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21.
22.
生物源与人为源有机气体氧化形成的二次有机气溶胶(SOA)对气候变化和人类健康具有重要影响。SOA的产生与其前体物研究已取得了一些进展,但由于有机气体之间存在复合相互作用以及SOA形成机制复杂,目前对不同有机气体混合体系中SOA的形成认知还比较匮乏。因此,深入了解有机气体多源、复杂的相互作用,摸清有机气体的大气氧化机制、SOA的形成及影响等对深入理解真实大气有机气体化学演变具有指导意义。本文旨在了解复合体系有机气体氧化生成SOA的相关研究进展。一方面总结了复合体系有机气体产生SOA质量浓度、产率、成分、挥发性、光学性质等的变化,侧重于实验室复合体系有机气体氧化对SOA形成的多重影响以及SOA组成元素、分子构成的变化特征,并总结了目前实验室基于模型对复合体系SOA生成的模拟研究和拟合情况;另一方面探究了环境因素,如相对湿度(RH)、温度(T)以及无机气体,如氮氧化物(NOx)、二氧化硫(SO2)、氨气(NH3)等对复合体系有机气体形成SOA的影响。 相似文献
23.
川西坳陷南段是四川盆地主要的天然气产区之一。前人对该区天然气的来源有多种见解。为了更清楚地认识此地区天然气的来源与运移,本文分析了平落坝、大兴西和白马庙气田16件天然气样品的C1-C4烃及CO2组份的碳同位素组成。所获得的同位素数据结合化学成份和地质资料表明,3个气田的烃类完全是热解成因的,都来源于气田下面的上三叠统烃源岩。这些气田的甲、乙烷碳同位素组成随深度呈不同规律的变化,这些变化归因于烃源岩生烃的热解过程和烃类运移的动力学过程。平落坝气田中侏罗统气藏的烃类大部份形成于烃源岩低成熟和成熟的早期阶段并受到晚期成熟气体的不断补给。平落坝和大兴西气田多数气藏的烃类被认为是从源区垂直向上运移通过上伏地层而进入气藏的,白马庙气田的烃类被认为是沿断裂通道向上侏罗统气藏聚集的。平落坝和大兴西气田的δ^13Cco2值有很宽的分布范围(-10.7‰~-0.7‰),这表明气田的CO2由来自基底的海洋碳酸盐岩无机碳成份和沉积地层的有机碳成份混合而成。这些气田的[He/CH4]-[N2/CH4]值之间和δ^13Cco2-δ^13Cc1值之间的相关性表明,非烃气体在进入气藏前已同烃类很好地混合,并被CH4为主流相的气流携带着向气藏运移。 相似文献
24.
Michael Ivanov Adriano Mazzini Valentina Blinova Elena Kozlova Jan-Sverre Laberg Tatiana Matveeva Marco Taviani Nikita Kaskov 《Marine and Petroleum Geology》2010
Multidisciplinary study of seep-related structures on Southern Vøring Plateau has been performed during several UNESCO/IOC TTR cruises on R/V Professor Logachev. High-resolution sidescan sonar and subbottom profiler data suggest that most of the studied fluid discharge structures have a positive relief at their central part surrounded by depression. Our data shows that the present day fluid activity is concentrated on the top of these “seep mounds”. Number of high hydrocarbon (HC) gas saturated sediment cores and 5 cores with gas hydrate presence have been recovered from these structures. δ13C of methane (between −68 and −94.6‰ VPDB) and dry composition of the gas points to its biogenic origin. The sulfate depletion generally occurs within the upper 30–200 cm bsf and usually coincides with an increase of methane concentration. Pore water δ18O ranges from 0.29 to 1.14‰ showing an overall gradual increase from bottom water values (δ18O ∼ 0.35‰). Although no obvious evidence of fluid seepage was observed during the TV surveys, coring data revealed a broad distribution of living Pogonophora and bacterial colonies on sea bottom inside seep structures. These evidences point to ongoing fluid activity (continuous seepage of methane) through these structures. From other side, considerable number and variety of chemosynthetic macro fauna with complete absence of living species suggest that present day level of fluid activity is significantly lower than it was in past. Dead and subfossil fauna recovered from various seep sites consist of solemyid (Acharax sp.), thyasirid and vesicomyid (cf. Calyptogena sp.) bivalves belonging to chemosymbiotic families. Significant variations in δ13C (−31.6‰ to −59.2‰) and δ18O (0.42‰ and 6.4‰) of methane-derived carbonates collected from these structures most probably related to changes in gas composition and bottom water temperature between periods of their precipitation. This led us to ideas that: (1) seep activity on the Southern Vøring Plateau was started with large input of the deep thermogenic gas and gradually decries in time with increasing of biogenic constituent; (2) authigenic carbonate precipitation started at the near normal deep sea environments with bottom water temperature around +5 °C and continues with gradual cooling up to negative temperatures recording at present time. 相似文献
25.
地震是地壳或岩石圈构造变形的一种方式,施加于边界断层及其活动块体内的力决定了它们的变形方式(伸展、挤压、走滑),而变形(或地震)的空间分布受岩石圈流变学控制,尤其是受断层和其间块体强度以及这些块体与岩石圈耦合作用的控制( Thatcher,2009).而火山岩浆作为低粘度熔体,其活动通常也会产生地震,地震类型和大小与岩... 相似文献
26.
温室气体浓度增加情景下大西洋温盐环流的演变 总被引:2,自引:0,他引:2
温室气体浓度增加(以CO2为主)引起的温盐环流演变在未来气候系统中扮演非常重要的角色.在最新的温室气体排放情景下,利用基于德国马普气象研究所为IPCC第四次评估报告而最新发展的气候模式(ECHAM5/MPIOM),对3种不同的温室气体排放假设(B1,A1B,A2)进行了可靠的数值模拟.在此基础上,就大西洋温盐环流和北大西洋深层水形成的变化,以及北大西洋不同海区的温盐环流对温室气体浓度增加的响应,对模拟结果进行了分析.研究揭示,到21世纪末,在3种CO2排放情景下,温盐环流强度分别减弱了4Sv(1Sv=106m3/s)、5.1Sv、5.2Sv,大体相当于减弱了20%、25%、25.1%.由于全球变暖引起副极地海区表层海水变暖变淡,拉不拉多海(LabradorSea)和丹麦海峡(DenmarkStrait)以南区域的深层对流有所减弱.而在格陵兰-冰岛-挪威海(GINSea)的情况相反,由于北大西洋暖流的增强,通过法鲁海峡(Faro-BankChannel)进入GIN海域的高盐水增加,导致GIN海域上层盐度(密度)增加,进而深层对流加强.在A1B情景下,由于全球变暖北大西洋的深层水生成率从16.2Sv降到了12.9Sv. 相似文献
27.
The C and H isotopic compositions of the methane in more than 160 gas samples from 10 basins in China are presented in this paper.The natural gases are classified as four types: biogenic gas ,bio-thermocatalytic transitional gas, gas associated with condensate oil ,and coal-type gas. The isotopic compositions of these gases closely related to the depositional basins, the types of organic matter,the stages of thermal evolution and the genetic characteristics of different gas reservoirs.Studies of the C and H isotopic compositions of terrigenous natural gases will provide valua-ble information on the prospecting and development of natural gases of different genetic types. 相似文献
28.
Trace gas measurements during aircraft flights in the tropopause region over Europe and North Africa
M. Schmidt R. Borchers P. Fabian G. Flentje W. A. Matthews A. Szabo S. Lal 《Journal of Atmospheric Chemistry》1984,2(2):133-143
During aircraft flights in May 1981 from Munich (40°N) to north of the Spitsbergen Islands (82°N) and to Monrovia, Liberia (6°N), air samples were obtained in the altitude range of 8 to 11 km and during the ascents and descents near the airports. These samples have been analyzed for the trace gas mixing ratios of CH4, CO and N2O. The results of these analyses are presented and discussed.The results provide new evidence of tropospheric-stratospheric exchange events in the vicinity of the subpolar and subtropical tropopause foldings and possibly show a case of transport of CO-enriched air in the upper troposphere above the North Atlantic Ocean. 相似文献
29.
Conclusions Some bituminous coals, mostly of high volatile rank, sampled from various coalfields contained on average 0.5 m3 t–1 nitrogen and 0.13 m3 t–1.Nitrogen is released more readily than methane during coal winning but the volumes of nitrogen released are small compared with ventilation quantities and are only likely to be of significance for detailed oxygen deficiency studies. 相似文献
30.
T. Wang H. Guo D. R. Blake Y. H. Kwok I. J. Simpson Y. S. Li 《Journal of Atmospheric Chemistry》2005,52(3):295-317
We present a 16-month record of ozone (O3), carbon monoxide (CO), total reactive nitrogen (NOy), sulphur dioxide (SO2), methane (CH4), C2 – C8 non-methane hydrocarbons (NMHCs), C1 – C2 halocarbons, and dimethyl sulfide (DMS) measured at a southern China coastal site. The study aimed to establish/update seasonal
profiles of chemically active trace gases and pollution tracers in subtropical Asia and to characterize the composition of
the `background' atmosphere over the South China Sea (SCS) and of pollution outflow from the industrialized Pearl River Delta
(PRD) region and southern China. Most of the measured trace gases of anthropogenic origin exhibited a winter maximum and a
summer minimum, while O3 showed a maximum in autumn which is in contrast to the seasonal behavior of O3 in rural eastern China and in many mid-latitude remote locations in the western Pacific. The data were segregated into two
groups representing the SCS background air and the outflow of regional continental pollution (PRD plus southern China), based
on CO mixing ratios and meteorological conditions. NMHCs and halocarbon data were further analyzed to examine the relationships
between their variability and atmospheric lifetime and to elucidate the extent of atmospheric processing in the sampled air
parcels. The trace gas variability (S) versus lifetime (τ) relationship, defined by the power law, Slnx = Aτ− b, (where X is the trace gas mixing ratio) gives a fit parameter A of 1.39 and exponent b of 0.42 for SCS air, and A of 2.86 and b of 0.31 for the regional continental air masses. An examination of ln[n-butane]/ln[ethane] versus ln[propane]/ln[ethane] indicates that their relative abundance was dominated by mixing as opposed
to photochemistry in both SCS and regional outflow air masses. The very low ratios of ethyne/CO, propane/ethane and toluene/benzene
suggest that the SCS air mass has undergone intense atmospheric processing since these gases were released into the atmosphere.
Compared to the results from other polluted rural sites and from urban areas, the large values of these species in the outflow
of PRD/southern China suggest source(s) emitting higher levels of ethyne, benzene, and toluene, relative to light alkanes.
These chemical characteristics could be unique indicators of anthropogenic emissions from southern China. 相似文献