Multifacetted study of a cretaceous coal with algal affinities—II. Composition of liquefaction products     

Z. Mudamburi  P.H. Given 《Organic Geochemistry》1985,8(3):221-231

Two hydrogen-rich lithobodies of highly alipathic character from a coal occurring in southwest Utah, have been studied. Bituminite (>50%), vitrinite (25–30%) and liptodetrinite (7–12%) are the principal macerals. The hexane-soluble products of hydrogenating the lithotypes at 400° with tetralin and hydrogen have been analyzed by GC-MS. Products identified include homologous series of alkylated naphthalenes, phenols, furans, cyclohexenones and hydroxy-pyridines. In the case of furans, the alkyl groups extend beyond C₃₀. Materials released by Soxhlet extraction with pyridine consist chiefly of homologous series of fatty acids and their methyl esters and of methyl alkyl ketones, which were not found in the hydrogenation products. The long alkyl chains in these substances can account for about 75% of the alkanes found in the hydrogenation products but not in the extracts. Most of the compounds mentioned in the foregoing are thought to be physically held or trapped in the coal, rather than chemically combined in its macromolecular network. Except for the fatty acids, the origins of these substances are difficult to identify.  相似文献   

Pyrolysis of immature Torbanite and of the resistant biopolymer (PRB A) isolated from extant alga Botryococcus braunii. Mechanism of formation and structure of torbanite     

C. Largeau  S. Derenne  E. Casadevall  A. Kadouri  N. Sellier 《Organic Geochemistry》1986,10(4-6)

Immature Torbanite and the resistant biopolymer (PRB A) isolated from extant B. braunii were previously compared using bulk spectroscopic methods. In the present work, analysis of 400°C pyrolysis products and pyrolysis residues provided further information on their structure and possible relationships. It appears that such polymers are based upon unbranched, saturated, cross-linked hydrocarbon chains up to C₃₁. In addition to these bridging structures, a substantial part of the alkyl chains is singly bound, as esters of unbranched, saturated or cis unsaturated, even fatty acids. These esters are sterically protected, against chemical degradations, by the network of the bioand geopolymer.Quantitative and qualitative observations derived from 400°C pyrolysis confirm that the chemical structure of PRB A and immature Torbanite are closely related. The pyrolysis residues show a similar evolution and numerous common features are noted, with respect to the nature and the distribution of the major constituents of the pyrolysates (hydrocarbons and fatty acids). Accordingly, Botryococcus provides what seems to be the first example of a close structural relationship between a biopolymer produced in large amounts by an extant alga and the geopolymer of an immature kerogen. The essential role of PRB A in Torbanite formation is ascertained. Moreover, it is found that the resistant biopolymer does not undergo important structural changes during the first stages of diagenesis. Thus, owing to steric protection, the esters of immature Torbanite show a distribution quite close to the one of PRB A esters, with exclusively even constituents and a large contribution of unsaturated acids.Recent observations pointed to the possible genesis of some algal kerogens principally by selective preservation of resistant macromolecules. Such a type of formation is clearly predominant in Torbanite, where the bulk of the fossil organic matter corresponds to a selectively preserved and weakly altered, resistant biopolymer, while incorporation of lipids into the kerogen structure during diagenesis seems to play a minor role.  相似文献   

藻类勃发—湖相油源岩形成的一种重要机制   总被引：38，自引：0，他引：38       下载免费PDF全文

刘传联  徐金鲤等 《地质论评》2001,47(2):207-210

浮游藻类是重要的湖相生油母质，本文以渤海湾盆地济阳坳陷早第三纪湖相生油岩为例，研究了其中藻类（主要是颗石藻和沟鞭藻＿化石的分布特征，并通过与现代水体中藻类生产和沉积作用的比较，探讨了生油湖泊中藻类生产和沉积方式及其对油源岩形成所起的控制作用，结果显示，藻类勃发现象在早第三纪生油湖泊中相当普遍，而且贯穿于各类油源岩的形成过程，这类快速事件性沉积是湖相油源岩形成的一种重要机制。  相似文献   

湘黔地区震旦纪菌藻硅质岩特征及形成机理探讨   总被引：7，自引：0，他引：7  

夏文杰  彭军 《矿物岩石》1993,13(3):21-28

湘黔地区震旦纪菌藻硅质岩化学成分纯净,硅质矿物含量95%以上,几乎都为泥晶—微晶石英,石英结晶度平均为6.35。岩石具菌藻生物结构,以纹层状构造为主。其中丰富的菌藻生物化石,按形态可划分为三种类型。岩石属原生沉积成因,二氧化硅的聚沉一方面通过菌藻有机体的硅化作用,另一方面是菌藻生物化学作用引起微环境变化而导致二氧化硅的聚沉。  相似文献   

Biological mechanisms driving the seasonal changes in the internal loading of phosphorus in shallow lakes   总被引：1，自引：6，他引：1  

XIE Ping 《中国科学D辑(英文版)》2006,49(Z1)

Because of the obvious importance of P as a nutrient that often accelerates growth of phytoplankton (including toxic cyanobacteria) and therefore worsens water quality, much interest has been devoted to P exchange across the sediment-water interface. Generally, the release mode of P from the sediment differed greatly between shallow and deep lakes, and much of the effort has been focused on iron and oxygen, and also on the relevant environmental factors, for example, turbulence and decomposition, but a large part of the P variation in shallow lakes remains unexplained. This paper reviews experimental and field studies on the mechanisms of P release from the sediment in the shallow temperate (in Europe) and subtropical (in the middle and lower reaches of the Yangtze River in China) lakes, and it is suggested that pH rather than DO might be more important in driving the seasonal dynamics of internal P loading in these shallow lakes, i.e., intense photosynthesis of phytoplankton increases pH of the lake water and thus may increase pH of the surface sediment, leading to enhanced release of P (especially iron-bound P) from the sediment. Based on the selective pump of P (but not N) from the sediment by algal blooms, it is concluded that photosynthesis which is closely related to eutrophication level is the driving force for the seasonal variation of internal P loading in shallow lakes. This is a new finding. Additionally, the selective pump of P from the sediment by algal blooms not only explains satisfactorily why both TP and PO4-P in the hypereutrophic Lake Donghu declined significantly since the mid-1980s when heavy cyanobacterial blooms were eliminated by the nontraditional biomanipulation (massive stocking of the filter-feeding silver and bighead carps), but also explains why TP in European lakes decreased remarkably in the spring clear-water phase with less phytoplankton during the seasonal succession of aquatic communities or when phytoplankton biomass was decreased by traditional biomanipulation. Compared with deep lakes, wax and wane of phytoplankton due to alternations in the ecosystem structure is also able to exert significant influences on the P exchange at the sediment-water interface in shallow lakes. In other words, biological activities are also able to drive P release from sediments, and such a static P release process is especially more prominent in eutrophic shallow lakes with dense phytoplankton.  相似文献   

浅议浅黄色花岗岩板材在高温条件下变色因素     

邱林  左爱莉  崔晓红 《新疆地质》2006,24(2):146-146,147,148

奇台县菊花黄花岗岩板材,经高温氧-乙炔喷焰烧后呈褐红色薄膜状石材板,使其经济价值增加80%.菊花黄花岗岩板材中的钾长石矿物经高温氧-乙炔喷焰烧后,当其受热达到一定的温度时褐黄色微斜长石中所含的低价铁氧化物中的2价铁离子变为3价铁离子,使岩石的颜色由黄色转化为褐红色,微斜长石由三斜晶系向稳定的单斜晶系转变,由于高于900℃高温作用石材表面时间短,故能在石材表面形成厚约1mm左右的红色薄膜.经褪色强化实验,从理论上推测该红色薄膜石材在大气条件下可保持10年以上不褪色.  相似文献   

超临界萃取技术在生物资源开发和有机废水处理中的应用研究   总被引：1，自引：0，他引：1  

刘华 《矿物岩石地球化学通报》1998,(1)

超临界萃取技术在生物资源开发和有机废水处理中的应用研究＠刘华￥中国科学院地球化学研究所超临界ＣＯ＿２萃取,有机废水处理,珊瑚姜油,辣椒色素超临界萃取技术在生物资源开发和有机废水处理中的应用研究刘华（中国科学院地球化学研究所,贵阳５５０００２）收稿日期：１９...  相似文献   

发光细菌法在环渤海污水样品遗传毒性检测中的应用     

崔志松  栾晓  高伟  李倩  杨官品  郑立 《海洋与湖沼》2015,46(1):228-232

建立了以经过遗传改造的发光细菌Acinetobacter sp.Rec A为受试物种的环境污染物遗传毒性快速检测方法,该方法最快可在3h内得到毒性评价结果。采用该方法评价了环渤海排污口12份污水样品的遗传毒性。环渤海12个排污口的污水样品均表现出了不同水平的遗传毒性,并呈现出一定的分布特征。其中,高毒水质集中出现在山东半岛污水样品中,中毒水质集中出现在辽东半岛地区,而低毒水质主要集中于京津冀地区。综上,在环渤海的污水样品遗传毒性检测中,这种新型发光细菌法具有快速、灵敏、简便等优点,可为以后近海环境的水质生物毒性检测提供参考依据,具有应用于近海环境水质快速监测与评价的潜力。  相似文献   

浮游植物化学分类法—CHEMTAX运算在南中国海应用的改进和优化   总被引：3，自引：1，他引：2  

王磊  黄邦钦  柳欣  肖武鹏 《海洋学报(英文版)》2015,34(2):124-131

In order to determine the phytoplankton community composition, the modification and optimizing of the CHEMical TAXonomy (CHEMTAX) running was carried out through samples grouping, successive run and ev...  相似文献   

Optical detection of Prorocentrum donghaiense blooms based on multispectral reflectance     

TAO Bangyi  PAN Delu  MAO Zhihu  SHEN Yuzhang  ZHU Qiankun  CHEN Jianyu 《海洋学报(英文版)》2013,32(10):48-56

Prorocentrum donghaiense is one of the most common red tide causative dinoflagellates in the Changjiang （Yangtze） River Estuary and the adjacent area of the East China Sea. It causes large-scale blooms in late spring and early summer that lead to widespread ecologic and economic damage. A means for distinguish- ing dinoflagellate blooms from diatom （Skeletonema costatum） blooms is desired. On the basis of measure- ments of remote sensing refectance [Rrs（λ）] and inherent optical parameters, the potential of using a mul- tispectral approach is assessed for discriminating the algal blooms due to P. donghaiense from those due to S. costatum. The behavior of two reflectance ratios [R1 = Rrs（560）/Rrs（532） and Re = Rrs（708）/Rrs（665）], suggests that differentiation of P. donghaiense blooms from diatom bloom types is possible from the current band setup of ocean color sensors. It is found that there are two reflectance ratio regimes that indicate a bloom is dominated by P. donghaiense; （1） R1 〉 1.55 and R2 〈 1.0 or （2） R1 〉 1.75 and R2 ≥ 1.0. Various sensitivity analyses are conducted to investigate the effects of the variation in varying levels of chlorophyll concentration and colored dissolved organic matter （CDOM） as well as changes in the backscattering ratio （bbp/bp） on the efficacy of this muitispectral approach. Results indicate that the intensity and inherent op- tical properties of the algal species explain much of the behavior of the two ratios. Although backscattering influences the amplitude of Rrs（λ）, especially in the 530 and 560 nm bands, the discrimination between P. donghaiense and diatoms is not significantly affected by the variation of bbp/bp. Since aCDOM （440） in coastal areas of the ECS is typically lower than 1.0 m-1 in most situations, the presence of CDOM does not interfere with this discrimination, even as SCDOM varies from 0.01 to 0.026 nm-1. Despite all of these effects, the dis- crimination of P. donghaiense blooms from diatom blooms based on multispectral measurements of Rrs（λ） is feasible.  相似文献