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21.
Sequential Separation of Uranium,Hafnium and Neodymium from Natural Waters Concentrated by Iron Coprecipitation 
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下载免费PDF全文 Carli A. Arendt Sarah M. Aciego Kenneth W.W. Sims Mark Robbins 《Geostandards and Geoanalytical Research》2015,39(3):293-303
A new ion exchange chromatography method is presented for the isolation of high field‐strength elements (HFSE) from freshwater and seawater samples that have undergone iron coprecipitation. Large volumes of water can be condensed through the application of iron coprecipitation, but clean separation of elements from the precipitate proves difficult. The technique described is a five‐column process designed to separate the HFSE, including rare earth elements such as neodymium and hafnium, before removing the iron and isolating uranium. Subsequent isolation of Nd and Hf was achieved using established ion exchange chromatography methods. The efficacy of our chemistry was verified by measurements of analytical reference materials – both reference solutions and seawater samples – subjected to the chemical separation methods described. Elution results indicate high yields (> 90%) determined by concentration measurements of a known reference material added to each column. Measurement results for isotopic compositions of seawater (U, Nd) and reference solutions (NIST SRM 960, U) were identical within uncertainty to previously published values. Compositions were identical between solutions (Spex CLMS3, Spex PLND2) that underwent different iron coprecipitation procedures. Isotopic determinations for reference materials JNdi‐1 and NIST SRM 960 measured with the mass spectrometers used in this study were in agreement with universally accepted values for these materials, and indicate high precision. 相似文献
22.
Germain Bayon Dominique Birot Claire Bollinger Jean Alix Barrat 《Geostandards and Geoanalytical Research》2011,35(1):145-153
We report on an improved method for determining trace element abundances in seawater and other natural waters. The analytical procedure involves co‐precipitation on iron hydroxides after addition of a Tm spike, and measurement by inductively coupled plasma‐sector field mass spectrometry (ICP‐SFMS). The validity of the method was assessed through a series of co‐precipitation experiments, using ultra‐diluted solutions of a certified rock reference material (BIR‐1). Results obtained for four natural water reference materials (NASS‐5, CASS‐4, SLEW‐3, SLRS‐4) are in agreement with published working values for rare earth elements, yttrium, vanadium and, when available, for hafnium, zirconium, thorium and scandium. A set of proposed values with uncertainties typically better than 8% RSD is proposed for Hf, Zr and Th. 相似文献
23.
Lin Zhang Fuliang Liu Yankun Jia Xiangyang Zhang 《Geostandards and Geoanalytical Research》2013,37(2):189-195
The Institute of Hydrogeology and Environmental Geology, Chinese Academy of Geological Sciences recently prepared four certified reference materials for hydrogen and oxygen stable isotopes in water, which are called ‘China Standard Water' (CSW)‐HO1–HO4 (hereafter referred to as HO1–HO4). These reference materials are intended for calibration purposes and provide reference values of their relative difference in 2H/1H and 18O/16O isotope‐amount ratios expressed in delta notation, normalised to the VSMOW–SLAP scale. The certified values of the reference materials were determined by an interlaboratory comparison of results from eleven participating laboratories. This paper describes in detail the production and certification procedure of the four reference materials. The first analytical data for the reference materials are also provided using a variety of analytical techniques, namely CO2–H2O equilibration and laser spectroscopy for δ18O and Cr reduction, as well as H2–H2O equilibration, laser spectroscopy, and high‐temperature conversion for δ2H. The reference values for materials HO1–HO4 and their associated uncertainties are assigned. 相似文献
24.
RésuméLe district de Betroka, soumis à un climat tropical sec, connaît d’importants problèmes de ressource en eau. Cette situation se traduit pour de nombreux habitants par la consommation d’eau de très mauvaise qualité tant sur le plan physico-chimique, que sur le plan bactériologique. Pour tenter d’améliorer cette situation, le gouvernement malgache a entrepris un programme d’alimentation en eau potable et assainissement en milieu rural (projet 350 forages), cadre du présent travail, afin d’assurer à l’eau destinée à l’alimentation humaine une qualité suffisante en termes bactériologique et minéral. L’étude microbiologique de l’eau souterraine du district de Betroka a confirmé l’absence de bactéries d’origine fécale. L’étude hydrochimique a révélé différents processus conduisant à la minéralisation des eaux souterraines en relation avec : (a) la remontée d’eau saline d’origine profonde à partir des fractures transversales du cisaillement majeur de Betroka, et à partir des failles normales à l’origine du graben de Mangoky et du domaine du massif en dôme et bassin du complexe intrusif d’Ianakafy ; (b) la dissolution des aérosols et embruns marins déposés, dissous par la pluie et entraînés jusqu’aux aquifères ; et (c) l’interaction des eaux météoriques et souterraines avec les minéraux des roches encaissantes (scapolite, phlogopite, biotite, hornblende, pyroxène…) qui pourrait également contribuer à la forte minéralisation observée. 相似文献
25.
《水文科学杂志》2013,58(5)
Abstract The isotopic compositions (18O and D) of groundwater, springs, rivers and lake waters are used to account for the hydrological processes in the area of the closed maar Lake Masoko in Tanzania. Springs and groundwater from the northern, western and southern parts of the lake basin display relatively stable compositions, close to those of the mean precipitation, evidencing their fast infiltration rate. Springs located in the eastern part of the basin have enriched compositions, which are on the mixing line between the ?"non evaporated? water and the evaporated lake water. This underlines the hydraulic continuity between the lake and the eastern springs and supports a previous proposition of grounwater outflow from Lake Masoko. The mixing parts of lake water calculated at each spring are constant through time, evidencing the inertia of the system. Furthermore, the mixing part of the lake water decreases linearly with the distance from the lake, suggesting an homogeneous and continuous aquifer. These observations point to a west to east groundwater flow, in agreement with the altitude of different potentials. 相似文献
26.
RÉSUMÉL’Algérie, depuis longtemps, souffre d’une pénurie des ressources en eau. La stratégie de l’état algérien consiste à augmenter les stocks d’eau en adoptant plusieurs solutions, parmi lesquelles, il y a la construction des barrages et des retenues d’eau. Mais cette solution est confrontée aux conditions météorologiques qui favorisent les pertes par évaporation, surtout dans les régions arides. Ce travail consiste à présenter les premiers essais algériens sur la préservation des plans d’eau, et augmenter ses stocks par la réduction de l’évaporation, en utilisant des substances chimiques à longue chaîne, capable de former une pellicule à l’interface air/eau, appelée « film mono-moléculaire ».Les résultats obtenus ont permis d’enregistrer des taux de réduction de l’évaporation significatifs. Ces taux varient en fonction de la substance utilisée, la durée entre deux applications de la substance et des conditions météorologiques de la région d’étude. 相似文献
27.
《水文科学杂志》2013,58(6)
Abstract Since the beginning of the 1990s, the Aral Sea is made of two separate entities: the Small Aral in the north and the Great Aral in the south. In this study, the water and salt balance of the Great Aral is analysed using newly available data: on the one hand, altimetric data of the sea level provided by the TOPEX/Poseidon satellite; and on the other, climate data provided by the ECMWF and NOAA within the framework of global climate re-analysis. These data indicate that the Great Aral received a mean groundwater inflow of about 4 km3 year-1 between 1993 and 2001. Without this contribution, the Aral Sea would disappear even faster than is being observed today. Moreover, the temporal resolution of the data shows a systematic phase difference between the model prediction and satellite measurements. This phase shift is considered to be due to the formation of temporary lakes between the last station measuring the Amu-Darya discharge and its mouth in the Great Aral. 相似文献
28.
《水文科学杂志》2013,58(6)
Abstract Abstract Various uncertainties are inherent in modelling any reservoir operation problem. Two of these are addressed in this study: uncertainty involved in the expression of reservoir penalty functions, and uncertainty in determining the target release value. Fuzzy set theory was used to model these uncertainties where the preferences of the decision maker for the fuzzified parameters are expressed as membership functions. Nonlinear penalty functions are used to determine the penalties due to deviations from targets. The optimization was performed using a genetic algorithm with the objectives to minimize the total penalty and to maximize the level of satisfaction of the decision maker with fuzzified input parameters. The proposed formulation was applied to the problem of finding the optimal release and storage values, taking Green reservoir in Kentucky, USA as a case study. The approach offers more flexibility to reservoir decision-making by demonstrating an efficient way to represent subjective uncertainties, and to deal with non-commensurate objectives under a fuzzy multi-objective environment. 相似文献
29.
《水文科学杂志》2013,58(6)
Abstract Dissolved oxygen (DO) is one of the most useful indices of river's health and the stream re-aeration coefficient is an important input to computations related to DO. Normally, this coefficient is expressed as a function of several variables, such as mean stream velocity, shear stress velocity, bed slope, flow depth, and Froude number. However, in free surface flows, some of these variables are interrelated, and it is possible to obtain simplified stream re-aeration equations. In recent years, different functional forms have been advanced to represent the re-aeration coefficient for different data sets. In the present study, the artificial neural network (ANN) technique has been applied to estimate the re-aeration coefficient (K 2) using data sets measured at different reaches of the Kali River in India and values obtained from the literature. Observed stream/channel velocity, bed slope, flow depth, cross-sectional area and re-aeration coefficient data were used for the analysis. Different combinations of variables were tested to obtain the re-aeration coefficient using an ANN. The performance of the ANN was compared with other estimation methods. It was found that the re-aeration coefficient estimated by using an ANN was much closer to the observed values as compared with the other techniques. 相似文献
30.
《水文科学杂志》2013,58(4)
Abstract Abstract By use of a coupled ocean–atmosphere–land model, this study explores the changes of water availability, as measured by river discharge and soil moisture, that could occur by the middle of the 21st century in response to combined increases of greenhouse gases and sulphate aerosols based upon the ?IS92a? scenario. In addition, it presents the simulated change in water availability that might be realized in a few centuries in response to a quadrupling of CO2 concentration in the atmosphere. Averaging the results over extended periods, the radiatively forced changes, which are very similar between the two sets of experiments, were successfully extracted. The analysis indicates that the discharges from Arctic rivers such as the Mackenzie and Ob’ increase by up to 20% (of the pre-Industrial Period level) by the middle of the 21st century and by up to 40% or more in a few centuries. In the tropics, the discharges from the Amazonas and Ganga-Brahmaputra rivers increase substantially. However, the percentage changes in runoff from other tropical and many mid-latitude rivers are smaller, with both positive and negative signs. For soil moisture, the results of this study indicate reductions during much of the year in many semiarid regions of the world, such as the southwestern region of North America, the northeastern region of China, the Mediterranean coast of Europe, and the grasslands of Australia and Africa. As a percentage, the reduction is particularly large during the dry season. From middle to high latitudes of the Northern Hemisphere, soil moisture decreases in summer but increases in winter. 相似文献