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61.
以苯酚和4—溴苯甲酸为原料,合成一种尚未见文献记载的新化合物——4—溴苯甲酸—2,3,4,5,6—五溴苯酯,用无水三氯化铝催化苯酚的全溴化。此产物可望在阻燃剂方面得到应用。 相似文献
62.
Shane M. Ohline Malcolm R. Reid Shamus L.G. Husheer Kim I. Currie Keith A. Hunter 《Marine Chemistry》2007
Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25]. 相似文献
63.
研制了 30 0双向自调导叶透平试验机组 ,安装在 10 0 0活塞式往复流透平试验台上 ,对两种叶轮方案和 6种不同喷咀、扩压器进行了不同活塞行程、不同周期和不同恒定输出电压下性能试验。试验结果表明在喷咀出口角α1=2 1 5°、扩压器入口角α2 =6 5 5°和α1=2 4°、α2 =6 3°组合最佳 ,最高效率达 5 3 3% ,而且在宽广流量系数范围内 ,特别是大流量系数范围内都有较高效率。大大优于常用对称翼透平。将上下游导叶固定 ,变成双向固定导叶透平。用No 1叶轮和 6种导叶出口角组合进行试验。表明最佳导叶出口角为 2 4°~ 30°,最高效率仍达 38 5 % ,比对称翼透平仍高许多 相似文献
64.
In order to investigate the relationships between the change of TCO2, △PCO2 and SST, current, upwelling and biological activities during El Nin(~)o event in the subtropical Pacific, the responses of TCO2 and △PCO2 in surface water in the subtropical Pacific during El Nin(~)o and La Nina have been simulated using a three-dimension carbon cycle model with biota pump. The results of numerical simulations show that TCO2 in sea water increases with reducing of SST during mature phase of El Nin(~)o in the subtropical West Pacific . At the same period , the Kuroshio in this region was weakened , the zonal currents were divergence , the upwelling carried the water with high concentrations of CO2 to the sea surface , so both of TCO2 and △PCO2 in surface water were increased . But TCO2 and △pCO2 were decreased during La Nina period. These simulated results confirmed the observations in 1982/1983 , 1986/1987 ,1991/1995 and 1997/1998 El Nin(~)o events . 相似文献
65.
66.
大庆长垣外围特低渗透扶杨油层CO_2非混相驱油试验研究 总被引:2,自引:0,他引:2
大庆长垣外围有3×108t特低渗透的扶杨油层储量在注水开发条件下难以有效动用,为提高这部分储量的有效动用率,开展了CO2非混相驱油试验研究。PVT测试结果表明,扶杨油层原油较稠,体积系数小,膨胀性和收缩性小,溶解系数较低;CO2驱油细管实验最小混相压力为29 MPa,比原始地层压力高8.6 MPa,现场试验为非混相驱;长岩心实验CO2驱油采收率比注水高4~6个百分点。综合室内可行性评价实验结果看,大庆长垣外围扶杨油层开展CO2驱油试验是可行的,并于2003年初在宋芳屯油田南部开辟了注气试验区,有注气井1口,采出井5口。矿场试验结果表明,CO2驱油能够使特低渗透、裂缝不发育的扶杨油层建立起有效驱动体系,从根本上改善其开发效果,该技术有望成为特低渗透扶杨油层有效动用的可行技术。 相似文献
67.
68.
GPS observations of the ionospheric F2-layer behavior during the 20th November 2003 geomagnetic storm over South Korea 总被引:4,自引:1,他引:3
The ionospheric F2-layer peak density (NmF2) and its height (hmF2) are of great influence on the shape of the ionospheric
electron density profile Ne (h) and may be indicative of other physical processes within the ionosphere, especially those
due to geomagnetic storms. Such parameters are often estimated using models such as the semiempirical international reference
ionosphere (IRI) models or are measured using moderately priced to expensive instrumentation, such as ionosondes or incoherent
scatter radars. Global positioning system (GPS) observations have become a powerful tool for mapping high-resolution ionospheric
structures, which can be used to study the ionospheric response to geomagnetic storms. In this paper, we describe how 3-D
ionospheric electron density profiles were produced from data of the dense permanent Korean GPS network using the tomography
reconstruction technique. These profiles are verified by independent ionosonde data. The responses of GPS-derived parameters
at the ionospheric F2-layer to the 20th November 2003 geomagnetic storm over South Korea are investigated. A fairly large
increase in the electron density at the F2-layer peak (the NmF2) (positive storm) has been observed during this storm, which
is accompanied by a significant uplift in the height of the F2 layer peak (the hmF2). This is confirmed by independent ionosonde
observations. We suggest that the F2-layer peak height uplift and NmF2 increase are mainly associated with a strong eastward
electric field, and are not associated with the increase of the O/N2 ratio obtained from the GUVI instruments aboard the TIMED satellite. It is also inferred that the increase in NmF2 is not
caused by the changes in neutral composition, but is related to other nonchemical effects, such as dynamical changes of vertical
ion motions induced by winds and E × B drifts, tides and waves in the mesosphere/lower thermosphere region, which can be dynamically
coupled upward to generate ionospheric perturbations and oscillations. 相似文献
69.
70.
在夏季分层期间对红枫湖南、北湖湖心的水样进行分层采集,同时测定了分层水样的温度、pH、HCO3-浓度、溶解氧(DO)、叶绿素a(Chl-a)及铵根离子(NH4+)、硝酸根离子(NO3-)、磷酸根离子(PO43-)的浓度,水体中CO2的分压(pCO2)由化学平衡及亨利定律求得。研究结果表明:光合作用、有机质降解及水体热分层是影响红枫湖夏季pCO2分布的主要因素。其中,温水层CO2欠饱和是光合作用吸收CO2引起的,温跃层中pCO2的急剧增加是光合产物降解产生CO2引起的。静水层沉积物附近pCO2最高并且还有持续增加的趋势,说明沉积物中有机质降解是静水层中CO2增加的主要原因,夏季湖底水温较高加快了沉积物中有机质的降解。分层现象使pCO2在水体中的分布差别明显,并且使静水层中CO2得到积累。此外,夏季红枫湖水体中pCO2的变化与NH4+、PO43-的变化密不可分,表现为温水层中光合作用消耗NH4+、PO43-,有机质降解过程伴随NH4+、PO43-的释放。 相似文献