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121.
The mid to late‐Holocene climates of most of Scotland have been reconstructed from seven peat bogs located across north–south and east–west geographical and climatological gradients. The main techniques used for palaeoclimatic reconstruction were plant macrofossil, colorimetric humification, and testate amoebae analyses, which were supported by a radiocarbon‐based chronology, aided by markers such as tephra isochrons and recent rises in pine pollen and in spheroidal carbonaceous particles (SCPs). Field stratigraphy was undertaken at each site in order to show that the changes detected within the peat profiles were replicable. Proxy climate records were reconstructed using detrended correspondence analysis (DCA) of the plant macrofossil data and a mean water table depth transfer function on the testate amoebae data. These reconstructions, coupled with the humification data, were standardised for each site and used to produce a composite record of bog surface wetness (BSW) from each site. The results show coherent wet and dry phases over the last 5000 years and suggest regional differences in climate across Scotland, specifically between northern and southern Scotland. Distinct climatic cycles are identified, all of which record a millennial‐scale periodicity which can be correlated with previously identified marine and ice core Holocene cycles. The key role of the macrofossil remains of Sphagnum imbricatum, a taxon now extinct on many sites, is discussed in relation to the identified climatic shifts. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
122.
Water pollution from diffuse sources is a problem of increasing concern. Efforts to control diffuse pollution have been confined mainly to agricultural land and forests. Little attention has been paid to sources of diffuse pollution from urban areas. A diffuse nitrate modelling tool (DNMT) has been developed for modelling the fate of nitrate in urban areas. This tool works at the catchment scale and has a modular structure that consists of three components: the hydrological module, the nitrogen cycle module and the nitrate transport module. The hydrological model describes the possible flow pathways. The nitrogen cycle model accounts for the mass balance of nitrate and calculates the amount of nitrate for potential loss. The nitrate transport module simulates the movement of nitrate within and from the soil to the receiving water. This paper demonstrates the development of the tool and its application in the White Cart Water catchment. This implementation of the tool shows that it has a good capability for simulating the fate of nitrate in urban catchments. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
123.
Reforestation of cleared land has the potential to reduce groundwater recharge, salt mobilization and streamflow. Stream salinity change is the net result of changes in stream salt load and streamflow. The net effect of these changes varies spatially as a function of climate, terrain and land cover. Successful natural resource management requires methods to map the spatial variability of reforestation impacts. We investigated salinity data from 2000 bores and streamflow and salinity measurements from 27 catchments in the Goulburn–Broken region in southeast Australia to assess the main factors determining stream salinity and opportunities for management through reforestation. For groundwater systems of similar geology, relationships were found between average annual rainfall and groundwater salinity and between groundwater salinity and low‐flow salinity. Despite its simplicity, we found that the steady‐state component of a simple conceptual coupled water–salt mass balance model (BC2C) adequately explained the spatial variation in streamflow and salinity. The model results suggest the efficiency of afforestation to reduce stream salinity could be increased by more than an order of magnitude through spatial planning. However, appreciable reductions in stream salinity in large rivers through land cover change alone would still require reforestation on an unprecedented scale. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
124.
J. L. Wang  Y. S. Yang 《水文研究》2008,22(21):4274-4286
DRASTIC has drawbacks in groundwater risk assessment that are important in guiding activities to prevention agricultural diffuse groundwater pollution. This paper presents an improved and GIS‐based D‐DRASTIC approach for groundwater nitrate risk assessment from diffuse agricultural sources based on DRASTIC. D‐DRASTIC considers the risk concept, nitrate loading, pollutant transport with runoff, depth to water, net recharge, aquifer media, soil media, topography, impact of the vadose zone media, and the hydraulic conductivity of the aquifer. D‐DRASTIC was developed within an ArcGIS environment and applied to the Upper Bann Catchment, Northern Ireland as a case study. D‐DRASTIC shows that ‘very high’ and ‘high’ zones of groundwater nitrate risk occupy 5% and 11% of the case study area, respectively. When considering groundwater pollution sources and pathways, the results using D‐DRASTIC are helpful in guiding the activities of groundwater pollution prevention at the catchment scale in the context of better implementation of the EU Water Framework Directive. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
125.
Water quality is a key aspect of the Everglades Restoration Project, the largest water reclamation and ecosystem management project proposed in the United States. Movement of nutrients and contaminants to and from Everglades peat porewater could have important consequences for Everglades water quality and ecosystem restoration activities. In a study of Everglades porewater, we observed complex, seasonally variable peat porewater chloride concentration profiles at several locations. Analyses and interpretation of these changing peat porewater chloride concentration profiles identifies processes controlling conservative solute movement at the peat–surface water interface, that is, solutes whose transport is minimally affected by chemical and biological reactions. We examine, with an advection–diffusion model, how alternating wet and dry climatic conditions in the Florida Everglades mediate movement of chloride between peat porewater and marsh surface water. Changing surface water–chloride concentrations alter gradients at the interface between peat and overlying water and hence alter chloride flux across that interface. Surface water chloride concentrations at two frequently monitored sites vary with marsh water depth, and a transfer function was developed to describe daily marsh surface water chloride concentration as a function of marsh water depth. Model results demonstrate that porewater chloride concentrations are driven by changing surface water chloride concentrations, and a sensitivity analysis suggests that inclusion of advective transport in the model improves the agreement between the calculated and the observed chloride concentration profiles. Published in 2007 by John Wiley & Sons, Ltd.  相似文献   
126.
Geochemically based hydrograph separation techniques were used in a preliminary assessment to infer how runoff processes change with landscape characteristics and spatial scale (1–233 km2) within a mesoscale catchment in upland Scotland. A two‐component end‐member mixing analysis (EMMA) used Gran alkalinity as an assumed conservative tracer. Analysis indicated that, at all scales investigated, acidic overland flow and shallow subsurface storm flows from the peaty soils covering the catchment headwaters dominated storm runoff generation. The estimated groundwater contribution to annual runoff varied from 30% in the smallest (ca 1 km2) peat‐dominated headwater catchment with limited groundwater storage, to >60% in larger catchments (>30 km2) with greater coverage of more freely draining soils and more extensive aquifers in alluvium and other drift. This simple approach offers a useful, integrated conceptualization of the hydrological functioning in a mesoscale catchment, which can be tested and further refined by focused modelling and process‐based research. However, even as it stands, the simple conceptualization of system behaviour will have significant utility as a tool for communicating hydrological issues in a range of planning and management decisions. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   
127.
To investigate the influence of diagenetic water media on the hydrogen isotopes of individual sedimentary aromatic compounds, a series of hydrous pyrolyses were conducted on herbaceous peat. Polycyclic aromatic hydrocarbons (PAHs) in hydrous pyrolysed samples and their hydrogen isotopic composition characteristics were studied. The aqueous medium demonstrated a significant influence on the hydrogen isotopic composition of the individual PAHs generated during pyrolysis. The results showed that the PAHs formed after pyrolysis in the presence of a saltwater medium with high δD value from a salt lake had a heavy hydrogen isotopic composition. The PAHs formed after pyrolysis in the presence of a fresh water medium with low δD value from a swamp had a light hydrogen isotopic composition. The difference in the average PAH δD value between the two hydrous experiments varied from –174‰ to –109‰, suggesting that the hydrogen isotopic composition of individual sedimentary PAHs can reflect the source of the diagenetic water medium. In addition, a comparative study found that the hydrogen isotopes of PAHs were superior to those of n-alkanes in the same sample for diagenetic water indications. The results indicated that the exchange of water-derived inorganic hydrogen and organic hydrogen was more intensive in freshwater experiments than in saltwater experiments. With an increase in the simulation temperature, the average δD value of PAHs generated in the hydrous simulation experiments showed an increasing trend, reflecting that the δD value of sedimentary PAHs formed with the participation of diagenetic water media was still closely related to the thermal maturity of organic matter. Comparative studies showed that the δD values of different types of organic compounds produced by hydrous pyrolysis of peat were in the order, PAHs > n-alkanes > methane.  相似文献   
128.
In the transformation from tidal systems to freshwater coastal landscapes, plants act as eco-engineering species that reduce hydrodynamics and trap sediment, but nature and timing of the mechanisms of land creation along estuaries remains unclear. This article focuses on the Old Rhine estuary (The Netherlands) to show the importance of vegetation in coastal landscape evolution, predominantly regarding tidal basin filling and overbank morphology. This estuary hosted the main outflow channel of the river Rhine between ca 6500 to 2000 cal bp , and was constrained by peat during most of its existence. This study reconstructs its geological evolution, by correlating newly integrated geological data and new field records to varying conditions. Numerical modelling was performed to test the inferred mechanisms. It was found that floodbasin vegetation and resulting organic accumulation strongly accelerated back-barrier infill, by minimizing tidal influence. After tidal and wave transport had already sufficiently filled the back-barrier basin, reed rapidly expanded from its edges under brackish conditions, as shown by diatom analysis and datings. Reed growth provided a positive infilling feedback by reducing tidal flow and tidal prism, accelerating basin infilling. New radiocarbon dates show that large-scale crevassing along the Old Rhine River – driven by tidal backwater effect – only started as nutrient-rich river water transformed the floodbasin into an Alder carr in a next phase of estuary evolution. Such less dense vegetation promotes crevassing as sediments are more easily transported into the floodbasin. As river discharge increased and estuary mouth infilling progressed, crevasse activity diminished around 3800 to 3000 cal bp , likely due to a reduced tidal backwater effect. The insights from this data-rich Holocene study showcase the dominant role that vegetation may have in the long-term evolution of coastal wetlands. It provides clues for effective use of vegetation in vulnerable wetland landscapes to steer sedimentation patterns to strategically adapt to rising water levels.  相似文献   
129.
泥炭是一种具有多种用途的宝贵自然资源,泥炭中的有机碳储量是研究全球碳库变化及碳循环过程的重要参数。由于泥炭多分布于沼泽中,且泥炭松软含水量大的特性,对于泥炭深度的调查、获取用于测试泥炭原状样品的质量不高,导致泥炭碳储量评价仍存在不确定性和偏差。笔者等在典型泥炭形成地若尔盖沼泽湿地地区,开展了浅钻泥炭调查取样工作,通过在泥炭斑块边缘及中心两种不同沼泽湿地地层开展的试验,验证了轻便钻机在难进入的沼泽湿地的适应性,配套的振动冲击工艺可高质量的获得无扰动的泥炭样品,同时查明了泥炭层的厚度。通过试验初步探索了采用轻便钻机配套振动冲击钻进工艺进行泥炭调查取样的有效性。浅层取样钻探作为泥炭调查取样的一种直接有效的技术手段,可以有效地提高泥炭调查效率和精度,为准确评价泥炭储量数据提供可靠的钻探技术服务支撑。  相似文献   
130.
基于二维运动波模型,建立了一个适用于小流域场次降雨产汇流过程的动力学模型。通过对典型小流域内不同区域(坡顶、坡中及坡底区域及距离流域出口的远近)种植植被时产流过程的数值模拟,分析了小流域内植被分布对产流过程的影响。结果表明:植被分布及其特性对小流域场次降雨产流有较明显的影响;下游区域种植植被的减水效果和延滞洪峰作用优于上游区域,陡坡区域减水效果优于缓坡区域,且郁闭度越大,这种差别越明显;在该研究条件下,下游区的减水效果可达到上游区的3倍;30%郁闭度条件下减水效果可达10%和20%郁闭度条件下的3倍和1.4倍。  相似文献   
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