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51.
E. J. Palin M. T. Dove S. A. T. Redfern C. I. Saniz-Díaz W. T. Lee 《Physics and Chemistry of Minerals》2003,30(5):293-304
As part of a wider study of the nature and origins of cation order–disorder in micas, a variety of computational techniques
have been used to investigate the nature of tetrahedral and octahedral ordering in phengite, K2
[6](Al3Mg)[4](Si7Al)O20(OH)4. Values of the atomic exchange interaction parameters J
n
used to model the energies of order–disorder were calculated. Both tetrahedral Al–Si and octahedral Al–Mg ordering were studied
and hence three types of interaction parameter were necessary: for T–T, O–O and T–O interactions (where T denotes tetrahedral
sites and O denotes octahedral sites). Values for the T–T and O–O interactions were taken from results on other systems, whilst
we calculated new values for the T–O interactions. We have demonstrated that modelling the octahedral and tetrahedral sheets
alone and independently produces different results from modelling a whole T–O–T layer, hence justifying the inclusion of the
T–O interactions. Simulations of a whole T–O–T layer of phengite indicated the presence of short-range order, but no long-range
order was observed.
Received: 8 August 2002 / Accepted: 14 February 2003
Acknowledgements The authors are grateful to EPSRC (EJP) and the Royal Society (CIS) for financial support. Monte Carlo simulations were performed
on the Mineral Physics Group's Beowulf cluster and the University of Cambridge's High Performance Computing Facility. 相似文献
52.
53.
54.
A two-layer primitive equation model is developed in this paper. The capabilities of this model aretested by the use of multiyearly averaged January and July sea surface level pressure fields and windfields which can be diagnosed from the pressure fields. The results show that the ocean surface currentsand undercurrents in the second layer driven by the sea surface wind and the sea surface pressure areclose to the observation. The results are also compared with that of the IAP OGCM and the OSUOGCM. 相似文献
55.
人工神经网络与分析测试技术的研究与发展 总被引:8,自引:0,他引:8
回顾了人工神经网络研究的发展历程,简要介绍了神经网络模型与算法,对分析测试技术和相关学科中的人工神经网络研究及在流程控制、错误诊断、参数估计、传感器模型、模式识别与分类、环境监测与治理及光谱与化学分析中的应用等作了评述。引用参考文献113篇。 相似文献
56.
本文利用横向各向同性介质(TIM)中的传播矩阵和面波形成条件,导出了面波波慢度方程。对瑞利波给出了各向同性及横向各向同性弹性介质中其相速度的解析解;对于勒夫波,给出了横向各向同性介质中的波慢度方程。 相似文献
57.
Nils-Otto Kitterrød Lars Gottschalk 《Stochastic Environmental Research and Risk Assessment (SERRA)》1997,11(6):459-482
Simulation of multigaussian stochastic fields can be made after a Karhunen-Loéve expansion of a given covariance function.
This method is also called simulation by Empirical Orthogonal Functions. The simulations are made by drawing stochastic coefficients
from a random generator. These numbers are multiplied with eigenfunctions and eigenvalues derived from the predefined covariance
model. The number of eigenfunctions necessary to reproduce the stochastic process within a predefined variance error, turns
out to be a cardinal question. Some ordinary analytical covariance functions are used to evaluate how quickly the series of
eigenfunctions can be truncated. This analysis demonstrates extremely quick convergence to 99.5% of total variance for the
2nd order exponential (‘gaussian’) covariance function, while the opposite is true for the 1st order exponential covariance
function. Due to these convergence characteristics, the Karhunen-Loéve method is most suitable for simulating smooth fields
with ‘gaussian’ shaped covariance functions. Practical applications of Karhunen-Loéve simulations can be improved by spatial
interpolation of the eigenfunctions. In this paper, we suggest interpolation by kriging and limits for reproduction of the
predefined covariance functions are evaluated. 相似文献
58.
Simulation of multigaussian stochastic fields can be made after a Karhunen-Loéve expansion of a given covariance function.
This method is also called simulation by Empirical Orthogonal Functions. The simulations are made by drawing stochastic coefficients
from a random generator. These numbers are multiplied with eigenfunctions and eigenvalues derived from the predefined covariance
model. The number of eigenfunctions necessary to reproduce the stochastic process within a predefined variance error, turns
out to be a cardinal question. Some ordinary analytical covariance functions are used to evaluate how quickly the series of
eigenfunctions can be truncated. This analysis demonstrates extremely quick convergence to 99.5% of total variance for the
2nd order exponential (‘gaussian’) covariance function, while the opposite is true for the 1st order exponential covariance
function. Due to these convergence characteristics, the Karhunen-Loéve method is most suitable for simulating smooth fields
with ‘gaussian’ shaped covariance functions. Practical applications of Karhunen-Loéve simulations can be improved by spatial
interpolation of the eigenfunctions. In this paper, we suggest interpolation by kriging and limits for reproduction of the
predefined covariance functions are evaluated. 相似文献
59.
借助辅助函数的思想, 采用波函数展开法给出了圆弧形凸起地形中隧洞对入射平面SH波影响问题的一个解析解.数值结果表明,凸起地形中隧洞的存在以及隧洞大小,对凸起地形表面运动,以及凸起地形中的隧洞的动应力集中均具有显著影响. 相似文献
60.
Zbigniew Sorbjan 《Boundary-Layer Meteorology》2004,112(1):57-80
The effects of baroclinicity, imposed on the dry mixed layer by the presenceof large-scale, horizontal temperature gradients, have been investigated basedon a large-eddy simulation model. The purpose of this investigation is to examinesimultaneous impacts of thermal stratification and shear in the atmospheric boundarylayer. For this purpose, five cases are considered – one barotropic, and four baroclinic.Based on the performed simulations, a new parametrization of the interfacial layer isproposed. The parameterization employs new interfacial scaling, which is valid at thetop of the mixed layer. In terms of new scales, dimensionless moments characterizingturbulence at the top of the shearless mixed layer are universal constants. In the shearedcase, dimensionless statistics of turbulence are shown to be functions of the interfacialRichardson number. 相似文献