新疆祁漫塔格维宝矿区西北部花岗闪长岩年代学、地球化学及其构造意义   总被引：3，自引：0，他引：3  

周建厚  丰成友  沈灯亮  李大新  王辉  张明玉  马圣钞 《地质学报》2015,89(3):473-486

维宝铜铅锌多金属矿床位于青海与新疆两省区交界处的若羌县境内,是近年来在新疆祁漫塔格地区新发现的具有大型远景规模的多金属矿床,本文对该矿床西北部含暗色包体花岗闪长岩开展了SIMS高精度锆石U-Pb定年和地球化学研究,结果表明该花岗闪长岩含有角闪石特征矿物,SiO2含量为60.74%~61.34%,K2O含量为3.01%~3.20%,A/CNK值为0.89~0.94,属于准铝质高钾钙碱性I型花岗岩;在球粒陨石标准化的稀土元素配分图上表现为右倾式,轻重稀土分馏明显,具有中等负Eu异常(δEu=0.56~0.59),微量元素以富集大离子亲石元素Rb、K和Th,明显亏损Ba、Ta、Nb、Ti等为特征。SIMS锆石U-Pb定年结果显示,花岗闪长岩结晶年龄为227.6±2.3 Ma(n=16,MSWD=0.02),形成于晚三叠世,是东昆仑祁漫塔格地区中—晚三叠世大规模中酸性岩浆侵入作用的产物。借助元素判别图解,结合矿床地质特征和区域构造演化特点,认为维宝矿区西北部花岗闪长岩形成的构造环境为后碰撞演化阶段,很可能是与深部壳幔混染有关的变火成岩部分熔融的产物。  相似文献   

Timing and tectonic setting of the Sijiaying banded iron deposit in the eastern Hebei province,North China Craton: Constraints from geochemistry and SIMS zircon U–Pb dating     

《Journal of Asian Earth Sciences》2014

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Dating Micrometre‐Thin Rims Using a LA‐ICP‐MS Depth Profiling Technique on Zircon from an Archaean Metasediment: Comparison with the SIMS Depth Profiling Method     

Colter J. Kelly  Christopher R.M. McFarlane  David A. Schneider  Simon E. Jackson 《Geostandards and Geoanalytical Research》2014,38(4):389-407

Laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) was examined as a tool for measuring isotopic variation as a function of ablation depth in unpolished zircon from an Archaean metasediment specimen. This technique was able to identify micrometre‐thin (> 3 μm) isotopically distinct mineral domains characterised by ca. 100 Myr younger ²⁰⁷Pb/²⁰⁶Pb ages associated with 2s age uncertainties as low ~ 0.2%, as well as elevated U content relative to grain interiors (up to an order of magnitude). Our calculated drilling rate suggests that each laser pulse excavated depths of ~ 0.06 μm. Ages resolved through the LA‐ICP‐MS methods overlap the 2s uncertainties of ²⁰⁷Pb/²⁰⁶Pb ages measured using SIMS depth profiling on the same zircon population. The rims were further evinced by the detection of relative enrichment (> 3 orders of magnitude) in REE in the outermost micrometres of the same zircon, measured using a different and independent LA‐ICP‐MS depth profiling technique. We propose a LA‐ICP‐MS U–Pb technique capable of quickly identifying and quantifying rims, which are indication of late, yet geologically significant, fluid events that are otherwise undefined.  相似文献   

Zircon Geochronology and Trace Element Geochemistry from the Xiaozhen Copper Deposit, North Daba Mountain: Constraints on Albitites Petrogenesis     

WANG Gang  WANG Zongqi  ZHANG Yingli  WANG Kunming 《《地质学报》英文版》2014,88(1):113-127

Albitite often accompanies with various metal and gem mineral deposits and a large number of occurrences have been reported globally, including the South Qinling orogen, China. The Xiaozhen copper deposit is a typical deposit in the North Daba Mountain area of the South Qinling orogen whose distribution is controlled by albitite veins and fractures. As there are few studies on the petrogenesis of albitite in Xiaozhen copper deposit, this paper focuses on the petrogenesis of albitite and its mineralization age. Detailed fieldwork and mineral microscopic observations initially suggest that albitite from the Xiaozhen copper deposit is igneous in origin. Further zircon trace element geochemistry studies indicate that these zircons have high Th/U ratios(0.5), low La content, high(Sm/La)N and Ce/Ce*values, and a strong negative Eu anomaly, which are commonly seen in magmatic zircons. The chondrite–normalized rare earth element(REE) patterns are consistent with magmatic zircons from throughout the world, and they fall within or near the field of magmatic zircons on discriminant diagrams. The calculated average apparent Ti–in–zircon temperature for young zircons is 780°C, consistent with magmatic zircon crystallization temperatures. Therefore, zircon geochemistry indicates that the albitite origin is magmatic. SIMS U–Pb dating on nine magmatic zircons yielded a concordia age of 154.8±2.2 Ma, which represents the formation of albitite and the metallogenic age. More importantly, it is consistent with the ages of Yanshanian magmatism and metallogenesis in the South Qinling orogen, so formation of the Xiaozhen copper deposit may be a closely related geological event.  相似文献   

新疆东天山土屋斑岩铜矿床地球化学、年代学、Lu-Hf同位素及其地质意义   总被引：11，自引：6，他引：5  

王银宏  薛春纪  刘家军  王建平  杨俊弢  张方方  赵泽南  赵云江 《岩石学报》2014,30(11):3383-3399

新疆东天山地区岩浆岩的岩石成因和地球动力学背景备受关注.本文获得的东天山土屋斑岩铜矿床SIMS锆石U-Pb定年、全岩元素地球化学和Lu-Hf同位素数据,以对这一问题进行约束.土屋斑岩铜矿床位于新疆东天山造山带晚古生代大南湖-头苏泉岛弧带中,赋矿地层为下石炭统企鹅山群,赋矿围岩主要为安山岩和闪长玢岩,含矿岩石主要为英云闪长岩.本文SIMS锆石U-Pb定年结果表明,土屋地区含矿岩体大约侵位于335Ma,土屋斑岩铜矿床成矿时代与成岩时代基本一致或稍晚.地球化学数据显示安山岩和闪长玢岩具有同源性及岛弧火山岩的特点,英云闪长岩具有埃达克质岩石的特征.土屋英云闪长岩具不均一的锆石ε_Hf(t)正值(+6.3~+16.1),表明其可能来源于俯冲板片的部分熔融.土屋斑岩铜矿床含矿岩体很可能是在早石炭世北天山洋板块北向俯冲的地球动力学背景下,大洋板片发生部分熔融形成埃达克质岩浆,在熔融过程中同时析出金属,随埃达克质岩浆一起上升,并与地幔橄榄岩发生交代作用,在岩体顶部富集成矿.  相似文献   

华北板块北缘古大洋闭合时间的限定 ——来自四子王旗西后壕子同碰撞花岗岩的证据   总被引：1，自引：0，他引：1  

孟庆鹏  贺元凯  张文  吴泰然  郑荣国  徐操  张昭昱 《地质通报》2013,32(11):1749-1759

位于华北板块北缘四子王旗北部的西后壕子花岗岩体的Cameca IMS-1280-SIMS锆石U-Pb年龄为266Ma±2Ma。该岩体主要由二长花岗岩组成,以出现大量颗粒较大的白云母为特征,具有较高的SiO2含量（75.21%~76.69%）,A/CNK值多大于1.1,CIPW标准矿物中刚玉的含量也都高于1%。在球粒陨石标准化稀土元素配分图解上,Eu具有强烈的负异常（δEu=0.03~0.11）,REE呈现出明显的M型四分组效应,部分微量元素也表现出non-CHARAC的性质。在原始地幔标准化微量元素配分图上,元素Ba、Nb、Sr和Ti相对亏损,Cs、Rb、Th和Pb相对富集。在构造环境判别图解中,所有样品均落入同碰撞花岗岩区域。结合区域地质背景及以上特征,西后壕子岩体应为强过铝质的高分异S型花岗岩,形成于二叠纪晚期的陆-陆碰撞环境中。270~260Ma期间,四子王旗地区发育EW向的碰撞花岗岩带,限定华北板块与南蒙古微大陆沿索伦缝合带的闭合时间为二叠纪晚期。  相似文献   

拉萨地块西段中新世查加寺钾质火山岩岩石成因^*——岩石地球化学、年代学和Sr-Nd同位素约束   总被引：3，自引：1，他引：2  

胡文洁  田世洪  杨竹森  张兆卿 《矿床地质》2012,31(4):813-830

通常认为,青藏高原碰撞后钾质超钾质岩是交代富集上地幔低度部分熔融的产物,而最近的研究则表明,钾质火山岩也可以起源于下地壳源区.文章对青藏高原拉萨地块西段新识别出的查加寺火山岩进行了岩石地球化学、锆石SIMS U-Pb定年和Sr-Nd同位素研究,结果表明其岩石类型为碱性系列钾质粗面岩,锆石SIMS U Pb 年龄为(23.97±0.28) Ma,说明火山活动为中新世.钾质粗面岩显示出富集LREE及LILE(K、Rb、Ba、Th、U、Pb)、亏损HFSE(Ti、Nb、Ta、P),具有类似于埃达克质岩的稀土元素分布模式和微量元素蛛网图分布模式的特征;具有高的La/Yb比值(81～105)、较高的ω(Sr)(409×10-6～472×10-6)、较高的Sr/Y比值(28-37)、较低的ω(Y)(11.5×10-6～15.7×10-6)、明显亏损重稀土元素Yb(0.78×10-6～1.08×1)-6)、较高的w(Al2O3)(15.47％～16.7％)、较低的w(MgO)(0.63％～2.12％),无明显的Eu、Sr负异常,类似于典型的埃达克岩成分特征;具有高的w(K2O)(6.28％～6.97％)、高的Rb/Sr比值(0.94～1.03)和低的Ba/Rb比值(2.21～2.51),以及Na2O、K2O与SiO2无明显的相关关系,表明源区的富钾矿物是以金云母为主;具有较低的ω(Cr) 、ω(Ni)(分别为53.4×10-6～69.4×10-6,11.4×10-6～23.5×10-6),以及较低的εNd值(-12.6～-11.8)和较高的87Sr/86Sr比值(0.73207～0.73249).所有这些特征都表明,查加寺钾质粗面岩起源于拉萨地块增厚下地壳富钾物质的部分熔融.查加寺钾质粗面岩具有约145Ma、75 Ma和30 Ma等3组继承锆石年龄群.  相似文献   

青海都兰县下得波利铜钼矿区锆石U-Pb测年及流体包裹体研究   总被引：5，自引：2，他引：3  

刘建楠  丰成友  亓锋  李国臣  马圣钞  肖晔 《岩石学报》2012,28(2):679-690

下得波利铜钼矿为近年新发现的斑岩型矿床,位于青海省昆南构造带。本文在详细调查矿区地质特征基础上,开展了花岗斑岩的年代学、岩石地球化学以及矿床流体包裹体研究。结果表明,下得波利矿区花岗斑岩的锆石SIMSU-Pb年龄为244.2±2.1Ma;成矿斑岩为钙碱性系列,具高硅(SiO2=72.00%～74.92%)、富铝(Al2O3=13.60%～14.52%)、低钾(K2O=1.86%～1.72%),富集轻稀土元素((La/Yb)N=11.83～5.64)和大离子亲石元素(LILE),亏损高场强元素(HFSE)等特征;流体包裹体的主要类型有富液相包裹体、富气相包裹体和含子矿物包裹体,与成矿作用密切相关的流体包裹体均一温度主要集中在250～310℃之间,盐度介于2.77%～32.27%NaCleqv,认为成矿流体不混溶作用所引起的富含挥发份物质的流体分离,是造成流体物理化学条件改变和金属元素淀积成矿的主要因素。  相似文献   

Geochronologic and isotope geochemical constraints on magmatism and associated W–Mo mineralization of the Jitoushan W–Mo deposit,middle–lower Yangtze Valley     

《International Geology Review》2012,54(13):1532-1547

The Jitoushan W–Mo ore body is a typical skarn-type deposit with the potential for porphyry Mo mineralization at depth. As it is newly discovered, only a few studies have been conducted on the geochronology and ore genesis of this deposit. The ore district consists of Cambrian to Silurian sedimentary and low-grade metasedimentary strata, intruded by granodiorite, diorite porphyry, granite porphyry, and quartz porphyry. Skarn W–Mo ore bodies are hosted in the contact zone between the granodiorite and Cambrian limestone strata. Within the granodiorite near the contact zone, quartz vein type and disseminated sulphide mineralization are well developed. The Mo-bearing granite porphyry has been traced at depth by drilling. Our results reveal two discrete magmatic events at ca. 138 and ca. 127 Ma in the study area. The molybdenite Re–Os isochronal age of 136.6 ± 1.5 million years is consistent with the first magmatic event. The zircon Hf isotope (?_Hf(t) =??12.55?3.91), sulphide isotopes (δ³⁴S = 3.32–5.59‰), and Re content of molybdenite (Re_content = 6.424–19.07 μg) indicate that the ore-forming materials were mainly derived from the deep crust. The regional tectonic system switched from a Late Jurassic transpressive regime to an earliest Cretaceous extensional regime at ca. 145 Ma, and at ca. 138 Ma, the Jitoushan W–Mo deposit formed in an extensional setting.  相似文献   

Zircon U–Pb and molybdenite Re–Os geochronology,Hf isotope analyses,and whole-rock geochemistry of the Donggebi Mo deposit,eastern Tianshan,Northwest China,and their geological significance     

《International Geology Review》2012,54(4):446-462

The geodynamic setting of Mesozoic magmatic rocks and associated mineralization in eastern Tianshan, Northwest China, are attracting increasing attention. The newly discovered giant Donggebi molybdenum deposit (0.508 Mt at 0.115% Mo) is located in the central part of eastern Tianshan, Xinjiang. The molybdenum mineralization was genetically associated with the Donggebi stock, comprised of porphyritic granite and granite porphyry. Secondary ion mass spectrometry (SIMS) zircon U–Pb dating constrains that the porphyritic granite and granite porphyry emplacement occurred at 233.8 ± 2.5 Ma and 231.7 ± 2.6 Ma, respectively. The Re–Os model ages of six molybdenite samples range from 235.2 to 237.0 Ma, with a weighted mean age of 236.1 ± 1.4 Ma, which is roughly consistent within errors with the zircon U–Pb ages, suggesting a Middle Triassic magmatic–mineralization event at Donggebi. Geochemically, the Donggebi granitoids are characterized by high SiO₂ and K₂O contents, with low MgO contents, belonging to high-K calc-alkaline granites. These rocks show pronounced enrichment in K, Rb, U, and Pb, and depletion in Sr, Ba, P, and Ti, with negative Eu anomalies (Eu/Eu* = 0.20–0.38). In situ Hf isotopic analyses of zircon from the porphyritic granite and granite porphyry yielded ε_Hf(t) values ranging from +6.6 to +10.5, and from +5.5 to +10.1, respectively. The geochemical and isotopic data imply that the primary magmas of the Donggebi granitoids could have originated by partial melting of a juvenile lower crust that involved some mantle components. Combined with the regional geological history, geochemistry of the Donggebi granitoids, and new isotopic age data, we thus propose that the Donggebi molybdenum deposit was formed in the Middle Triassic, and occurred in an intracontinental extension setting in eastern Tianshan.  相似文献