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Jean-François Lambert Lorenzo Stievano Irène Lopes Marwen Gharsallah Lingyu Piao 《Planetary and Space Science》2009,57(4):460-21825
We present here selected results recently obtained on the molecular characterization of amino acids adsorption on oxide minerals and their further polymerization by thermal activation, in the general frame of assessing Bernal's hypothesis on the origin of biopolymers on mineral surfaces. Adsorption mechanisms may be identified by a combination of vibrational spectroscopy, 13C solid-state NMR, and molecular modeling. Depending on a particular amino acid, the oxide surface investigated, and the water activity during adsorption (i.e., whether it is carried out from the gas phase or from an aqueous solution), contributions from electrostatic adsorption, outer-sphere and inner-sphere (coordination) complexes may be observed. These mechanisms result in significant adsorption selectivities from equimolar mixtures of different amino acids. Upon thermal activation at moderate temperatures (150-160 °C), clean polymerization events occur and can easily be observed by thermogravimetric analysis. There are some hints of selectivity in this step too. The water activity during thermal treatment plays an important role for the thermodynamics of polymerization. 相似文献
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Investigating the period 1983–1994 for western Greece, a possible correlation between the selectivity characteristics of the SES (seismic electric signals of the VAN method) and earthquake parameters has been reported by Uyeda et al. [Uyeda, S., Al-Damegh, K.S., Dologlou, E., Nagao, T., 1999. Some relationship between VAN seismic electric signals (SES) and earthquake parameters, Tectonophysics, 304, 41–55.]. They found that the earthquake source mechanism changed from largely strike-slip type to thrust type at the end of 1987, and this coincided with a shift in the SES sensitive site from Pirgos (PIR) to Ioannina (IOA) VAN station. Here, we report the results for the period January 1, 2002–July 25, 2004, during which the SES sensitive site of PIR became again active, after a 10-year period of “quiescence”. This activation was followed by strike slip earthquakes (on August 14, 2003 and March 17, 2004 with magnitude 6.4 and 6.5, respectively) in the Hellenic arc, which provides additional evidence on the correlation reported by Uyeda et al. The SES activities recorded at PIR have been discriminated from “artificial” noise by employing the natural time-domain analysis introduced recently. 相似文献
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方目网囊对蓝圆鲹和多齿蛇鲻的选择性比较 总被引：1，自引：0，他引：1
为检测方目网囊对蓝圆鱼参和多齿蛇鲻的选择作用 ,2 0 0 0年 1 1～ 1 2月在南海北部海域试验了 4种目大的方目网囊。结果表明 ,方形网目网囊有利于释放纺缍形 (如蓝圆 鱼参)、圆形或近圆形 (如多齿蛇鲻 )两种形体鱼类的小、幼鱼 ,且对后者的释放效果更好。当网囊目大分别为 45、5 0mm时 ,蓝圆鱼参的5 0 %选择体长 (L0 .5)分别为 1 2 1 2 2、1 2 8 77mm ;当网囊目大分别为 40、45、5 0mm时 ,多齿蛇鲻的L0 5分别为 1 2 4 1 2、1 2 6 75、1 3 9 3 2mm。通过不同目大网囊对蓝圆鱼参、多齿蛇鲻选择性比较分析 ,发现 5 0mm目大方目网囊的选择效果好于 40、45mm目大的网囊 ,因此 ,在南海区拖网渔业中采用 5 0mm目大的方目网囊是必要的 ,同时建议将 1 5 0mm作为蓝圆鱼参、多齿蛇鲻的最小可捕叉长标准。 相似文献
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Geochemical study of clays used as barriers in landfills 总被引：1，自引：0，他引：1
This is a hydraulic and geochemical study on 2 materials: natural clay (AN) and a regenerated material made up of a sand-bentonite (SB) mixture. The hydraulic part allowed us to conclude that a 10% industrial bentonite content mixed with sand offers hydraulic properties that are similar to those of AN material and are lower than the required standards. The geochemical properties of both AN and SB matrixes are comparable with those of some of the synthetic leachates studied. Furthermore, the Langmuir model helped us to identify the adsorption capacities of both matrixes with the following selectivities: Pb > Cu > Cd > Zn. 相似文献
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拖网选择性引起的鱼类表型性状选择差的初步研究 总被引：5，自引：0，他引：5
本文应用数值模拟的方法,研究了拖网选择性引起的鱼类表型性状(生长速率K、极限体长L∞、初次性成熟年龄Am)的选择差,通过假设不同的白噪音CV、自然死亡系数M、极限体长L∞、种群的样本大小Ss及网目尺寸Ms来估算鱼类表型性状的选择差在最大捕捞死亡系数逐渐加强时的变化情况。模拟结果表明捕捞死亡系数越大,造成的K、L∞、Am选择差也越大,并且Am的选择差增大的速率比K、L∞的小。白噪音越大,自然死亡系数越大,种群受捕捞影响产生的K、L∞、Am的选择差越大;极限体长的大小和种群的样本大小对K、L∞、Am的选择差的影响不大;网目尺寸越大,K、L∞、Am的选择差越小。随着最大捕捞死亡系数的增大,种群的生长速率变大,极限体长变小,初次性成熟年龄提前。表明了捕捞压力造成鱼类生存环境的变化,鱼类种群发生自适应进化响应,表现在表型性状的变化,且捕捞强度越大,环境差异越大,导致的表型性状选择差越大。 相似文献
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Ashiwani Kumar Gupta P.K. Banerjee Arun Mishra P. Satish Pradip 《International Journal of Mineral Processing》2007
The frothers of alcohol family (MIBC and Alpha-terpineol) were compared with polyglycol ethers (DF-1012) in terms of two phase characterization parameters like foamability, foam stability, surface activity and bubble size distribution. In this research, fundamental two phase frother characterization parameters were linked with three phase coal flotation behavior. 相似文献