，查明511铀矿地浸采矿中的水文地质问题。  相似文献   

Use of deuterated water as a conservative artificial groundwater tracer     

Matthew W. Becker  Tyler B. Coplen 《Hydrogeology Journal》2001,9(5):512-516

Conservative tracers are necessary to obtain groundwater transport velocities at the field scale. Deuterated water is an effective tracer for this purpose due to its similarity to water, chemical stability, non-reactivity, ease of handling and sampling, relatively neutral buoyancy, and reasonable price. Reliable detection limits of 0.1 mg deuterium/L may be obtained in field tests. A field example is presented in which deuterated water, bromide, and pentafluorobenzoic acid are used as groundwater tracers. Deuterated water appeared to be transported conservatively, producing almost identical breakthrough curves as that of other soluble tracers. Electronic Publication  相似文献