Complexation of mercury by dissolved organic matter in surface waters of Galveston Bay, Texas   总被引：3，自引：0，他引：3  

Seunghee Han  Gary A. Gill  Ronald D. Lehman  Key-Young Choe 《Marine Chemistry》2006,98(2-4):156-166

The chemical speciation of dissolved mercury in surface waters of Galveston Bay was determined using the concentrations of mercury-complexing ligands and conditional stability constants of mercury-ligand complexes. Two classes of natural ligands associated with dissolved organic matter were determined by a competitive ligand exchange-solvent solvent extraction (CLE-SSE) method: a strong class (L_s), ranging from 19 to 93 pM with an average conditional stability constant (K_HgLs) of 10²⁸, and a weak class (L_w) ranging from 1.4 to 9.8 nM with an average K_HgLs of 10²³. The range of conditional stability constants between mercury and natural ligands suggested that sulfides and thiolates are important binding sites for dissolved mercury in estuarine waters. A positive correlation between the estuarine distribution of dissolved glutathione and that of mercury-complexing ligands supported this suggestion. Thermodynamic equilibrium modeling using stability constants for HgL, HgCl_x, Hg(OH)_x, and HgCl(OH) and concentrations of each ligand demonstrated that almost all of the dissolved mercury (> 99%) in Galveston Bay was complexed by natural ligands associated with dissolved organic matter. The importance of low concentrations of high-affinity ligands that may originate in the biological system (i.e., glutathione and phytochelatin) suggests that the greater portion of bulk dissolved organic matter may not be important for mercury complexation in estuarine surface waters.  相似文献   

Organic enrichment and structure of the macrozoobenthic community in the northern Adriatic Sea in an area facing Adige and Po mouths   总被引：1，自引：0，他引：1  

Simonini  R.; Ansaloni  I.; Bonvicini Pagliai  A.M.; Prevedelli  D. 《ICES Journal of Marine Science》2004,61(6):871-881

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现场海水中有机污染物光学测量方法研究     

孙继昌  惠力  吴承璇  程岩  程广欣  徐珊珊  宋文杰 《海洋技术学报》2005,24(4):54-56

介绍了一种用光学方法对海水中的有机污染物（主要包括：叶绿素-a、黄色物质、石油）进行测量的光学系统，该系统可同时测量海水中多种有机污染物的种类和浓度。  相似文献   

Effect of marine animal excretions on differential growth of phytoplankton species   总被引：2，自引：0，他引：2  

Arzul  Genevieve; Seguel  Miriam; Clement  Alejandro 《ICES Journal of Marine Science》2001,58(2):386-390

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The ICES North Sea benthos survey: the sedimentary environment   总被引：2，自引：1，他引：2  

Basford  D. J.; Eleftheriou  A.; Davies  I. M.; Irion  G.; Soltwedel  T. 《ICES Journal of Marine Science》1993,50(1):71-80

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Tectonic core of a sedimentary drift: a potential ridge propagation feature beneath the Blake Outer Ridge     

Dayton Dove  Steven C. Jaume  Erin Beutel 《Marine Geophysical Researches》2007,28(1):1-11

The Blake Outer Ridge is a 480–kilometer long linear sedimentary drift ridge striking perpendicular to the North American coastline. By modeling free-air gravity anomalies we tested for the presence of a crustal feature that may control the location and orientation of the Blake Outer Ridge. Most of our crustal density models that match observed gravity anomalies require an increase in oceanic crustal thickness of 1–3 km on the southwest side of the Blake Outer Ridge relative to the northeast side. Most of these models also require 1–4 km of crustal thinning in zone 20–30 km southwest of the crest of the Blake Outer Ridge. Although these features are consistent with the structure of oceanic fracture zones, the Blake Outer Ridge is not parallel to adjacent known fracture zones. Magnetic anomalies suggest that the ocean crust beneath this feature formed during a period of mid-ocean ridge reorganization, and that the Blake Outer Ridge may be built upon the bathymetric expression of an oblique extensional feature associated with ridge propagation. It is likely that the orientation of this trough acted as a catalyst for sediment deposition with the start of the Western Boundary Undercurrent in the mid-Oligocene.  相似文献   

High-resolution measurements of chromophoric dissolved organic matter in the Mississippi and Atchafalaya River plume regions   总被引：4，自引：0，他引：4  

Robert F. Chen  G. Bernard Gardner 《Marine Chemistry》2004,89(1-4):103

Chromophoric dissolved organic matter (CDOM) was measured in the spring and summer in the northern Gulf of Mexico with the ECOShuttle, a towed, instrumented, undulating vehicle. A submersible pump mounted on the vehicle supplied continuously flowing, uncontaminated seawater to online instruments in the shipboard laboratory and allowed discrete samples to be taken for further analysis. CDOM in the northern Gulf of Mexico was dominated by freshwater inputs from the Mississippi River through the Birdfoot region and to the west by discharge from the Atchafalaya River. CDOM was more extensively dispersed in the high-flow period in the spring but in both time periods was limited by stratification to the upper 12 m or so. Thin, subsurface CDOM maxima were observed below the plume during the highly stratified summer period but were absent in the spring. However, there was evidence of significant in situ biological production of CDOM in both seasons.The Mississippi River freshwater end member was similar in spring and summer, while the Atchafalaya end member was significantly higher in the spring. In both time periods, the Atchafalaya was significantly higher in CDOM and dissolved organic carbon (DOC) than the Mississippi presumably due to local production and exchange within the coastal wetlands along the lower Atchafalaya which are absent along the lower Mississippi. Nearshore waters may also have higher CDOM due to outwelling from coastal wetlands. High-resolution measurements allow the differentiation of various water masses and are indicative of rapidly varying (days to weeks) source waters. Highly dynamic but conservative mixing between various freshwater and marine end members apparently dominates CDOM distributions in the area with significant in situ biological inputs (bacterial degradation of phytoplankton detritus), evidence of flocculation, and minor photobleaching effects also observed. It is clear that high-resolution measurements and adaptive sampling strategies allow a more detailed examination of the processes that control CDOM distributions in river-dominated systems.  相似文献   

渤海南部海底沉积物颜色的研究   总被引：1，自引：0，他引：1  

周伟  王琦  赵其渊  周莉  沈渭全 《海洋科学》1990,14(3):31-35

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Eddy Diffusion Coefficients of Suspended Particulate Matter: Effects of Wind Energy Transfer and Stratification     

Lars Chresten Lund-Hansen  Morten Pejrup  Jens Valeur  Anders Jensen 《Estuarine, Coastal and Shelf Science》1994,38(6)

Gross sedimentation rates (GSR) have been measured using sediment traps placed at nine different levels above the bed (0·3, 0·5, 0·8, 1·0, 2·0, 4·0, 6·0, 8·0 and 10·0 m). The sediment traps were deployed for 1·25 years and recovered 28 times during the study period. Low average GSR values of 5·5 g m^-2 day^-1 were obtained at 10·0 m, and high average GSR values of 114·8 g m^-2 day^-1 were obtained at 0·3 m. An expression for the eddy diffusion coefficient of suspended particulate matter (K_s), based on the measured GSR is given. The expression has been used for modelling of K_s at the different trap levels above the bed. High values (≈42 cm² s^-1) of K_s were obtained at the upper traps, whereas low values (≈2 cm² s^-1) were obtained near the bed. Comparison between level of turbulent energy in terms of shear stress at the boundaries of the water column, i.e. from the wind and the bed flow, showed that wind energy exceeded that of the bed flow by a factor 16. At 5·0 m K_s was positively correlated (r=0·66) to the eddy diffusion coefficient of momentum (K_m) derived from the wind energy transfer to the water, giving an average β of 0·5 for K_s =βK_m. The density difference between surface and bottom waters has been designated a parameter of stratification, and is discussed in relation to variations of K_s and K_m .  相似文献   

Optical properties of low molecular weight and colloidal organic matter: Application of the ultrafiltration permeation model to DOM absorption and fluorescence   总被引：4，自引：1，他引：4  

Claude Belzile  Laodong Guo   《Marine Chemistry》2006,98(2-4):183-196

Cross-flow ultrafiltration (CFF) is often used to obtain separation and concentration of colloids from bulk natural water samples. Application of the ultrafiltration permeation model allows the quantitative determination of the low molecular weight material (LMW, < 1 kDa) and colloids in bulk dissolved organic matter (DOM) from measurements of time series permeate samples obtained from CFF. Detailed analysis of a Yukon River water sample shows that DOM absorption coefficient and fluorescence follow the permeation model and that the complex spectral optical properties of LMW DOM can be reconstructed from CFF data. A combination of measured and modeled data indicates that the LMW contribution to bulk DOM optical properties obtained from CFF can be grossly underestimated by the use of a low concentration factor (CF, the ratio of initial sample volume to retentate volume). Even at a relatively high CF of 19, optical properties of LMW DOM calculated from measurements of the retentate or integrated permeate would underestimate true values by 5–36%. In the Yukon River sample, LMW dissolved organic carbon represented 26% of the bulk concentration, but only 3–14% of the colored DOM was in the LMW fraction while 31–33% of bulk DOM florescence was due to LMW DOM. The contrasting optical properties of LMW and colloidal DOM support the concept that analysis of bulk DOM absorption and fluorescence properties reveals information about DOM molecular weight.  相似文献