Modeling on adsorption–desorption of trace metals to suspended particle matter in the Changjiang Estuary     

Y. Y. Zhang  E. R. Zhang  J. Zhang 《Environmental Geology》2008,53(8):1751-1766

The uptake and release of trace metals (Cu, Ni, Zn, Cd, and Co) in estuaries are studied using river and sea end-member waters and suspended particulate matter (SPM) collected from the Changjiang Estuary, China. The kinetics of adsorption and desorption were studied in terms of environmental factors (pH, SPM loading, and salinity) and metal concentrations. The uptake of the metals studied onto SPM occurred mostly within 10 h and reached an asymptotic value within 40 h in the Changjiang Estuary. As low pH river water flows into the high pH seawater and the water become more alkaline as it approaches to the seaside of estuary, metals adsorb more on SPM in higher pH water, thus, particulate phase transport of metal become increasingly important in the seaward side of the estuary. The percentage of adsorption recovery and the distribution coefficients for trace metals remained to be relatively invariable and a significant reduction only occurred in very high concentrations of metals (>0.1 mg L⁻¹). The general effect of salinity on metal behavior was to decrease the degree of adsorption of Cu, Zn, Cd, Co, and Ni onto SPM but to increase their adsorption equilibrium pH. The adsorption–desorption kinetics of trace metals were further investigated using Kurbatov adsorption model. The model appears to be most useful for the metals showing the conservative behavior during mixing of river and seawater in the estuary. Our work demonstrates that dissolved concentration of trace metals in estuary can be modeled based on the metal concentration in SPM, pH and salinity using a Kurbatov adsorption model assuming the natural SPM as a simple surfaced molecule.  相似文献   

Bedrock, soils, and hillslope hydrology in the Central Texas Hill Country, USA: implications on environmental management in a carbonate-rock terrain     

C. M. Woodruff Jr  L. P. Wilding 《Environmental Geology》2008,55(3):605-618

The Hill Country of Central Texas, USA, is undergoing rapid socioeconomic development, but environmental management of this region is hampered by misconceptions about local bedrock, soils, terrain, and hydrologic processes. The Hill Country is underlain mostly by Glen Rose Limestone (Lower Cretaceous) and exhibits a stepped terrain, which has been incorrectly attributed to alternating hard and soft bedrock strata. Other characteristics mistakenly attributed to this landscape include thin soils with scant water-retention capabilities, and rapid runoff as the dominant hydrologic process. This report presents new findings: unweathered bedrock is well indurated, but interbeds exhibit variable weathering rates. Recessive slopes (“risers”) on this stepped terrain result from rapid deterioration of strata having generally heterogeneous depositional fabrics (bioturbation and irregular clay partings) in contrast to ledge-forming strata having homogeneous fabrics. A stony regolith is thus formed beneath risers, providing porous and permeable ground that retards runoff and promotes the formation of moderately deep to deep (two-tiered) regolith/soil zones. These surficial materials on local steep slopes compose important natural environmental buffers; they support diverse biota and enhanced geochemical cycling of nutrients; they also exhibit significant water retention and enhanced erosion abatement. Proper land management demands recognition of these attributes in the siting, design, and construction of facilities.  相似文献   

Numerical modeling assessment of three-gate structures for capturing contaminated groundwater     

Paul F. Hudak 《Environmental Geology》2008,55(6):1311-1317

This modeling study evaluated the capability of alternative funnel-and-gate structures with three gates for capturing contaminated groundwater in a hypothetical unconfined aquifer. Simulated interceptor structures were linear and 45 m wide, consisting of three gates and two funnels (walls). One gate occupied the center and two gates occupied the ends of the interceptor structures. The structures, positioned perpendicular to regional groundwater flow, traversed the entire thickness of the aquifer. A total of four structures were evaluated (numbers designate widths of end, center, and end gates, respectively, in meters): 3-3-3, 2-5-2, 1-7-1, and 4-1-4. Particle tracking and zonal water budgets identified shapes of capture zones and discharge patterns for each interceptor structure. A mass transport model, accounting for advection and hydrodynamic dispersion, tested the capability of each structure for capturing a contaminant plume. Results suggest that: time-dependent capture zones underestimate the amount of time to capture a contaminant plume, wide center gates facilitate plume capture, and wide end gates facilitate lateral containment of contaminants. Of the structures simulated, the 2-5-2 configuration was relatively efficient at processing and containing the simulated contaminant plume.  相似文献   

A GPR study of subsidence-creep-fault processes in Morelia, Michoacán, Mexico     

Jorge A. Avila-Olivera  Víctor H. Garduo-Monroy 《Engineering Geology》2008,100(1-2):69-81

In 1983, inhabitants of the City of Morelia, Michoacán, Mexico, began to observe a series of differential settlements causing damages to constructions along linear trends parallel to a system of regional faults. The same phenomenon occurs in others cities of the Mexican Volcanic Belt (MVB), such as Celaya, Aguascalientes, and Querétaro, and is linked to a structurally controlled subsidence, caused by groundwater withdrawal, and the presence of geological faults. We define this subsidence type as Subsidence-Creep-Fault Processes (SCFP), based on the necessary elements for their generation, and we studied them through geophysical and geotechnical techniques. In Morelia, the geophysical investigations have been carried out using ground-penetrating radar (GPR). GPR profiles, perpendicular to the axis of the surface fault generated by the SCFP were carried out. The common-offset single-fold profiling was used, with a central frequency of 50 MHz. In all cases it has been possible to visualize a fault plane dividing two blocks, the presence of synthetic and antithetic faults, influence zones from 20 m to 40 m, and a maximum “net throw” of 4 m. Exploration trenches followed the same direction of the profiles obtained with GPR (perpendicular to the axis of the surface fault). These trenches exposed a fault plane dividing two blocks with different lithology, generating a maximum “net throw” of 4.40 m; as well they help in the determination of influence zones that varied from 14 m to 40 m.  相似文献   

Triassic Nb-enriched basalts, magnesian andesites, and adakites of the Qiangtang terrane (Central Tibet): evidence for metasomatism by slab-derived melts in the mantle wedge   总被引：10，自引：0，他引：10  

Qiang Wang  Derek A. Wyman  Jifeng Xu  Yusheng Wan  Chaofeng Li  Feng Zi  Ziqi Jiang  Huaning Qiu  Zhuyin Chu  Zhenhua Zhao  Yanhui Dong 《Contributions to Mineralogy and Petrology》2008,155(4):473-490

New chronological, geochemical, and isotopic data are reported for Triassic (219–236 Ma) adakite-magnesian andesite-Nb-enriched basaltic rock associations from the Tuotuohe area, central Qiangtang terrane. The adakites and magnesian andesites are characterized by high Sr/Y (25–45), La/Yb (14–42) and Na₂O/K₂O (12–49) ratios, high Al₂O₃ (15.34–18.28 wt%) and moderate to high Sr concentrations (220–498 ppm) and ε_ND (t) (+0.86 to +1.21) values. Low enrichments of Th, Rb relative to Nb, and subequal normalized Nb and La contents, and enrichments of light rare earth elements combine to distinguish a group of Nb-enriched basaltic rocks (NEBs). They have positive ε_ND (t) (+2.57 to +5.16) values. Positive correlations between Th, La and Nb and an absence of negative Nb anomalies on mantle normalized plots indicate the NEBs are products of a mantle source metasomatized by a slab melt rather than by hydrous fluids. A continuous compositional variation between adakites and magnesian andesites confirms slab melt interaction with mantle peridotite. The spatial association of the NEBs with adakites and magnesian andesites define an “adakitic metasomatic volcanic series” recognized in many demonstrably subduction-related environments (e.g., Mindanao arc, Philippines; Kamchatka arc, Russia; and southern Baja California arc, Mexico). The age of the Touhuohe suite, and its correlation with Triassic NEB to the north indicates that volcanism derived from subduction-modified mantle was abundant prior to 220 Ma in the central Qiangtang terrane.  相似文献   

City senses: On the radical possibilities of pragmatism in geography     

Gary Bridge 《Geoforum》2008,39(4):1570-1584

This paper explores the radical possibilities of pragmatism for geography using the illustration of arguments concerning a renewed (urban) public realm through the exchange of validity claims in communication. Pressing further the pragmatist possibilities of Habermas’s idea of communicative action it draws on John Dewey’s work, and a range of contemporary pragmatist philosophers, to consider human communicability in its widest sense. This is then explored using an example of the spatiality and performativity of body-minds in a range of communicative spaces of the city. Then the paper moves on to consider the radical implications of pragmatism for geography in general in terms of body-mind/environment relations; a transactional view of space; experience, rationality and radical democracy.  相似文献   

Structural elements of the Makran region, Oman sea and their potential relevance to tsunamigenisis     

Mohammad Mokhtari  Iraj Abdollahie Fard  Khaled Hessami 《Natural Hazards》2008,47(2):185-199

The character of convergence along the Arabian–Iranian plate boundary changes radically eastward from the Zagros ranges to the Makran region. This appears to be due to collision of continental crust in the west, in contrast to subduction of oceanic crust in the east. The Makran subduction zone with a length of about 900 km display progressively older and highly deformed sedimentary units northward from the coast, together with an increase in elevation of the ranges. North of the Makran ranges are large subsiding basins, flanked to the north by active volcanoes. Based on 2D seismic reflection data obtained in this study, the main structural provinces and elements in the Gulf of Oman include: (i) the structural elements on the northeastern part of the Arabian Plate and, (ii) the Offshore Makran Accretionary Complex. Based on detailed analysis of these data on the northeastern part of the Arabian Plate five structural provinces and elements—the Musendam High, the Musendam Peneplain, the Musendam Slope, the Dibba Zone, and the Abyssal Plain have been identified. Further, the Offshore Makran Accretionary Complex shown is to consist Accretionary Prism and the For-Arc Basin, while the Accretionary Prism has been subdivided into the Accretionary Wedge and the Accreted/Colored Mélange. Lastly, it is important to note that the Makran subduction zone lacks the trench. The identification of these structural elements should help in better understanding the seismicity of the Makran region in general and the subduction zone in particular. The 1945 magnitude 8.1 tsunamigenic earthquake of the Makran and some other historical events are illustrative of the coastal region’s vulnerability to future tsunami in the area, and such data should be of value to the developing Indian Ocean Tsunami Warning System.  相似文献   

桃山铀矿田桃山断裂及其保矿作用   总被引：2，自引：0，他引：2  

张万良 《地质论评》2008,54(6):768-774

桃山铀矿田位于江西省中部,断裂构造发育,既有成矿构造,也有保矿构造,其中斜贯桃山矿田的桃山断裂即是一保矿构造,它形成于车免近时期,走向北东,倾向南东,右行正断,并具铰链断层性质,上盘地块掀斜下落,致使上盘成矿壳层向NW和NE倾斜,由于倾末端的侵蚀深度较小,保矿条件较好,加强这些地带的铀矿勘查和评价具有重要意义。  相似文献   

南海西部海域新生代构造古地理演化及其对油气勘探的意义   总被引：6，自引：2，他引：4       下载免费PDF全文

谢锦龙  黄冲  向峰云 《地质科学》2008,43(1):133-153

南海西部海域构造复杂,主要发育有北东—北东东向、北西向和近南北向3组深大断裂。其中,北西向断裂与板块汇聚、碰撞有关,多具走滑性质;北东—北东东向断裂具有与中国东部裂谷盆地相似的发育特点,呈张扭性质;近南北向断裂可能是南海在扩张活动期间于洋、陆壳过渡部位形成的走滑调节断裂,是洋盆扩张的西部边界。新生代里,南海经历了4次成盆事件与3期扩张活动,盆地经历了古新世—中始新世陆缘断陷、渐新世—早中新世扩展与中中新世以来的热沉降3个演化阶段。陆缘断陷阶段的充填系列主要是北东—北东东向与北西向的河流—冲积扇、湖泊沼泽等陆相沉积及火山岩等;盆地扩展阶段表现为中-小型断陷、断-坳陷逐渐复合与联合为大-中型坳陷,古地理格局逐渐由河流与湖沼陆相环境演变为滨海至浅海相的沉积环境;热沉降阶段的成盆活动逐渐减弱以至停止,地层表现超覆,盆地出现联合迹象。结合以往勘探与油气资源调查成果分析,认为南海西部海域陆架陆坡区发育的大-中型沉积盆地石油地质条件良好,蕴藏着丰富的油气资源,勘探潜力巨大。  相似文献   

被断裂破坏的盖层封闭能力评价方法及其应用   总被引：3，自引：0，他引：3       下载免费PDF全文

吕延防  万军  沙子萱  付晓飞  付广 《地质科学》2008,43(1):162-174

断层对盖层的破坏主要表现为两个方面:一是减小了盖层的连续封盖面积,二是减小了盖层的厚度。盖层被断层破坏的主要影响因素有断层的断距、倾角和盖层厚度。通过对影响因素研究,提出了盖层有效断接厚度的新概念和计算方法。根据我国部分与断层有关的大-中型气田气柱高度资料,发现了有效断接厚度与所能封闭的最大气柱高度的对数线性关系,并由此提出了评价被断层破坏的盖层封闭能力的新方法。通过对库车坳陷库姆格列木群膏泥岩盖层的应用研究,所得结论与勘探实践完全吻合,证明所提出的评价方法是可行的。  相似文献