Emission of nitric oxide from soils and termite nests in a Trachypogon savanna of the Orinoco basin   总被引：2，自引：0，他引：2  

Alberto Rondón  Christer Johansson  Fugenio Sanhueza 《Journal of Atmospheric Chemistry》1993,17(3):293-306

Nitric oxide fluxes from soils in the Trachypogon savanna of the Orinoco basin were determined during the dry season using the static chamber method. The emission from dry soils fluctuated from 0.4 to 3 ng N m^–2 s^–1 and increased up to 25 ng N m^–2 s^–1 after moderate watering or light rain-falls (1 to 5 mm). The mean emission values are up to 6 times lower than one observed earlier at the Chaguaramas site, but up to 10 times higher than one recorded at the Guri site, indicating an important spatial variability in NO fluxes of the Venezuelan savanna region. The changes observed after the addition of nitrogen to the soil, in the form of ammonium and/or nitrate, indicate a high denitrification potential in this acidic soil. Burning of the surface vegetation produced an increase by a factor of 10 in the emission rate of NO, but the effect was relatively short in time, about 5 days. It was estimated for the savanna region that burning increases the total NO soil emission during the dry season by 15% compared to the unburnt case. Soils with termite nests emit 10 times more NO than soil without nests, but the contribution from this source is less than 2% of the total savanna soil flux.  相似文献   

人工植被和流动沙丘近地面层湍流通量的计算     

刘树华  辛国君  陈荷生  冯金朝  刘立超 《气象》1993,19(9):9-13

提出了由Ｂｕｓｉｎｇｅｒ建议的无量纲廓线通用函数形式的近地面层稳定度参数ζ的相似方程分析解。代替了以往采用数值迭代法求ζ，并应用于沙漠人工植被和裸露流动沙丘上的实例资料分析。采用目前广泛应用的空气动力学方法，分别计算了动量和热量交换系数，感热和潜热通量，并由波文比－能量平衡方法进行了验证。结果表明：采用Ｂｕｓｉｎｇｅｒ无量纲通量廓线关系形式的近地面层稳定度参数ζ的相似方程分析解，代替以往惯用的数值  相似文献   

Fractionation of phosphorus in the sediments of a tropical estuary   总被引：3，自引：0，他引：3  

A. N. Balchand  S. M. Nair 《Environmental Geology》1994,23(4):284-294

Fractionation of phosphorus in the sediments of the Cochin estuary situated along the southwest coast of India was studied by applying sequential chemical extraction. The different forms of phosphorus were estimated seasonally (premonsoon, monsoon, and postmonsoon) under eight different schemes. The major forms of phosphorus analyzed were exchangeable P, anion exchangeable P, carbonate-bound P, labile and resistant organic P, Fe and Al P, calcium-bound P, and hydrolyzable surplus P. Quantitatively, the above fractions in isolation or in combination vary in content due to chemoestuarine variability and seasonal fluctuations. Changes in speciation have been noted in association with salinity variations in the waterway, especially following enhanced river runoff during the monsoon. The chemical forms of the sediment-bound phosphorus in the northern parts of this estuary have been shown to be modified by nonpoint sources. Sediment P fractionation defines the role of chemical speciation of phosphates (as nutrients) and is indicative of the processes controlling the pathways of P into the coastal waters. The changes in the exchangeable P, together with marked regional variations in calcium-bound P, exemplify the complex estuarine variability of phosphorus. Enhanced amounts of exchangeable P mark its appearence in high saline waters, signifying the presence of biologically available nutrient phosphorus. The calcium-bound P and hydrolyzable surplus P show significant relation with sediment organic carbon and Fe whereas other forms do not exhibit any marked covariation. The Ca and Na NTA extraction scheme is very specific in its selectivity.  相似文献   

内蒙中部地区水系沉积物异常评价方法     

田书文 《铀矿地质》1986,(6)

通过对内蒙中部地区水系沉积物U、~(210)Po的区域概查,在约60000km~2范围内,发现了104个U异常点,296个~(210)Po异常点,并圈出了U异常晕圈210个,~(210)Po异常圈144个。在此基础上,总结了评价异常的方法、程序和10个主要评价判据,并对异常进行了分类(Ⅰ,Ⅱ,Ⅲ类)。文章通过对三个实例的解剖、从较多的U、~(210)Po异常中分辨出矿异常及非矿异常。从而说明,在干旱荒漠地区进行水系沉积物测量,快速扫面,是普查找矿远景行之有效的方法之一。  相似文献   

Physical,radiative, and dynamical processes within a nighttime marine stratus cloud     

Ismail Gultepe 《Pure and Applied Geophysics》1995,144(2):321-350

Observations taken by aircraft and conventional platforms are used to investigate dynamical, physical, and radiative processes within a marine stratus cloud during the Canadian Atlantic Storms Program (CASP) II field project which took place over the east coast of Canada. Stratus which formed over the ocean on February 6, 1992 during the nighttime, is studied to analyze cloud top and base processes. The cloud was supercooled during the study period. Fluctuations and fluxes are calculated along constant flight altitude legs approximately 100 km long in space. The scales of structures larger than 5 km are removed from the analysis using a running average technique. Droplet spectra obtained by a forward scattering spectrometer probe (FSSP) were used in a 1-D radiative transfer model to calculate infrared (IR) fluxes and radiative heating rates. A heat conservation equation was used to estimate vertical air velocity (w _a ) within the cloud. The results showed that, because of a warmer ocean surface, significant moisture and heat were transferred from the ocean surface to the boundary layer. The cloud base was at about 400 m height and the top was at about 1.4 km.w _a at the cloud base was estimated about 5 cm s^–1. Strong IR cooling rate at the cloud top was calculated to be 75°C day^–1 for a 100 m thick layer. Negative skewness inw _a , suggesting narrow downdrafts, was likely due to radiative cooling at the cloud top. The entrainment velocity was found to be about 1.5 cm s^–1 at cloud top. Mean moisture and heat fluxes within the cloud were estimated to be comparable to those from the ocean surface. Vertical air velocity at the cloud top due to radiative cooling was found to be about –40 cm s^–1.  相似文献   

全球变化中的北极碳汇：现状与未来     

高众勇  陈立奇  CAI Wei-jun  WANG Yong-chen 《地球科学进展》2007,22(8):857-865

由于海冰覆盖，北极碳汇（Arctic Carbon Sink）在全球碳通量预算中经常被忽略或简单处理。但随着全球变化加剧，北极发生快速变化，北极碳循环及其对全球变化的响应与反馈日趋重要。综合对北极碳汇的研究结果，分析了北极碳汇的来源、变化以及主要调控因子，评估了北极碳汇现状。探讨了在全球变化中，影响北极碳汇变化的因素及其对未来北极碳汇变化趋势的影响。   相似文献   

Factors Controlling Sulfide Geochemistry in Sub-tropical Estuarine and Bay Sediments     

John W. Morse  Heather Thomson  David W. Finneran 《Aquatic Geochemistry》2007,13(2):143-156

The primary factors that control the concentration of total reduced (inorganic) sulfide in coastal sediments are believed to be the availability of reactive iron, dissolved sulfate and metabolizable organic carbon. We selected nine sites in shallow (<3 m), close to sub-tropical, estuaries and bays along the central Texas coast that represented a range in sediment grain size (a proxy for reactive iron), salinity (a proxy for dissolved sulfate), and total organic carbon (a proxy for metabolizable organic carbon). Based on these parameters a prediction was made of which factor was likely to control total reduced sulfide at each site and what the relative total reduced sulfide concentration was likely to be. To test the prediction, the sediments were analyzed for total reduced sulfide, acid volatile sulfide, and citrate dithionate-extractable, HCl-extractable and total Fe in the solid phase. Using solid-state gold–mercury amalgam microelectrodes and voltammetry, we determined pore water depth profiles of Fe(II) and ΣH₂S and presence or absence of FeS_(aq). At five of the nine sites the calculated degree of sufildization of citrate dithionite-reactive-iron was close to or greater than 1 indicating that rapidly reactive iron was probably the limiting factor for iron sulfide mineral formation. At one site (salinity = 0.9) dissolved Fe(II) was high, ΣH₂S was undetectable and the total reduced sulfide concentration was low indicating sulfate limitation. At the last three sites a low degree of sulfidization and modest total reduced (inorganic) sulfide concentrations appeared to be the result of a limited supply of metabolizable organic carbon. Fe(II)–S(-II) clusters (FeS_(aq)) were undetectable in 10 out of 12 bay sediment profiles where ΣH₂S was close to or below detection limits, but was observed in all other porewater profiles. Acid volatile sulfide, but not total reduced sulfide, was well correlated with total organic carbon and ranged from being undetectable in some cores to representing a major portion of total reduced sulfide in other cores. Although predicted controls on total reduced sulfide were good for very low salinity water or sandy sediments, they were only right about half the time for the other sediments. The likely reasons for the wrong predictions are the poor correlation of total organic carbon with grain size and differing fractions of metabolizable organic carbon in different sedimentary environments. Differences in sediment accumulation rates may also play a role, but these are difficult to determine in this region where hurricanes often resuspend and move sediments. This study demonstrates the need to examine more complex and often difficult to determine parameters in anoxic “normal marine” sediments if we are to understand what controls the concentration and distribution of sulfides.  相似文献   

Simulation of Atmospheric Boundary Layer Characteristics during Indian Summer Monsoon using Observations from Monsoon Trough Boundary Layer Experiment at Jodhpur, India     

T. V. B. P. S. Rama Krishna  Maithili Sharan 《Pure and Applied Geophysics》2007,164(8-9):1839-1859

The diurnal structure of the boundary layer during Indian summer monsoon period is studied using a one-dimensional meteorological boundary layer model and the observations collected from the Monsoon Trough Boundary Layer Experiment conducted in 1990 at Jodhpur, India. The model was initialized with the observed temperature profiles at 0530 LST on 17 July, 1990 at Jodhpur and was run for 26 hours. The study is carried out with a geostrophic wind speed of 9.5 m s⁻¹ corresponding to the strong wind simulation. The mean thermodynamic and wind structure simulated by the model are in good agreement with those observed from 30 m tower. The computed surface layer characteristics such as the surface fluxes, TKE and standard deviations of velocity components are found to be reasonably in good agreement with those based on turbulence measurements. The shear and buoyancy budget computed from the model are also compared with the turbulence measurements. The integrated cooling budget in the nocturnal boundary layer is examined.  相似文献   

The impact of hurricanes on sedimenting particulate matter in the semi-arid Bahía de La Paz,Gulf of California     

Norman Silverberg  Evgueni Shumilin  Fernando Aguirre-Bahena  Ana Patricia Rodríguez-Castañeda  Dmitry Sapozhnikov 《Continental Shelf Research》2007

From 2002 through 2004, time-series sediment trap samples were collected from a depth of 410 m in Cuenca Alfonso, Bahía de La Paz, on the SW coast of the Gulf of California. The instrument recorded the impact of the local passage of hurricanes “Ignacio” (24–26 August) and “Marty” (21–23 September) in 2003. These two events accounted for 82% of the total rainfall measured in 2003, equivalent to the annual average precipitation in years without hurricanes. Mean total mass fluxes (TMFs) of 2.88 and 3.58 g m⁻² d⁻¹ were measured during the week of each hurricane as well as the following week. This may have been enough to produce a lamina in the underlying sediment with characteristics peculiar to such events. The terrigenous component was particularly abundant, with notably higher concentrations of Fe, Sc, Co and Cs and REEs. In contrast, TMFs throughout 2002–2004 (excluding the hurricane periods) averaged only 0.73 g m⁻² d⁻¹ and had a larger marine biogenic component. The extraordinary elemental fluxes during the 29 days of hurricane-influenced sedimentation represented a great proportion of the totals over an entire “normal” year: Co (67.8%) >Sc (62.6) >Fe (59.6) >Cs (53.4)>Lu (51.5)>La (51.3)>Yb (51.0)>Ce (49.5) >Tb (48.4) >Sm (44.7)>Cr (36.5) >Ca (31.0)>Eu (25.4%). The terrigenous fraction was calculated using (a) TMF minus the sum of CaCO₃, biogenic silica and organic matter and (b) the ratio of Sc in the trap samples to the average in the Earth's crust. The latter was consistently smaller, but the two methods offered similar results following hurricanes (78% vs. 63%, respectively). For normal sedimentation, however, the difference method yielded values twice as large as the Sc method (58% vs. 30%) This suggests that the mineralogy of the terrigenous fraction may also vary, with unsorted dessert soil being carried to sea by the powerful flash floods associated with hurricanes. Eolian supply of particles, particularly Sc-free quartz grains, possibly from beyond the limited fluvial drainage basin, apparently dominates normal sedimentation.  相似文献   

Effects of irrigation on CO₂ and CH₄ fluxes from Mongolian steppe soil     

Shigeru Mariko  Tadaaki Urano 《Journal of Hydrology》2007,333(1):118-123

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