The variation of sediments organic carbon content in Chongming east tidal flat during Scirpus mariqueter growing stage   总被引：1，自引：0，他引：1  

CHEN Hua  WANG Dongqi  CHEN Zhenlou  WANG Jun  XU Shiyuan 《地理学报》2005,15(4):500-508

The investigations on the organic carbon (OC) of core sediments were carried out in Chongming east tidal flat (CM) during Scirpus mariqueter growing stage (from April to December 2004) in Yangtze Estuary. The Yangtze River annually transports a runoff discharge of 30,000 m3/s, carrying about 480 million tons of sediments to the estuarine and coastal area, which formed a great OC pool. In the sampling spots, seven quadrats of 50 cm × 50 cm and five sediments cores of 20 cm deep (40 cm deep in December) were randomly established in order to collect vegetations and core sediments samples during the low tide each month except November. After pretreatment, the core sediments were sieved and their OC contents were measured according to the potassium dichromate method. The results show that the higher surface sediment OC content in summer comes from allochthonous terrigenous particle settlements on the Chongming east middle tidal flat S. mariqueter zone. In autumn and winter, the decomposing of the defoliated S. mariqueter increases the surface sediments OC content. Settling velocity, sediment temperature and S. mariqueter growth are the main factors that can control the sediment carbon content. Summer is the "carbon losing" period of the tidal flat sediments, while from September, it changes into the "carbon accumulating" period of sediment OC pool because of the decomposing of dead S. mariqueter community in the sediments. From this alternation of "carbon losing" period and "carbon accumulating" period, we conclude that carbon in the OC pool of the middle tidal flat S. mariqueter zone sediments mainly comes from the atmospheric carbon rooted by S. mariqueter photosynthesis.  相似文献   

Effect of vegetation with different evolution degree on soil organic matter in a semi-arid environment (Cabo de Gata-Níjar Natural Park, SE Spain)     

V. Aranda  C. Oyonarte 《Journal of Arid Environments》2005,62(4):631-647

The organic matter of the surface horizons of soils developed below scrub vegetation in a Mediterranean semi-arid area of great environmental interest (Cabo de Gata-Níjar Natural Park, SE Spain) has been studied. The study mainly concentrates on examining the influence of two vegetation types, one evolved (according to its successional stage), and the other clearly degraded as a result of prior removal of vegetation. In spite of the homogeneity in the results obtained from the analysis of the organic matter from the soils studied, a relationship may be established between vegetation biotype and characteristics and evolution of the soil organic matter. The evolved vegetation results in the presence in the soil of a somewhat more evolved and stable organic matter (demonstrated by certain chemical and microbiological aspects), resulting in a greater degree of humification, thus favouring the protection of the soil and the ecosystem as a whole. Hence, the presence of degraded vegetation might lead to soil degradation, something that is unsustainable in semi-arid areas that are particularly fragile in nature.  相似文献   

Evolution of Hydrothermal System at the Dizon Porphyry Cu-Au Deposit, Zambales, Philippines     

Akira Imai 《Resource Geology》2005,55(2):73-90

Abstract. Evolution of hydrothermal system from initial porphyry Cu mineralization to overlapping epithermal system at the Dizon porphyry Cu‐Au deposit in western central Luzon, Zambales, Philippines, is documented in terms of mineral paragen‐esis, fluid inclusion petrography and microthermometry, and sulfur isotope systematics. The paragenetic stages throughout the deposit are summarized as follows; 1) stockwork amethystic quartz veinlets associated with chalcopyrite, bornite, magnetite and Au enveloped by chlorite alteration overprinting biotite alteration, 2) stockwork quartz veinlets with chalcopyrite and pyrite associated with Au and chalcopyrite and pyrite stringers in sericite alteration, 3) stringer quartz veinlets associated with molybdenite in sericite alteration, and 4) WNW‐trending quartz veins associated with sphalerite and galena at deeper part, while enargite and stibnite at shallower levels associated with advanced argillic alteration. Chalcopyrite and bornite associated with magnetite in quartz veinlet stockwork (stage 1) have precipitated initially as intermediate solid solution (iss) and bornite solid solution (bnss), respectively. Fluid inclusions in the stockwork veinlet quartz consist of gas‐rich inclusions and polyphase inclusions. Halite in polyphase inclusions dissolves at temperatures ranging from 360d?C to >500d?C but liquid (brine) and gas (vapor) do not homogenize at <500d?C. The maximum pressure and minimum temperature during the deposition of iss and bnss with stockwork quartz veinlets are estimated to be 460 bars and 500d?C. Fluid inclusions in veinlet stockwork quartz enveloped in sericite alteration (stage 2) consist mainly of gas‐rich inclusions and polyphase inclusions. In addition to the possible presence of saturated NaCl crystals at the time of entrapment of fluid inclusions that exhibit the liquid‐vapor homogenization temperatures lower than the halite dissolution temperatures in some samples, wide range of temperatures of halite dissolution and liquid‐vapor homogenization of polyphase inclusions from 230d?C to >500d?C and from 270d?C to >500d?C, respectively, suggests heterogeneous entrapment of gaseous vapor and hypersaline brine. The minimum pressure and temperature are estimated to be about 25 bars and 245d?C. Fluid inclusions in veinlet quartz associated with molybdenite (stage 3) are dominated by gas‐rich inclusions accompanied with minor liquid‐rich inclusions that homogenize at temperatures between 350d?C and 490d?C. Fluid inclusions in vuggy veinlet quartz associated with stibnite (stage 4) consist mainly of gas‐rich inclusions with subordinate polyphase inclusions that do not homogenize below 500d?C. Fluid inclusions in veinlet quartz associated with galena and sphalerite (stage 4) are composed of liquid‐rich two‐phase inclusions, and they homogenize into liquid phase at temperatures ranging widely from 190d?C to 300d?C (suggesting boiling) and the salinity ranges from 1.0 wt% to 3.4 wt% NaCl equivalent. A pressure of about 15 bars is estimated for the dilute aqueous solution of 190d?C from which veinlet quartz associated with galena and sphalerite precipitated. In addition to a change in temperature‐pressure regime from lithostatic pressure during the deposition of iss and bnss with stockwork quartz veinlets to hydrostatic pressure during fracture‐controlled quartz veinlet associated with galena and sphalerite, a decrease in pressure is supposed to have occurred due to unroofing or removal of the overlying piles during the temperature decrease in the evolution of hydrothermal system. The majority of the sulfur isotopic composition of sulfides ranges from ±0 % to +5 %. Sulfur originated from an iso‐topically uniform and homogeneous source, and the mineralization occurred in a single hydrothermal system.  相似文献   

Temperature and pH Dependence of Some Metals Leaching from Fly Ash of Municipal Solid Waste     

Lallan Prasad Gupta    Hodaka Kawahata    Mio Takeuchi  Hidekazu Ohta  Yoshiro Ono 《Resource Geology》2005,55(4):357-372

Abstract. Municipal solid waste combustion leads to concentration of various metals in the solid residue (fly ash) remaining after combustion. These metals pose serious environmental hazard and require proper handling and monitoring in order to control their harmful effects. Leachability of some metals from fly ash was examined in fly ash and Milli-Q water mixture (liquid-to-solid ratio, 100) under various temperature and pH conditions in the laboratory. The leaching experiments conducted for 24 hours showed that pH was generally more important than temperature in controlling the amount of metals leached out of the fly ash. However, at a given pH, rise in temperature led to different degree of (usually one to two fold) enhanced or reduced leaching of metals. Owing to amphoteric nature of oxides of Al, Cr, Pb and Zn, these metals often yielded typical pattern of increase and decrease in their concentrations with change in pH. The extent of leaching of Cr and Pb in our experiments suggests that decrease of pH to acidic range in the case of Pb and to neutral to acidic range for Cr over a long period of storage of fly ash at solid waste dumping site may facilitate leaching of these metals from fly ash, leading to contamination of groundwater to the level that exceeds beyond the level permitted by the environmental laws.  相似文献   

Chemistry and Sulfur Isotopes in a Chert-dominant Sequence around the Stratiform Manganese Deposit of the Noda-Tamagawa Mine, Northern Kitakami Terrane, Northeast Japan: Implication for Paleoceanographic Environmental Setting     

Kosei Komuro    Katsuyuki Yamaguchi  Yoshimichi Kajiwara 《Resource Geology》2005,55(4):337-351

Abstract. Chemistry and sulfur isotopes are analyzed for a series of rocks in the chert‐dominant sequence around the stratiform manganese ore deposit of the Noda‐Tamagawa mine in the northern Kitakami Terrane, northeast Japan. The sequence is litholog‐ically classified into six units in ascending order: lower bedded chert, lower black shale, massive chert, manganese ore, upper black shale, and upper bedded chert. The rocks around the manganese ore deposit exhibit anomalous enrichment in Ni (max. 337 ppm), Zn (102) and U (30) in the upper part of lower bedded chert, Mo (122), Tl (79) and Pb (33) in the lower black shale, MnO, Cu (786) and Co (62) in the manganese ore, and As (247) and Sb (17) in the upper black shale. The aluminum‐normalized profiles reveal zonal enrichment of redox‐sensitive elements around the manganese bed: Zn‐Ni‐Fe‐Mo‐U(‐Co), Tl‐Pb(‐Mo), Mn‐Fe‐Cu‐V‐Cr‐Co(‐Zn) and As‐Sb in ascending order. The uppermost part of the lower bedded chert and black shale exhibit negative Ce/Ce* values, whereas the massive chert, manganese ore and lower part of the upper bedded chert display positive values. The isotopic δ³⁴S values are 0±6 % in the lower part of the lower bedded chert, ‐19 to ‐42 % in the upper part of the lower bedded chert, ‐36 to ‐42 % in the lower black shale, ‐28 to ‐35 % in the massive chert, manganese ore and upper black shale, and ‐23±5 % in the upper bedded chert. Thus, there is a marked negative shift in δ³⁴S values in the lower bedded chert, and an upward‐increasing trend in δ³⁴S through the manganese ore horizon. The present data provide evidence for a change in the paleoceanographic environmental resulting from inflow of oxic deepwater into the stagnant anoxic ocean floor below the manganese ore horizon. This event is likely to have triggered the precipitation of manganese oxyhydroxides. The redistribution of redox‐sensitive elements through the formation of metalliferous black shale and manganese carbonate ore may have occurred in association with bacterial decomposition of organic matter during early diagenesis of initial manganese oxyhydroxides.  相似文献   

古尔班通古特沙漠生物结皮的分布特征   总被引：47，自引：1，他引：47  

张元明  陈晋  王雪芹  潘惠霞  辜智慧  潘伯荣 《地理学报》2005,15(1):53-60

新疆古尔班通古特沙漠是我国最大的固定和半固定沙漠，其间广泛发育着以地衣植物为主的生物结皮，是除种子植物以外的固定沙面的重要生物因子。研究表明，选择适当的时段，应用遥感技术并结合地面调查来研究沙漠生物结皮的空间分布格局是可行的，遥感制图与地面调查的结果基本一致。该沙漠南部是生物结皮最为丰富的区域，各种类型的生物结皮均有充分发育，呈连续分布，但其分布模式向北、向西和向东变得破碎。通过统计生物结皮像元的面积，得到生物结皮覆盖率超过33％的像元面积占研究区总面积的28．7％。生物结皮的分布对地貌部位有较强的选择性，生物结皮的不同发育阶段种类组成亦有较大的差别。  相似文献   

Mercury and methylmercury biogeochemistry in a thawing permafrost wetland complex,Northwest Territories,Canada          下载免费PDF全文

J. Gordon  W. Quinton  B. A. Branfireun  D. Olefeldt 《水文研究》2016,30(20):3627-3638

In arctic and sub‐arctic environments, mercury (Hg), more specifically toxic methylmercury (MeHg), is of growing concern to local communities because of its accumulation in fish. In these regions, there is particular interest in the potential mobilization of atmospherically deposited Hg sequestered in permafrost that is thawing at unprecedented rates. Permafrost thaw and the resulting ground surface subsidence transforms forested peat plateaus into treeless and permafrost‐free thermokarst wetlands where inorganic Hg released from the thawed permafrost and draining from the surrounding peat plateaus may be transformed to MeHg. This study begins to characterize the spatial distribution of MeHg in a peat plateau–thermokarst wetland complex, a feature that prevails throughout the wetland‐dominated southern margin of thawing discontinuous permafrost in Canada's Northwest Territories. We measured pore water total Hg, MeHg, dissolved organic matter characteristics and general water chemistry parameters to evaluate the role of permafrost thaw on the pattern of water chemistry. A gradient in vegetation composition, water chemistry and dissolved organic matter characteristics followed a toposequence from the ombrotrophic bogs near the crest of the complex to poor fens at its downslope margins. We found that pore waters in poor fens contained elevated levels of MeHg, and the water draining from these features had dissolved MeHg concentrations 4.5 to 14.5 times higher than the water draining from the bogs. It was determined through analysis of historical aerial images that the poor fens in the toposequence had formed relatively recently (early 1970s) as a result of permafrost thaw. Differences between the fens and bogs are likely to be a result of their differences in groundwater function, and this suggests that permafrost thaw in this landscape can result in hotspots for Hg methylation that are hydrologically connected to downstream ecosystems. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Contrasting hydrological response of coastal and desert biocrusts          下载免费PDF全文

Giora J. Kidron  Burkhard Büdel 《水文研究》2014,28(2):361-371

Biocrusts abound in southern Israel, covering the Hallamish dune field near Nizzana (NIZ) in the Negev (mean annual precipitation of 95 mm) and the coast of Nizzanim (NIM) near Ashdod (mean annual precipitation of 500 mm). While the hydrological response of the NIZ crust to natural rain events was thoroughly investigated, no data is available on the hydrological response of the NIM crust. Runoff was monitored in runoff plots during the years 2005–2008, and in addition, sprinkling experiments were carried out on NIM and NIZ crusts. For the evaluation of the possible factors that may control runoff initiation, fine content of the parent material, crust thickness, compressional strength, hydrophobicity, surface microrelief, organic matter, biomass (chlorophyll a and total carbohydrates) and the crust's species composition of NIM were studied and compared to that of NIZ. The data showed that in comparison to the NIZ crust that readily generated runoff, no runoff was produced by the NIM crust. This was so despite the fact that (1) Microculeus vaginatus predominated in both crusts, (2) the substantially higher rain intensities in NIM, (3) the greater thickness and higher chlorophyll content and (4) the lower microrelief at NIM in comparison to NIZ. The lack of runoff in NIM was explained by its low amounts of exopolysaccharides that did not suffice to affectively clog the surface and in turn to facilitate runoff initiation. The absence of runoff and its consequences on the NIM ecosystem are discussed. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

基于主体功能区约束的大气污染物总量控制目标分配研究   总被引：1，自引：0，他引：1  

蒋洪强  张静  卢亚灵  刘年磊 《地域研究与开发》2015,(3)

考虑经济发展水平、污染物排放现状、污染物治理水平、空气质量,特别是国家主体功能区环境目标约束等因素,构建大气污染物排放总量分配的指标体系,用改进的等比例分配方法对2015年国家SO2,NOx总量控制目标进行区域分配。分配结果表明:SO2和NOx削减量大的省份主要集中在华北平原及其周围地区,这些地区污染物排放量大、空气质量较差;削减比例较大的地区主要集中在西部地区以及北京、天津2个直辖市,这些地区单位GDP能耗高、工业污染物去除率低、空气质量差;削减量相对较小的地区主要集中在西南和南部一些省份;削减比例较小的地区主要集中在中南部和南部几个省份,这些地区污染物排放量相对较少,空气质量好于其他省份。  相似文献   

Pre‐ and post‐impoundment nitrogen in the lower Missouri River          下载免费PDF全文

Dale W. Blevins  Donald H. Wilkison  Shelley L. Niesen 《水文研究》2014,28(4):2535-2549

Large water‐sample sets collected from 1899 through 1902, 1907, and in the early 1950s allow comparisons of pre‐impoundment and post‐impoundment (1969 through 2008) nitrogen concentrations in the lower Missouri River. Although urban wastes were not large enough to detectably increase annual loads of total nitrogen at the beginning of the 20^th century, carcass waste, stock‐yard manure, and untreated human wastes measurably increased ammonia and organic‐nitrogen concentrations during low flows. Average total‐nitrogen concentrations in both periods were about 2.5 mg/l, but much of the particulate‐organic nitrogen, which was the dominant form of nitrogen around 1900, has been replaced by nitrate. This change in speciation was caused by the nearly 80% decrease in suspended‐sediment concentrations that occurred after impoundment, modern agriculture, drainage of riparian wetlands, and sewage treatment. Nevertheless, bioavailable nitrogen has not been low enough to limit primary production in the Missouri River since the beginning of the 20^th century. Nitrate concentrations have increased more rapidly from 2000 through 2008 (5 to 12% per year), thus increasing bioavailable nitrogen delivered to the Mississippi River and affecting Gulf Coast hypoxia. The increase in nitrate concentrations with distance downstream is much greater during the post‐impoundment period. If strategies to decrease total‐nitrogen loads focus on particulate N, substantial decreases will be difficult because particulate nitrogen is now only 23% of total nitrogen in the Missouri River. A strategy aimed at decreasing particulates also could further exacerbate land loss along the Gulf of Mexico, which has been sediment starved since Missouri River impoundment. In contrast, strategies or benchmarks aimed at decreasing nitrate loads could substantially decrease nitrogen loadings because nitrates now constitute over half of the Missouri's nitrogen input to the Mississippi. Ongoing restoration and creation of wetlands along the Missouri River could be part of such a nitrate‐reduction strategy. Published 2013. This article is a U.S. Government work and is in the public domain in the USA.  相似文献