Arsenic Distribution Pattern in Different Sources of Drinking Water and their Geological Background in Guanzhong Basin,Shaanxi, China     

LUO Kunli  ZHANG Shixi  TIAN Yuan  GAO Xing 《《地质学报》英文版》2014,88(3):984-994

To study arsenic(As) content and distribution patterns as well as the genesis of different kinds of water, especially the different sources of drinking water in Guanzhong Basin, Shaanxi province, China, 139 water samples were collected at 62 sampling points from wells of different depths, from hot springs, and rivers. The As content of these samples was measured by the intermittent flowhydride generation atomic fluorescence spectrometry method(HG-AFS). The As concentrations in the drinking water in Guanzhong Basin vary greatly(0.00–68.08 μg/L), and the As concentration of groundwater in southern Guanzhong Basin is different from that in the northern Guanzhong Basin. Even within the same location in southern Guanzhong Basin, the As concentrations at different depths vary greatly. As concentration of groundwater from the shallow wells(50 m deep, 0.56–3.87 μg/L) is much lower than from deep wells(110–360 m deep, 19.34–62.91 μg/L), whereas As concentration in water of any depth in northern Guanzhong Basin is 10 μg/L. Southern Guanzhong Basin is a newly discovered high-As groundwater area in China. The high-As groundwater is mainly distributed in areas between the Qinling Mountains and Weihe River; it has only been found at depths ranging from 110 to 360 m in confined aquifers, which store water in the Lishi and Wucheng Loess(Lower and Middle Pleistocene) in the southern Guanzhong Basin. As concentration of hot spring water is 6.47–11.94 μg/L; that of geothermal water between 1000 and 1500 m deep is 43.68–68.08 μg/L. The high-As well water at depths from 110 to 360 m in southern Guanzhong Basin has a very low fluorine(F) value, which is generally 0.10 mg/L. Otherwise, the hot springs of Lintong and Tangyu and the geothermal water in southern Guanzhong Basin have very high F values(8.07–14.96 mg/L). The results indicate that highAs groundwater in depths from 110 to 360 m is unlikely to have a direct relationship with the geothermal water in the same area. As concentration of all reservoirs and rivers(both contaminated and uncontaminated) in the Guanzhong Basin is 10 μg/L. This shows that pollution in the surface water is not the source of the high-As in the southern Guanzhong Basin. The partition boundaries of the high- and low-As groundwater area corresponds to the partition boundaries of the tectonic units in the Guanzhong Basin. This probably indicates that the high-As groundwater areas can be correlated to their geological underpinning and structural framework. In southern Guanzhong Basin, the main sources of drinking water for villages and small towns today are wells between 110–360 m deep. All of their As contents exceed the limit of the Chinese National Standard and the International Standard(10 μg/L) and so local residents should use other sources of clean water that are 50 m deep, instead of deep groundwater(110 to 360 m) for their drinking water supply.  相似文献   

The challenge of dating early pleistocene fossil teeth by the combined uranium series–electron spin resonance method: the Venta Micena palaeontological site (Orce,Spain)     

Mathieu Duval  Christophe Falguères  Jean‐Jacques Bahain  Rainer Grün  Qingfeng Shao  Maxime Aubert  John Hellstrom  Jean‐Michel Dolo  Jordi Agusti  Bienvenido Martínez‐Navarro  Paul Palmqvist  Isidro Toro‐Moyano 《第四纪科学杂志》2011,26(6):603-615

The palaeontological site of Venta Micena (Orce, Andalusia, Spain) lies in the eastern sector of the Guadix–Baza basin, one of the best documented areas in Europe for Plio‐Pleistocene biostratigraphy. The combination of biochronological and palaeomagnetic results, combined with the radiometric data obtained for Atapuerca Sima del Elefante, indicated that the Venta Micena stratum was formed between the Jaramillo and Olduvai palaeomagnetic events, most likely between 1.22 and 1.77 Ma. Five fossil teeth from two outcrops (sites A and B) were selected to assess the potential of combined uranium series–electron spin resonance (US‐ESR) dating of Early Pleistocene sites. Although the US‐ESR results of the first outcrop showed a large scatter between the three teeth, the mean age of 1.37 ± 0.24 Ma can be considered a reasonable age estimate for Venta Micena. The mean ESR age of 0.62 ± 0.03 Ma obtained for site B seems to be a severe underestimation when compared with the independent age control. This underestimation is attributed to a relative recent U‐mobilization event that led to some U‐leaching. The results show that any ESR age calculations of old samples are extremely sensitive to variations in the measured ²³⁰Th/²³⁴U ratios in dental tissues. Although the results demonstrate that ESR can in principle be applied to Early Pleistocene sites, they also reveal the complexity of dating such old teeth. It is necessary to continue research in several directions, such as study of the behaviour of ESR signals in old teeth and understanding recent U‐mobilization processes, to improve the reliability of the combined US‐ESR dating method applied to Early Pleistocene times, a period for which the number of available numerical dating techniques is very limited. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Variation and pattern in the responses of mammal faunas to Late Pleistocene climatic change in southeastern South Australia     

Amy C. Macken  Gavin J. Prideaux  Elizabeth H. Reed 《第四纪科学杂志》2012,27(4):415-424

We examined mammal occurrence and variability through the Late Pleistocene vertebrate fossil deposit of Grant Hall in Victoria Fossil Cave, Naracoorte, South Australia. To determine long‐term patterns of change, we compared the composition and relative abundance trends of the assemblage with a nearby Middle Pleistocene deposit in Cathedral Cave. Total species richness did not change through the Grant Hall sequence, dated from 93 ± 8 to 70 ± 5 ka. However, species relative abundances varied between ecologically divergent species, and in some cases between species that demonstrate similar environmental preferences. For some species this variation is comparable to that recorded in Cathedral Cave. Of those showing similar trends between the two deposits, the forest inhabitant, Pseudomys fumeus, recorded an 8.6% decline through Grant Hall, coincident with a 9.7% increase in the dry heath/mallee dweller Pseudomys apodemoides. These patterns indicate that climatic transition from relatively warm, moist to cooler, drier conditions impacted some species in similar ways through climatic cycles of the past. However, the majority of the fauna demonstrated complex responses that are individual and variable through time. Statistical tests of species trends from the Grant Hall assemblage caution that large fossil samples are required to validate patterns observed. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

大连地区更新世的哺乳动物     

高春玲 《国土资源》2000,(1)

大连地区碳酸盐岩分布广泛 ,裂隙溶洞发育 ,洞穴堆积物中蕴含了丰富的更新世哺乳动物化石和古文化遗物 ,在境内陆地和附近海域陆续发现了 30余处化石点。在众多的化石点中尤以古龙山遗址和大连动物群最引人注目 ,前者在同一地点内采集到 377种上万件的脊椎动物骨骼化石 ,并伴有石器、骨器、灰烬等远古人类活动的遗物 ;后者包括了 2 8种早更新世的小型哺乳动物 ,这是大连乃至东北地区的首次报导。这些事实说明了东北地区不只是仅有晚更新世的动物群 ,至少还有早更新世的大连动物群 ,即使在晚更新世 ,也不只是单一的披毛犀 -猛犸象动物群 ,还存在着具有从华北向东北过渡性质的古龙山动物群。今后工作中应注意寻找古人类及中更新世的哺乳动物化石 ,加强对全新世动物遗骨的研究。  相似文献   

Improved age constraint for pre‐ and post‐Anglian temperate‐stage deposits in north Norfolk,UK, from analysis of serine decomposition in Bithynia opercula     

Rob Westaway 《第四纪科学杂志》2010,25(5):715-723

The ‘new glacial stratigraphy’ (NGS) of Britain postulates that deposits hitherto assigned to the Anglian glaciation in Marine Isotope Stage (MIS) 12 represent MIS 16, 12, 10 and 6. This controversial idea can be tested at Sidestrand in north Norfolk, where fossiliferous temperate‐stage deposits underlie the oldest and overlie the youngest of the glacial deposits. Previous work has considered biostratigraphy and amino acid dating of these temperate‐stage deposits, but did not achieve tight age constraint using the amino acid evidence alone. The total hydrolysable amino acid fraction in intra‐crystalline protein from Bithynia tentaculata opercula has previously been analysed for concentrations of serine and alanine. Statistical screening of these data gives alanine/serine ratios of 4.572 ± 0.114 for the Sidestrand Hall Member (beneath the glacial deposits) and 3.564 ± 0.091 for the Sidestrand Cliff Formation (overlying the glacial deposits). These ratios imply ages of MIS 13a and 11c, respectively, indicating the latest Cromerian and early Hoxnian interglacials and invalidating the NGS. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Paleomagnetic Excursions Recorded in the Yanchi Playa in Middle Hexi Corridor, NW China Since the Last Interglacial     

YANGTaibao YUYongtao LIJijun ANCongrong LIUJinfeng ZHANGJunyan 《山地科学学报》2004,1(2):128-142

Paleomagnetic determinations on lithologieal profiles of two paralleled long drillin gcores covering the past 130 kyr B.P., GT40 and GT60,from the Yanchi Playa in the arid Northwestern China indicate that a series of pronounced paleomagnetic excursions have been documented. By correlating our results with published regional and worldwide reports 4 excursion events out of 10 apparent reversal signals (labeled from GT-1 to GT-10) were identified as excursion events coeval with the Mono Lake Event (28.4 kyr-25.8 kyr), Laschamp Event (43.3 kyr-40.5kyr), Gaotai Event (82.8 kyr-72.4 kyr) and the Blake Event (127.4 kyr-113.3 kyr), respectively. GT-9 correlates with the above-mentioned Gaotai Event,GT-7 and GT-6 correspond to two stages of the Laschamp Event and GT-5 to the Mono Lake Event. It is noteworthy that the so-called Gaotai Event has not been reported as a pronounced paleomagnetic excursion in the Northwestern China. Every magnetic excursion event corresponds to paleointensity minima, anteceding those established abrupt paleoclimatic change events, such as the Younger Drays and the Heinrich Events (H1-H6). Here, we tentatively propose that these geomagnetic excursions/reversals can be viewed as precursors to climate abruptness. During the transitional stages when the earth‘s magnetic field shifted between a temporal normal and a negative period, the earth‘s magnetic paleointensity fell correspondingly to a pair of minima. Although more precise chronology and more convincing rock magnetic parameter determinations are essentially required for further interpretation of their intricate coupling mechanism, these results may have revealed, to some extent, that the earth‘s incessantly changing magnetic field exerts an strong influence on the onset of saw-tooth shaped abrupt climate oscillations through certain feedback chains in arid Central Asia or even North Hemispheric high latitude regions.  相似文献   

Deepwater Ventilation and Stratification in the Neogene South China Sea     

李前裕赵泉鸿  钟广法翦知湣 田军成鑫荣  汪品先陈木宏 《中国地质大学学报(英文版)》2007,18(2):95-108

Combined data of physical property, benthic foraminifera, and stable isotopes from ODP Sites 1148, 1146, and 1143 are used to discuss deep water evolution in the South China Sea (SCS) since the Early Miocene. The results indicate that 3 lithostratigraphic units, respectively corresponding to 21-17 Ma, 15-10 Ma, and 10-5 Ma with positive red parameter (a*) marking the red brown sediment color represent 3 periods of deep water ventilation. The first 2 periods show a closer link to contemporary production of the Antarctic Bottom Water (AABW) and Northern Component Water (NCW), indicating a free connection of deep waters between the SCS and the open ocean before 10 Ma. After 10 Ma, red parameter dropped but stayed higher than the modern value (a*=0), the CaCO3 percentage difference between Site 1148 from a lower deepwater setting and Site 1146 from an upper deepwater setting enlarged significantly, and benthic species which prefer oxygen-rich bottom conditions dramatically decreased. Coupled with a major negative excursion of benthic δ13C at ~10 Ma, these parameters may denote a weakening in the control of the SCS deep water by the open ocean. Probably they mark the birth of a local deep water due to shallow waterways or rise of sill depths during the course of sea basin closing from south to east by the west-moving Philippine Arc after the end of SCS seafloor spreading at 16-15 Ma. However, it took another 5 Ma before the dissolved oxygen approached close to the modern level. Although the oxygen level continued to stabilize, several Pacific Bottom Water (PBW) and Pacific Deep Water (PDW) marker species rapidly increased since ~6 Ma, followed by a dramatic escalation in planktonic fragmentation which indicates high dissolution especially after ~5 Ma. The period of 5-3 Ma saw the strongest stratified deepwater in the then SCS, as indicated by up to 40% CaCO3 difference between Sites 1148 and 1146. Apart from a strengthening PDW as a result of global cooling and ice cap buildup on northern high latitudes, a deepening sea basin due to stronger subduction eastward may also have triggered the influx of more corrosive waters from the deep western Pacific. Since 3 Ma, the evolution of the SCS deep water entered a modern phase, as characterized by relative stable 10% CaCO3 difference between the two sites and increase in infaunal benthic species which prefer a low oxygenated environment. Thesubsequent reduction of PBW and PDW marker species at about 1.2 Ma and 0.9 Ma and another significant negative excursion of benthic δ13C to a Neogene minimum at ~0.9 Ma together convey a clear message that the PBW largely disappeared and the PDW considerably weakened in the Mid-Pleistocene SCS. Therefore, the true modern mode SCS deep water started to form only during the "Mid-Pleistocene climatic transition" probably due to the rise of sill depths under the Bashi Strait.  相似文献   

Palynological Evidence of Late Pleistocene Soft-sediment Deformation Event in the Northeastern Margin of the Tibetan Plateau     

WEI Lijie  LI Zhenhong  DONG Xiaopeng  CUI Jiawei  HUANG Ting  KOU Linlin 《《地质学报》英文版》2023,97(3):841-854

The northeastern margin of the Tibetan Plateau is the youngest part of the Tibetan Plateau where tectonic activity is intense and climate change is complex. In this study, combined with field investigations, we explored accelerator mass spectrometry 14C and optically stimulated luminescence dating and palynological analysis of the sedimentary sequence in the Qingshuihe Basin to explain the origin of soft-sediment deformation layer. Dating and palynological results from the Sanchahe section in th...  相似文献   

晚更新世以来珠江三角洲钻孔年代及沉积演化     

林鹏辉  李宏卫  詹伟琪  凌恳  宋盈瑾  徐晓琳  赖忠平 《地质论评》2023,69(Z1):333-335

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印度河扇水道堤岸外侧更新世沉积物波发育特征与形成过程分析^*          下载免费PDF全文

浩克  纪友亮  张胜久  刘炎鑫  Khurram Shahzad  Saad Ahmed Mashwani  刘笑语  姜燕 《古地理学报》2022,24(2):389-404

印度河扇更新世发育的沉积物波结构复杂、形态多样,其形成过程的认识程度低。本次研究通过高分辨率地震数据和地震解释技术,研究了印度河扇沉积物波的波长、形态、波峰变化等形态特征;阐述了沉积物波与沉积物变形特征的差异、识别了两者的区分标志;总结了水道堤岸斜坡和区域斜坡上沉积物波的分布规律;在此基础上,讨论了沉积物波的形成机理和控制因素,分析了沉积物波的形成过程,并建立了印度河扇沉积物波的形成模式。研究表明: (1)研究区沉积物波波长平均为486.84 m,最大1473 m;波高在10~60 m之间,平均30 m。(2)沉积物波的形态有对称型和非对称型,其迁移方式有上坡迁移型、加积型和下坡迁移型;沉积物波主要发育在水道堤岸的斜坡上,在区域斜坡上也发育少量的沉积物波,这2种沉积物波波脊的走向差异很大,水道堤岸斜坡上的沉积物波主要分布于水道凹岸堤岸的外侧,距离水道越远其规模(波长、波高)越小,波脊走向近于NE-SW方向,与水道的走向平行或斜交;区域斜坡上的沉积物波波脊的走向多为NW-SE向,平行于区域斜坡的走向,离源区越远规模越大。(3)水道堤岸斜坡上的沉积物波是由水道型浊流在离心力的作用下,溢出水道的凹岸,在堤岸外侧的斜坡上沉积形成的,堤岸斜坡的角度对沉积物波的发育规模影响不大,浊流的强度和输沙量对其规模影响大;区域斜坡上发育的沉积物波是由顺坡而下的非水道化的浊流沉积形成;滑塌变形造成的起伏地貌以及早期沉积物波的存在,也都影响了后期沉积物波的发育。  相似文献