环境样品中痕量元素的化学形态分析Ⅰ．分析技术在化学形态分析中的应用   总被引：21，自引：7，他引：21  

何红蓼 李冰杨红霞  倪哲明 《岩矿测试》2005,24(1):51-58

文章介绍了形态分析的基本概念,常用的联用分析技术,如气相色谱原子吸收光谱、气相色谱原子荧光光谱、气相色谱微波诱导等离子体原子发射光谱、气相色谱电感耦合等离子体质谱、高效液相色谱电感耦合等离子体质谱等在环境样品(水、土壤、沉积物)中痕量元素化学形态(价态、金属有机化合物等)分析中的应用,土壤和沉积物中污染元素的顺序提取步骤,以形态分析发展动态。引用文献72篇。  相似文献   

吐哈盆地十红滩铀矿床水文地球化学特征   总被引：6，自引：0，他引：6  

乔海明  张天太  张复新  尚高峰  宋哲 《铀矿地质》2005,21(6):345-352

本文根据水化学资料的研究,探讨了十红滩铀矿床含矿含水层高矿化度地下水的成因,分析了高矿化度水对铀溶解迁移的影响及碳酸盐的形成机理.  相似文献   

DMS and SO2 at Baring Head, New Zealand: Implications for the Yield of SO2 from DMS     

Warren J. de Bruyn  Mike Harvey  Jill M. Cainey  Eric S. Saltzman 《Journal of Atmospheric Chemistry》2002,41(2):189-209

Atmospheric dimethyl sulfide (DMS) and sulfur dioxide (SO₂) concentrations were measured at Baring Head, New Zealandduring February and March 2000. Anti-correlated DMS and SO₂ diurnalcycles, consistent with the photochemical production of SO₂ from DMS, were observed in clean southerly air off the ocean. The data is used to infer a yield of SO₂ from DMS oxidation. The estimated yields are highly dependent on assumptions about the DMS oxidation rate. Fitting the measured data in a photochemical box model using model-generated OH levels and the Hynes et al. (1986) DMS + OH rate constant suggests that theSO₂ yield is 50–100%, similar to current estimates for the tropical Pacific.However, the observed amplitude of the DMS diurnal cycle suggests that the oxidation rate is higher than that used by the model, and therefore, that theSO₂ yield is lower in the range of 20–40%.  相似文献   

Oxydation expérimentale de Fe-tourmalines et corrélation avec une déprotonation des groupes hydroxyleAnnealing in oxidising conditions of Fe-tourmalines and correlated deprotonation of OH groups     

Yves Fuchs  Martine Lagache  Jorge Linares 《Comptes Rendus Geoscience》2002,334(4):245-249

Annealing at 400?T?600 °C (40?P?60 MPa and HM buffer-controlled f(O₂)) of tourmalines synthesised at the same T and P with NNO buffer induces an oxidation of Fe²⁺ into Fe³⁺ in some Y sites only (Mössbauer Spectroscopy data). Annealing in the same conditions of natural tourmalines is consistent with these results. FTIR spectroscopy shows that oxidation of Fe²⁺ into Fe³⁺ is charge-balanced by deprotonation of the external OH₍₃₎ groups. To cite this article: Y. Fuchs et al., C. R. Geoscience 334 (2002) 245–249.  相似文献   

巴音宝力格隆起带中新生代盆地砂岩型铀矿成矿地质条件及远景分析   总被引：2，自引：2，他引：2  

李国新  孙泽轩  姚毅锋  黄大友 《铀矿地质》2003,19(3):148-153

本根据野外调查及室内系列编图成果，分析了巴音宝力格隆起带中新生代盆地砂岩型铀矿成矿地质条件，认为下白里统巴彦花组是中新生代盆地的找矿目的层位，并存在古河道与潜水层间氧化带两种砂岩型铀矿类型。巴彦毛都、准巴彦塔拉、乌里雅斯太和伊勒门盆地是形成砂岩型铀矿的远景盆地。  相似文献   

光催化氧化法处理难降解废水的研究进展   总被引：8，自引：3，他引：8  

梁喜珍  黄国林  陈中胜  覃业贤  郑建英 《华东地质学院学报》2003,26(2):179-182

综述了光催化氧化处理难降解废水的研究现状及发展趋势。介绍了影响光催化氧化反应速率的因素及光催化氧化法在处理难降解废水中的应用。  相似文献   

吐哈盆地西南缘地浸砂岩型铀矿地质特征及找矿前景   总被引：7，自引：11，他引：7       下载免费PDF全文

周巧生  李占游 《中国地质》2003,30(2):186-191

通过对近几年来十红滩地区铀矿勘查资料及找矿成果的综合研究，系统阐述了吐哈盆地西南缘十红滩矿床的地质构造、含矿岩系沉积环境、砂体分布、层问氧化带发育特征等铀成矿条件，对矿区南、北矿带控矿层间氧化带分带性、矿体形态、规模、空间展布、铀存在形式、成矿年龄及铀成矿规律进行了详细研究。进一步总结了区域砂岩型铀成矿条件和找矿前景，指出吐哈盆地西南缘随着找矿工作进展可望成为大型地浸砂岩型铀资源基地，并对指导天山造山带及类似地区地浸砂岩型铀矿找矿具有重要意义。  相似文献   

自然电场法在寻找层间氧化带型砂岩铀矿中的应用     

姚毅锋  陈志国 《物探与化探》2003,27(3):187-188

介绍了自然电场形成的原理及在寻找层间氧化带砂岩型铀矿中的应用.根据氧化带与还原带的自然电位变化特征,利用自然电场法可以确定盆地层间氧化带前锋线,由此推测层间氧化带砂岩型铀矿大体空间位置.  相似文献   

A Laboratory and Theoretical Study on the Uptake of SO2 Gas by Large and Small Water Drops Containing Heavy Metal Ions     

A. Heusel-Waltrop  K. Diehl  S. K. Mitra  H. R. Pruppacher 《Journal of Atmospheric Chemistry》2003,44(2):211-223

Laboratory experiments have been carried out to investigate the uptake of sulfur dioxide by water drops containing heavy metal ions where the metal ions serve as catalysts to oxidise the taken up S(IV) into S(VI). During the gas uptake the drops were freely suspended at their terminal velocity in the airstream of the Mainz vertical wind tunnel. Two series of experiments were carried out, one with large millimeter size water drops containing manganese or iron ions, and the other with small water drops containing manganese ions and having radii in hundreds of micron size range. The experimental results were compared against model computations using the Kronig–Brink model and the fully mixed model, modified for the case that heavy metal ions present in the liquid phase act as catalysts for the oxidising process. The results of the model calculations show that there are only small differences between the predicted gas uptake according to the two models. In addition it was found that the experimental obtained results from the uptake of SO₂ by water drops containing heavy metal ions for both, large and small water drops did agree with the model results.  相似文献   

Heavy metal retention in secondary precipitates from a mine rock dump and underlying soil, Dalarna, Sweden   总被引：7，自引：2，他引：7  

Zhixun Lin  Roger B. Herbert Jr. 《Environmental Geology》1997,33(1):1-12

This study investigates the retention of heavy metals in secondary precipitates from a sulfidic mine rock dump and underlying podzolic soils by means of mineralogical and chemical extraction methods. The rock dump, which is at least 50 years old, consists of a 5–10-cm-thick leached zone and an underlying 110–115-cm-thick accumulation zone. Optical microscopy and electron microprobe analyses confirm that pyrrhotite weathering has proceeded much further in the leached horizon relative to the accumulation horizon. The weathering of sulfides in the leached zone has resulted in the migration of most heavy metals to the accumulation zone or underlying soils, where they are retained in more stable phases such as secondary ferric minerals, including goethite and jarosite. Some metals are temporarily retained in hydrated ferrous sulfates (e.g., melanterite, rozenite). Received: 28 October 1996 · Accepted: 24 February 1997  相似文献