Infrared estimates of aliphatic kerogen carbon in sedimentary rocks     

H.J. Schenk  E.G. Witte  P.J. Müller  K. Schwochau 《Organic Geochemistry》1986,10(4-6)

An infrared routine has been developed to estimate the aliphatic portion of kerogen carbon in sedimentary rocks. The procedure does not require isolation of the organic matter and is based on a computer-assisted determination of global band areas in the region of the aliphatic carbon-hydrogen stretching vibrations around 2900cm⁻¹. From these integrated absorptions the amount of aliphatic carbon C_al (mg of aliphatic carbon per gram of solvent-extracted rock) is calculated by means of a calibration with model rocks. Carbonate overtones which interfere in the case of limestones are eliminated by comparison to a CaCO₃ standard.The method has been applied to rocks containing kerogens of different types and maturities at TOC levels of 0.5 to 12%. The aliphatic carbon concentrations range from 0.5 to 60mg·g⁻¹ and correlate reasonably well with the residual genetic potentials of the rocks as measured by S₂ values from Rock-Eval pyrolysis. The ratio S₂/C_al is found to decrease with burial depth reflecting a maturity enhanced conversion of aliphatic carbon to fixed aromatic carbon under Rock-Eval conditions.  相似文献   

盆地烃类运移二维二相流动数学模型分析与应用实例   总被引：5，自引：1，他引：5       下载免费PDF全文

陶一川  姜鹏 《地球科学》1995,20(3):314-321

从地质固体系统与流体系统相互作用所形成的能量流、物质流的观点，系统地论述了建立烃类运移主要控制方程，即烃水两相拉格朗日型异常地层压力方程和饱和度方程，研制了开发了烃类运移数值模拟系统，阐明了该耦合系统的要素功能和求解方法，提供了改善系统模拟精度的措施，最后介绍了该模拟系统在松辽盆地东南隆起某测线的应用实例。  相似文献   

塔里木盆地北部油气田水文地质及水文地球化学特征   总被引：1，自引：0，他引：1       下载免费PDF全文

张建林  陶一川  陈荣书  张忠先 《地球科学》1995,4(3)

以实测的流体资料为基础，初步揭示了塔北地区油田水文地质和水文地球化学特征。塔北地区存在两股地下水流，南部生油区为压实水流，由南向北流动，北部为重力水流，由北向南流动，这两股水流交汇于雅克拉和轮南地区，向上封闭式内泄。无论重力水流或压实水流，皆为非海相成因、非浓缩成因溶滤水。表明：油气藏的形成绝大部分是寒武－奥陶纪生油层二次成油的结果。  相似文献   

异常压力与油气分布   总被引：123，自引：2，他引：123  

杜栩  郑洪印 《地学前缘》1995,2(4):137-148

随着油气勘探活动的不断加深，国内外相继发现了许多异常高压油气田。据不完全统计，全世界已发现超压盆地１８０多个，其中１６０多个为富含油气盆地。异常高压油气田约占全球油气田３０％左右，因此，对异常压力的研究，具有举足轻重的意义。本文介绍了异常地层压力的概念、特征及分类；详细论述了异常压力的成因，即烃类生成作用、欠压实作用、液态烃类的裂解作用、粘土矿物的后生成岩作用、构造作用、温度变化等；系统阐述了世界典型含油气盆地的超压形成机制、超压体系中油气初次运移机理以及超压与油气分布关系；并在此基础上，归纳总结出了五种超压油气藏成藏模式，即：（１）位于超压体系中的低渗超压油气藏；（２）位于超压层系中，以礁灰岩（或浊积砂岩）为储层的高压油气藏；（３）位于超压带上倾方向，以退覆三角洲平原和分流河道砂岩为储层的常压或过渡带超压油气藏；（４）位于超压带上、下部的超压油气藏；（５）位于远离超压体系的泄压区常压油气藏，本文对指导、加深新老油气区勘探具有实际应用价值。  相似文献   

Lacustrine basin hydrocarbon exploration – current thoughts     

Barry Jay Katz 《Journal of Paleolimnology》2001,26(2):161-179

Although much of the world's petroleum resource-base is associated with marine systems, regionally lacustrine petroleum systems are important. Individual accumulations may exceed several billion barrels. In each of these cases the oil is derived from a lacustrine source rock and may be produced from either nonmarine or marine reservoir rocks. The purpose of this paper is to describe the factors that control lacustrine source rock development and the nature of lacustrine reservoirs. Lacustrine oils display different physical and chemical characteristics than their marine counterparts. These differences can be related to the nature of their precursor material. Although the nature of the products are different, the geochemical threshold criteria for defining source rocks in both settings are the same because of common expulsion requirements. Commercially significant lacustrine systems require the presence of large, long-lived lakes. Such lake settings are tectonic in origin and restricted to climatic settings where precipitation exceeds evaporation. Within these large lake systems three primary factors determine source rock potential and quality. These factors are primary productivity level, organic preservation potential, and matrix sedimentation rate, which controls the dilution of preserved organic matter. Source rock potential is maximized where both productivity and preservation potential are maximized and sedimentation rate is minimized. To some degree these factors can compensate for each other. Hydrocarbon reservoir potential within lacustrine basins is partially impacted by overall tectonic setting. Within extensional settings, transport distances tend to be limited, with much of the sediment being transported away from the basin. The sediments delivered to the lake are poorly sorted and sedimentologically immature, commonly resulting in poor reservoirs due to both primary properties and their susceptibility to diagenesis. Within rifts better reservoirs tend to develop along platform or flexural margins. Stacking of reservoirs is important in lacustrine systems but baffles and barriers are often present between individual sand units. These barriers form as a result of lake level fluctuations. In compressional settings transport distances tend to be longer, resulting in more mature, better sorted sediments leading to higher quality reservoirs. These reservoirs typically develop in fluvial-deltaic and wave-dominated shoreline settings. Lacustrine carbonate reservoirs are locally important. These carbonates tend to develop during lake level lowstands and are dependent on diagenesis (dissolution and karstification) for porosity and permeability development. Lacustrine reservoirs are often stratigraphically and areally limited and display low individual well production rates. Within pure lacustrine systems exploration opportunities appear to be often restricted by either reservoir presence or quality (i.e., production rates). The best exploration opportunities in lacustrine basins appear to be associated with hybrid systems where a lacustrine source and marine reservoir exist.  相似文献   

Chemical variation from biolipids to sedimentary organic matter in modern oceans and its implication to the geobiological evaluation of ancient hydrocarbon source rocks     

Wang Hongmei  Ma Xiangru  Liu Deng  Yang Xiaofen  Li Jihong 《Frontiers of Earth Science》2007,1(4):399-404

Understanding the dynamics of organic matter in modern marine water columns greatly favors the geobiological evaluation of hydrocarbon source rocks. Biolipids could make great contribution to petroleum hydrocarbons due to their comparable chemical components and the slightly refractory characteristics of biolipids during the microbial/thermal degradation. A variety of environmental factors such as temperature, CO₂ and salinity could affect the biochemical contents in microorganisms. As a result, microorganisms living in a changing environmental condition might have a different contribution to the petroleum formation. Organic carbon flux is shown to bear a positive correlation with the primary productivity only within a certain range of biomass volumes in a specific biohabitat. Furthermore, organic matter is degraded much quickly in a water column with oxic conditions. Therefore, the anoxic condition, along with the enhanced biological productivity, would be one of the significant factors in the formation of high-quality hydrocarbon source rocks. The formation of biofilms and microbial mats favors the preservation of sedimentary organic matter by decreasing the degradation rate of organic matter. Identification of biofilms and microbial mats in sedimentary rocks will thus greatly help to understand the depositional processes of organic matter finally preserved in hydrocarbon source rocks. __________ Translated from Earth Science—Journal of China University of Geosciences, 2007, 32(6): 748–754 [译自: 地球科学—中国地质大学学报  相似文献   

柴达木盆地北缘中侏罗统大煤沟组七段烃源岩有机地球化学特征及生烃潜力   总被引：2，自引：0，他引：2  

刘云田  杨少勇  胡凯  曹剑  边立曾  汪立群  陈琰 《高校地质学报》2007,13(4):703-713

柴达木盆地北缘地区在中侏罗世晚期,即大煤沟组七段(J2d7)时演化至最大湖侵期,发育了一套湖相泥页岩。通过对区内鱼卡煤矿井下样品的实测分析,结合先前报道的研究成果,确认了这套湖相泥页岩为优质烃源岩,藻类体、角质体和孢子体是这套源岩的主要生烃显微组分,有机质类型最好可达II1型。热演化研究表明,该套源岩在不同构造单元处于差异热演化阶段,既可生油亦可生气。虽然J2d7段烃源岩在平面上不同凹陷区具有一定的非均质性,但其生烃潜力,特别是在赛什腾—鱼卡凹陷地区,完全可与我国西北地区其它侏罗系优质烃源岩相媲美。长期以来,下侏罗统烃源岩被认为是柴北缘地区的主要油气源,J2d7段优质烃源岩的确认,对于深化柴北缘地区的油气勘探和地质研究具有重要意义。  相似文献   

柴达木盆地北缘冷湖地区侏罗系-古近系储层流体包裹体特征与油气运移     

颜亮亮  胡凯  曹剑  刘云田  汪立群  杨少勇  彭晓群  陈琰 《华东地质学院学报》2007,30(4):301-308

柴达木盆地北缘冷湖地区的侏罗系—古近系储层是柴北缘地区的重点勘探对象,通过对采自该区7口典型钻井中的储层岩心样品进行流体包裹体分析,揭示了油气运移的一些基本特征。首先,根据储层含油气包裹体丰度的差异,认为冷湖地区并不存在从五号→四号→三号构造的顺层油气运移指向,油气主要自昆特依凹陷呈放射状向构造带运移。其次,储层油气包裹体类型的差异表明,深部侏罗系储层中曾经接受过一期成熟度较低的石油充注,但规模可能有限;冷湖地区可能并不存在大规模的天然气聚集;原油普遍遭受过水洗降解等次生变化。最后,综合包裹体岩相学和显微测温结果,提出本区侏罗系—古近系储层中目前所发现的油气大多为中新世后形成。这些认识为区域油气深入勘探提供了重要的基础参考信息。  相似文献   

大兴安岭摩天岭雨养泥炭沼泽多环芳烃分布特征与来源分析   总被引：3，自引：0，他引：3  

史彩奎  贾益群  王国平 《湿地科学》2007,5(3):260-265

运用气相色谱—质谱(GC-MS)技术对大兴安岭摩天岭(47°22′23″N,120°38′45″E)雨养泥炭沼泽泥炭柱中的多环芳烃(PAHs)污染物进行了分析。结果表明,研究区雨养泥炭沼泽表层PAHs总含量的质量比为1 874.4 ng/g,与国内外雨养泥炭沼泽表层相比,其污染水平相对较高。由于研究区气候冷湿,雨养泥炭沼泽中的有机质腐殖化程度较低,有机碳含量较高,这和其PAHs含量的相关性较小。研究区样品中检测出的PAHs主要以2~3环的多环芳烃为主;由PAHs分子标志物指标分析结果可知,研究区雨养泥炭沼泽PAHs污染物的主要来源是当地森林火灾与大气远距离沉降;沉降的PAHs污染物是原油开采、石油生产和化石燃料燃烧的共同贡献。在距地表15~34 cm处,柱状剖面层的PAHs含量显著增加,这是由于1987年和1998年大兴安岭发生森林火灾树木燃烧所致。  相似文献   

对流层氮氧化物光化学转化特征研究   总被引：10，自引：0，他引：10       下载免费PDF全文

朱彬  孙照渤  安俊岭 《大气科学》2002,26(4):487-495

应用大气光化学模式研究了日间影响NOx光化学转化率的主要物理化学因子.探讨了在不同NMHC/NOx比值时,NOx光化学特征及其转化产物的变化规律.结果表明,影响NOx转化率的主要因子是阳光辐射强度和NMHC/NOx比值.但在NMHC/NOx比值很低时,光强的增加并不能显著提高NOx转化率.温度和初始臭氧浓度对NOx转化率的影响次之.相对湿度对NOx转化率的影响较小.在不同NMHC/NOx比值下,NOx转化特征和产物有很大区别.NMHC/NOx比值高时,产物中PAN＞HNO3.NMHC/NOx比值中(低)时,产物主要是HNO3,PAN等有机氮不到10%(1%).最后初步比较了模拟和观测的NOy组成.  相似文献