Laboratory study of the rates and products of the phototransformations of naphthalene adsorbed on samples of titanium dioxide,ferric oxide,muscovite, and fly ash     

Chantal Guillard  Hervé Delprat  Can Hoang-van  Pierre Pichat 《Journal of Atmospheric Chemistry》1993,16(1):47-59

The photodegradation of naphthalene (NPH), chosen as a model of polynuclear aromatic pollutants, has been studied in the presence of a layer of four water-insoluble inorganic solids which can be found in the troposphere (TiO₂, Fe₂O₃, muscovite, and a fly ash sample). Direct photolysis of NPH is negligible at >340 nm. Dark adsorption of NPH on TiO₂ (mainly anatase, nonporous, 50 m² g^–1) at 293 K corresponds to a surface coverage ofca. 50% at equilibrium. Under these conditions (saturated surface), the stationary-state photocatalytic degradation reaches 0.4 molecule nm^–2 h^–1 (>340 nm, radiant fluxca. 22 mW cm^–2). Dioxygen is required and its partial pressure in air is such that the degradation is zero order in O₂. Water vapor markedly increases the rate. The other particulates have also an effect, less important than that of TiO₂, however quite noticeable with respect to surface area unit for the fly ash sample which contains 3.2% Fe₂O₃. Apart from 1,4-naphthoquinone, which is the main intermediate product in all cases, 2-naphthol, phthalide, phthaldialdehyde, phthalic acid, acetophenone, benzaldehyde, benzoic acid are also formed on dry TiO₂. Depending on their volatility, these compounds are transferred to the gas phase or remain principally adsorbed on the solid particles where they are further transformed. For instance, phthalic acid (or anhydride) and benzoic acid are generated from 1,4-naphthoquinone. Degradation mechanisms are briefly discussed.  相似文献   

我国风云极轨气象卫星及应用进展     

何锡玉  蔡夕方  朱亚平  张雷 《气象科学进展》2021,(1)

我国风云极轨气象卫星数据,目前已经被应用在天气预报、气候预测、自然灾害、环境监测、科学研究等多个重要领域,为我国国民经济建设、国防建设、防灾减灾和全球许多国家的经济发展做出了重要贡献。本文介绍了我国风云极轨气象卫星的发展历程,重点阐述了目前风云极轨气象卫星在卫星数据预处理、定量产品反演、卫星资料同化等方面的应用研究进展,并展示了第二代风云极轨气象卫星在全球业务观测、大气三维探测、海洋环境监测、数值预报应用等相关典型应用。在国家创新战略发展框架下,根据“国家级气象现代化总体方案”确定的2020年气象卫星及应用发展目标,第二代极轨气象卫星风云三号03批卫星系统工程必将进一步发挥重大支撑作用。  相似文献   

金沙本底站空气质量与颗粒物浓度变化特征分析     

吴栋桥  周登 《气象科学进展》2021,(1)

利用华中区域代表性站点金沙国家大气本底站2007—2018年的PM_2.5、PM₁₀颗粒物质量浓度数据,2019年3月—2019年6月反应性气体数据,对华中区域空气质量进行整体评价,并分析了颗粒物浓度的变化特征及其影响因素。结果表明,反应性气体CO、SO₂、NO、NO₂质量浓度其日平均最大值、平均值均达到一级标准,O₃日平均值超标率为10.6%,PM_2.5超标率为18%,PM₁₀超标率为17%。从颗粒物质量浓度多年变化来看,2007—2013年金沙站大气颗粒物质量浓度属于上升趋势,2013年至今质量浓度呈现下降趋势,风向风速也在一定程度上影响颗粒物的来源。  相似文献   

Enhancement of radon signals in geophysical studies with the track technique     

A. Tidjani  M. Monnin  J -L. Seidel 《Pure and Applied Geophysics》1990,132(3):495-504

The existence of a suspected geological fault has been confirmed using Solid State Nuclear Track Detectors (SSNTDs) by measuring radon concentration variations in the upper soil above its inferred position. The results obtained prompted us to increase the natural radon signal in the soil, using an additional radon source; this enhancement technique, has been experimentally checked with SSNTD detectors.On leave from Faculté des Sciences, Laboratoire des D.S.T.N. Université de Dakar, Dakar-Fann, Sénégal  相似文献   

Seasonal variation of atmospheric dimethylsulfide at Amsterdam Island in the southern Indian Ocean     

B. C. Nguyen  N. Mihalopoulos  S. Belviso 《Journal of Atmospheric Chemistry》1990,11(1-2):123-141

Daily measurements of atmospheric concentrations of dimethylsulfide (DMS) were carried out for two years in a marine site at remote area: the Amsterdam Island (37°50S–77°31E) located in the southern Indian Ocean. DMS concentrations were also measured in seawater. A seasonal variation is observed for both DMS in the atmosphere and in the sea-surface. The monthly averages of DMS concentrations in the surface coastal seawater and in the atmosphere ranged, respectively, from 0.3 to 2.0 nmol l^-1 and from 1.4 to 11.3 nmol m^-3 (34 to 274 pptv), with the highest values in summer. The monthly variation of sea-to-air flux of DMS from the southern Indian Ocean ranges from 0.7 to 4.4 mol m^-2 d^-1. A factor of 2.3 is observed between summer and winter with mean DMS fluxes of 3.0 and 1.3 mol m^-2 d^-1, respectively.  相似文献   

大理州2005年初夏干旱成因探析     

高安生  陈红玉  黄玮 《云南地理环境研究》2006,18(3):34-39,57

大理州2005年初夏出现了严重干旱气象事件.从500pHa高空环流特征、500pHa距平场特征、西太平洋副高特征量及北太平洋中低纬海温距平场、OLR距平场对这次干旱的成因进行了分析,分析结果表明：2005年初夏（4月1日～6月10日）降水异常偏少气温明显偏高是发生干旱的主要原因,高空大气环流异常、西太平洋副高持续偏强偏西、冷空气活动偏北是导致干旱的直接原因;孟加拉湾南部4月OLR场呈明显正距平,抑制低值系统的发展和东北移影响云南,是影响2005年大理初夏干旱重要原因;北太平洋中低纬海温特征与大理州初夏干旱有一定的遥相关性.  相似文献   

区域复合生态系统分析及其可持续发展对策     

杨国华  周永章  郑奔 《云南地理环境研究》2006,18(6):26-29

从系统物质循环角度分析了人类社会-经济-自然复合生态系统不可持续发展的原因是由于大量生产-大量消费-大量废弃的线性生产和消费模式耗用了大量资源，产生太多的废弃物，破坏了复合系统正常的物质代谢。提出系统调节，实现系统可持续发展的途径，包括控制人口增长，适度消费；调整复合系统生产链的数量结构和比例关系；建立协调的结构网络关系，构建循环型社会。  相似文献   

Tectonically driven fluid flow and associated low-grade metamorphism during the Alpine compression in the eastern Iberian Chain (Spain)     

J.D. Martín-Martín  J. Tritlla  E. Cardellach  D. Gmez-Gras 《Journal of Geochemical Exploration》2006,89(1-3):267

Fluid inclusions and clay mineralogy of the Permo-Triassic rocks from the Espina and Espadà Ranges (SE Iberian Chain, Spain) have been investigated to establish their relationship with hydrothermal fluid circulation during the Alpine Orogeny. Primary fluid inclusions in quartz-filled tension gashes in Permo-Triassic sandstones reveal maximum temperatures around 230 °C and very constant salinities of 8.5% wt. eq. NaCl. Secondary fluid inclusions found in quartz from the Santonian Ba–Cu–Hg deposits show similar compositional and thermodynamic characteristics, denoting an Alpine recrystallization. Clay mineral composition of Permo-Triassic mudrocks is characterized by pyrophyillite, indicating low-grade metamorphic conditions. Field observations and experimental data suggest that the crystallization of quartz in tension gashes, the formation of secondary fluid inclusions and the development of the metamorphism are contemporaneous and related to fluid circulation during the Alpine compression. Fluid flow took place along the Hercynian fault system that was reactivated during the Mesozoic rift stage and inverted during the Alpine deformation.  相似文献   

Rodent paleofaunas as indicators of climatic change in Europe during the last 125,000 years     

Manuel Hernández Fernández 《Quaternary Research》2006,65(2):308-323

This paper presents a quantitative reconstruction of the European late Pleistocene paleoclimate based on 72 rodent assemblages of five sequences from France, Germany and Bulgaria, covering the last interglacial-glacial cycle. They show a pattern of severe changes in temperature, with reduced precipitation during the coldest periods. A tentative correlation between the isotopic and palynological records and the paleotemperature changes is shown. These changes are consistent with variations in atmospheric circulation patterns in response to an expanding-retracting Fennoscandian ice-sheet. They can be attributed to the enhancement-weakening of the Scandinavian-Polar anticyclone and its associated dry winds, the south-north shifting of the North Atlantic Polar Front, and the varying supply of moist air from the Atlantic. Qualitative paleoenvironmental analysis shows broadleaved-deciduous forests in France and Bulgaria during most of the studied period. Taiga and tundra appeared in eastern France during the lower Würm. The German sequence indicates the presence of coniferous forests. These results are broadly consistent with other paleobiological records (mammalian, avian and insect faunas, isotopic record in dental tissue, palynology). The main discrepancies with the paleoclimate inferred from the palynological record are found during the coldest periods and are probably due to the interaction between vegetation, climate, and atmospheric CO₂ levels.  相似文献   

Abrupt climate change: An alternative view   总被引：2，自引：0，他引：2  

Carl Wunsch 《Quaternary Research》2006,65(2):191-203

Hypotheses and inferences concerning the nature of abrupt climate change, exemplified by the Dansgaard-Oeschger (D-O) events, are reviewed. There is little concrete evidence that these events are more than a regional Greenland phenomenon. The partial coherence of ice core δ¹⁸O and CH₄ is a possible exception. Claims, however, of D-O presence in most remote locations cannot be distinguished from the hypothesis that many regions are just exhibiting temporal variability in climate proxies with approximately similar frequency content. Further suggestions that D-O events in Greenland are generated by shifts in the North Atlantic ocean circulation seem highly implausible, given the weak contribution of the high latitude ocean to the meridional flux of heat. A more likely scenario is that changes in the ocean circulation are a consequence of wind shifts. The disappearance of D-O events in the Holocene coincides with the disappearance also of the Laurentide and Fennoscandian ice sheets. It is thus suggested that D-O events are a consequence of interactions of the windfield with the continental ice sheets and that better understanding of the wind field in the glacial periods is the highest priority. Wind fields are capable of great volatility and very rapid global-scale teleconnections, and they are efficient generators of oceanic circulation changes and (more speculatively) of multiple states relative to great ice sheets. Connection of D-O events to the possibility of modern abrupt climate change rests on a very weak chain of assumptions.  相似文献