Robust Regulation of Alkalinity in Highly Uncertain Continuous Anaerobic Digestion Processes     

Víctor Alcaraz‐González  Fabián Azael Fregoso‐Sanchez  Hugo Oscar Mendez‐Acosta  Victor Gonzalez‐Alvarez 《洁净——土壤、空气、水》2013,41(12):1157-1164

In this paper, a multiple‐input multiple‐output (MIMO) model‐based robust control scheme is proposed for the indirect control of both total alkalinity and the ratio (intermediate alkalinity)/(total alkalinity) by regulating volatile fatty acid concentrations and strong ions concentration, while guaranteeing the so‐called operational stability in anaerobic digestion (AD) processes. The proposed MIMO regulator is an adaptive controller derived from an AD model which incorporates the physicochemical equilibrium of the system as well as the use of a robust interval observer to estimate key process bounds that are used in the computation of the control efforts. Numerical simulations were carried out for a number of operating conditions under the most uncertain scenarios. Results showed that the proposed multivariable control law is able to recover the system stability around a pre‐determined set point in the face of parameter uncertainty and load disturbances.  相似文献   

Adsorption of Complex Pollutants from Aqueous Solutions by Nanocomposite Materials     

Yeoung‐Sheng Wang  Shu‐Huei Hsieh  Chang‐Hung Lee  Jao‐Jia Horng 《洁净——土壤、空气、水》2013,41(6):574-580

In view of water pollutants becoming more complex, both anionic and cationic pollutants need to be removed. The multi‐pollutants simultaneous removal is paid more and more attention. Hence, development composite materials for treatment complex wastewater are the aim of this study. In this research, iron–nickel nanoparticles deposited onto aluminum oxide (α‐Al₂O₃) and carbon nanotubes (CNTs) to form nanocomposite materials Fe–Ni/Al₂O₃ and Fe–Ni/CNTs, respectively, were used as adsorbents. The adsorption capacities of Fe–Ni/Al₂O₃ and Fe–Ni/CNTs for AO7, HSeO, and Pb²⁺ were observed to be 5.46, 8.28, 27.02, and 25.6 mg/g, 15.29 and 17.12 mg/g, separately. The composite materials with negative charges were superior in adsorption of anionic pollutants. Using orthogonal experimental design and analysis of variance to co‐treat dye AO7, HSeO and Pb²⁺ in aqueous solutions, seven testing factors were included: (1) adsorbent types, (2) amount of iron, (3) solution pHs, (4) AO7 concentrations, (5) Pb²⁺ concentrations, (6) HSeO concentrations and (7) reaction time. The experimental results showed that the removal of complex pollutants AO7, HSeO, and Pb²⁺ on Fe–Ni/CNTs could reach up to 90% in the optimal treatment conditions. When using Fe–Ni/CNTs as the adsorbent, the sorption isothermals were well fitted in the Freundlich isotherm, and R² could reach up to 0.98.  相似文献   

Dynamic,Mechanistic, and Thermodynamic Modeling of Zn(II) Ion Biosorption onto Zinc Sequestering Bacterium VMSDCM     

Vishal Mishra  Chandrajit Balomajumder  Vijay K. Agarwal 《洁净——土壤、空气、水》2013,41(9):883-889

The surface of the bacterial cells before the biosorption of Zn(II) ion has been found rough, heterogeneous, and non‐crystalline together with tremendous protrusions and negatively charged functional groups. The bacterium was characterized as rod shaped with Gram‐negative type of cell wall structure. In reaction dynamics, pseudo‐second‐order kinetics with higher linear correlation coefficient (R²) ranging between 0.97 and 0.99, lower sum of square errors (SSE) (0.035–0.081) and chi (χ²) (0.0013–0.009) provided a better explanation of sorption of Zn(II) ion on bacterium surface as compared to pseudo‐first‐order model. The removal of Zn(II) was governed by both film and intra‐particle diffusion at onset and later stage of sorption of metal ion on the surface of bacterial cells. The R² (0.92–0.94) for intra‐particle diffusion model was quite higher with lower values of SSE (9.56–16.33) and chi (χ²) (11.26–19.65) against the Bangham's model. The positive value of ΔH (16.628 × 10^?6 kJ/mol) and ΔS (5320.90 kJ/mol/K) showed that the biosorption of Zn(II) ion across liquid phase on bacterial surface was endothermic with increased randomness at solid–liquid interface. The negative values of ΔG demarcated the whole process as spontaneous in nature. In the present work, the distribution coefficient was found to be > 0.5 at various temperature ranges. At the attainment of equilibrium, the residual concentration of Zn(II) ion in liquid phase was around 0.6 mg/L, which was much below the limit described by United States Environmental Protection Agency (USEPA), i.e. 5 mg/L.  相似文献   

Rhizofiltration of a Heavy Metal (Lead) Containing Wastewater Using the Wetland Plant Carex pendula     

Brijesh K. Yadav  Maarten A. Siebel  Johan J. A. van Bruggen 《洁净——土壤、空气、水》2011,39(5):467-474

Rhizofiltration is a subset technique of phytoremediation which refers to the approach of using plant biomass for removing contaminants, primarily toxic metals, from polluted water. The effective implementation of this in situ remediation technology requires experimental as well as conceptual insight of plant–water interactions that control the extraction of targeted metal from polluted water resources. Therefore, pot and simulation experiments are used in this study to investigate the rhizofiltration of a lead containing wastewater using plants of Carex pendula, a common wetland plant found in Europe. The metal contaminant extraction along with plant growth and water uptake rates from a wastewater having varying Pb concentration is studied experimentally for 2 wk. The temporal distribution of the metal concentration in the wastewater and the accumulated metal in different compartments of C. pendula at the end are analyzed using atomic absorption spectrometry. Parameters of the metal uptake kinetics are deduced experimentally for predicting the metal removal by root biomass. Further, mass balance equations coupled with the characterized metal uptake kinetics are used for simulating the metal partitioning from the wastewater to its accumulation in the plant biomass. The simulated metal content in wastewater and plant biomass is compared with the observed data showing a good agreement with the later. Results show that C. pendula accumulates considerable amounts of lead, particularly in root biomass, and can be considered for the cleanup of lead contaminated wastewaters in combination with proper biomass disposal alternatives. Also, the findings can be used for performing further non‐hydroponics experiment to mimic the real wetland conditions more closely.  相似文献   

Source Based Characterization and Pollution Profile of a Baker's Yeast Industry     

Mustafa Evren Ersahin  Recep Kaan Dereli  Hale Ozgun  Berivan Gunes Donmez  Ismail Koyuncu  Mahmut Altinbas  Izzet Ozturk 《洁净——土壤、空气、水》2011,39(6):543-548

Baker's yeast industry has significant effects on environment due to significant water consumption and high strength wastewater production. Effluents from baker's yeast industry are characterized by high concentrations of biological oxygen demand (BOD₅), chemical oxygen demand (COD), total Kjeldahl nitrogen (TKN), total dissolved solids (TDS), sulfate, and dark brown color. The aim of this study is to provide a detailed quantitative and qualitative identification and characterization of the wastewater sources from different processes of a baker's yeast industry. It is identified that the most polluted wastewater components of the facility are coming from rotary drum filter and evaporation process. However, the highest pollution loads is identified as tank and equipment cleaning effluent due to very high flow rate from this source. The efforts should be on the way to minimize the water usage for the tank and equipment cleaning process, and to recycle less polluted waste streams back to the process.  相似文献   

城市开发区工业与生活混合污水处理设计——以四川省成都市某工业开发区为例     

李娜  罗隆诚  赵绍燕 《地下水》2011,33(2):130-131

城市工业开发区建设时推荐我国工业规模化和产业结构升级的重要措施和手段.但随着而来的是各种各样的工业废水、生活污水汇聚,为城市污水处理厂设计和工艺选择提出了新的要求.文章以四川省成都市为例,生化处理部分采用改良A2/O工艺.结果表明,该工艺具有较好的除氮去磷效果,出水可稳定达到国家<城镇污水处理厂污染物排放标准>(GB1...  相似文献   

低温环境下消化污泥和玉米秸秆强制通风堆肥过程中物理化学和生物学指标的研究     

高孟春  王子超  胡波  王敏  赵从从  杨慧心  田颖  王步英 《中国海洋大学学报(自然科学版)》2011,41(11):13-17

在低温环境下采用强制通风堆肥技术对消化污泥和玉米秸秆进行了堆肥化处理。在环境温度为9～15℃和初始C/N比为19.61情况下,第4天堆体温度达到最高温度60℃,堆体温度保持55℃以上时间为9d。污泥堆肥过程中总有机碳和C/N比下降明显,而NO3--N和重金属含量升高。pH值、电导率、NH4+-N、纤维素酶和脲酶的活性呈先增加后降低的趋势。种子发芽指数在第35天达到84.14%。研究结果表明,消化污泥和玉米秸秆强制通风堆肥在35d达到了腐熟要求。  相似文献   

Provisional Elemental Values for IAEA‐Sewage Sludge by Instrumental Neutron Activation Analysis     

Mohammad Wasim  Mohammad Arif  Sajid Iqbal  Muhammad Daud 《Geostandards and Geoanalytical Research》2013,37(1):87-93

The International Atomic Energy Agency (IAEA) organised a proficiency test (PT), IAEA‐CU‐2010‐02, for the determination of elements in sewage sludge. The PT sample was analysed by semi‐absolute standardless k₀‐instrumental neutron activation analysis (k₀‐INAA). Results for seven elements (As, Co, Cr, Fe, Hg, Se, Zn) were submitted to the IAEA by our laboratory. All of our results were scored ‘acceptable’ by the ‘result evaluation criteria’ adopted by the IAEA. The same analytical methodology produced quantitative results for twenty‐six additional elements. In total, thirty‐six elements were determined with uncertainty varying from 4 to 11%. This paper presents the provisional mass fractions of twenty‐six additional elements (Ag, Al, Br, Ca, Ce, Cl, Dy, Eu, Ga, Hf, I, K, La, Mg, Mn, Na, Rb, Sb, Sc, Sm, Ta, Tb, Th, V, U, W) not reported by the IAEA. The analytical methodology was discussed with important sources of spectral, nuclear and fission‐product interferences. It was shown that the important components of uncertainties were the k₀ factor, Q₀ factor, detector efficiency, mass and counting statistics. The methodology was validated by analysing the IAEA‐S7 reference material.  相似文献   

Natural oligotrophy vs. pollution-induced eutrophy on the SE Mediterranean shallow shelf (Israel): Environmental parameters and benthic foraminifera     

Orit Hyams-Kaphzan  Ahuva Almogi-Labin  Chaim Benjamini  Barak Herut 《Marine pollution bulletin》2009,58(12):1888-1902

The eastern Mediterranean is naturally highly oligotrophic, but urbanization along the Levant coast has led to raised organic and nutrient loads. This study tracks living foraminiferal assemblages at two sites near an activated sewage sludge outfall from 11/2003 to 5/2004. Oligotrophic site PL29 shows seasonal variations in O_2, chlorophyll a, and organic carbon, and has an abundant, diverse benthic foraminiferal assemblage living at various in-sediment depths. At eutrophic site PL3, ∼16 years of sludge injection favor a depleted assemblage primarily of opportunist foraminifera. This site shows less seasonality, is subjected to organic matter overload, O₂-stress, and periodic anoxia, foraminifera are less abundant and diverse, and live at shallower depths. The assemblages at both sites represent a common pool of species, with Ammonia tepida highly dominant. Benthic foraminifera were therefore found to be sensitive to trophic trajectories, respond on sub-seasonal time-scales, and track injection and dispersal of organic loads on the shelf.  相似文献   

Water Quality of the River Yamuna in the Delhi Stretch: Key Determinants and Management Issues   总被引：1，自引：0，他引：1  

Chaman Trisal  Tanveera Tabassum  Ritesh Kumar 《洁净——土壤、空气、水》2008,36(3):306-314

The assessment of water quality of the River Yamuna in the Delhi stretch was carried out by determining changes in the concentration levels of 19 physico‐chemical parameters. It was observed that vegetation plays an important role in acting as a biological sink for mineral nutrients, thereby restoring the water quality. It is proposed that restoration of the inundation pattern of floodplains would greatly help in re‐aeration of the overlying water and re‐absorption of pollutants through mud/water exchanges.  相似文献