膨胀石墨吸附重油的热力学研究     

曹晓燕  魏淑伟  杨桂朋  周立敏 《中国海洋大学学报(自然科学版)》2008,38(1):103-106

研究膨胀石墨对模拟海水中重油的吸附热力学行为.结果表明:在293～308 K,含油量为2.172～18.11 mg·dm-3实验浓度范围内,膨胀石墨对模拟海水中重油的吸附是放热过程,吸附等温线符合Freundlich和Langmuir方程.根据热力学函数关系计算出膨胀石墨对模拟海水中重油的标准吸附焓变为-39.49 kJ·mol-1,标准吉布斯自由能变为-22.40～-23.50 kJ·mol-1,说明吸附过程可自发进行.  相似文献   

Silver in Tokyo Bay estuarine waters and Japanese rivers     

Yan Zhang  Hajime Obata  Toshitaka Gamo 《Journal of Oceanography》2008,64(2):259-265

Dissolved and particulate concentrations of silver in Tokyo Bay estuarine waters and Japanese rivers were determined in this study. The dissolved silver concentrations in the surface water of Tokyo Bay range from 5.9 to 15.1 pmol kg⁻¹, which is comparable to those in the surface water of the Japan Sea, but two or three times higher than those in the surface water of the open ocean. However, elevated concentrations of dissolved silver are not found in Tokyo Bay compared with those in other highly urbanized estuaries, such as San Francisco Bay (20∼243 pmol kg⁻¹). In the Tokyo Bay estuary, silver typically exhibits non-conservative mixing behavior, which is a common feature in the other estuaries reported previously. Dissolved silver concentrations decrease with salinity from the rivers to the mouth of Tokyo Bay. Silver is efficiently scavenged by suspended particulates, as evidenced by the high conditional distribution coefficients for silver throughout the estuary (log K_d > 5.0 ± 0.6). The silver fluxes into Tokyo Bay via inflowing rivers and atmospheric deposition were estimated as 83 kg y⁻¹ and 15 kg y⁻¹, respectively. A simple budget calculation shows that the silver supplied from rivers and atmosphere must be rapidly scavenged within the Tokyo Bay estuary.  相似文献   

坠落物体产生的冲击荷载对海底管线的损伤分析     

张海  刘蕊  王秀存  田英辉 《海洋技术学报》2008,27(1):77-80

提出了坠落物体产生的冲击荷载对海底管线的损伤一种简易可行的分析方法。对坠落物体进行分类,然后进行运动形式分析,求得冲击速度,根据动力问题控制方程,使用著名商业软件‘ANSYS/LS-DYNA’,‘LS-DYNA’是世界上最著名的通用显式动力分析程序,对实际的工程算例进行了仿真模拟分析。得到的计算结果与已有经验方程结果是基本一致的。该方法可以和一般风险分析方法一起用作海底管线损伤分析和保护措施校核分析。  相似文献   

Onshore sandbar migration at Tairua Beach (New Zealand): Numerical simulations and field measurements   总被引：1，自引：0，他引：1  

B. van Maanen  P.J. de Ruiter  Giovanni Coco  K.R. Bryan  B.G. Ruessink 《Marine Geology》2008,253(3-4):99-106

We observed the onshore migration (3.5 m/day) of a nearshore sandbar at Tairua Beach, New Zealand during 4 days of low-energy wave conditions. The morphological observations, together with concurrent measurements of waves and suspended sediment concentrations, were used to test a coupled, wave-averaged, cross-shore model. Because of the coarse bed material and the relatively low-energy conditions, the contribution of the suspended transport to the total transport was predicted and observed to be negligible. The model predicted the bar to move onshore because of the feedback between near-bed wave skewness, bedload, and the sandbar under weakly to non-breaking conditions at high tide. The predicted bathymetric evolution contrasts, however, with the observations that the bar migrated onshore predominantly at low tide. Also, the model flattened the bar, while in the observations the sandbar retained its steep landward-facing flank. A comparison between available observations and numerical simulations suggests that onshore propagating surf zone bores in very shallow water (< 0.25 m) may have been responsible for most of the observed bar behaviour. These processes are missing from the applied model and, given that the observed conditions can be considered typical of very shallow sandbars, highlight a priority for further field study and model development. The possibility that the excess water transported by the bores across the bar was channelled alongshore to near-by rip-channels further implies that traditional cross-shore measures to judge the applicability of a cross-shore morphodynamic model may be misleading.  相似文献   

南汇东滩沉积物粒度特征及其与水动力的关系   总被引：2，自引：0，他引：2  

黄广  陈沈良  胡静 《海洋湖沼通报》2008,(1):32-38

沉积物粒度参数可以用来反演沉积物沉积的水动力条件和沉积环境。根据对南汇边滩采集的表层沉积物粒度资料进行分析,结果表明:沉积物类型以黏土质粉砂为主;随着沉积物平均粒径Mz的减小,分选逐渐变好,偏态由极正偏向正偏转变,并向近对称接近。运用Pe- jurp的三角图式对沉积环境进行划分,结果表明南汇东滩的水动力条件总体上较强,沉积物粒径总体上偏粗,属于径流—潮流共同作用的河口浅滩沉积环境。对潮流底应力和沉积物临界起动切应力的计算进一步印证了该区水动力较强,对应沉积物颗粒偏粗的现象。  相似文献   

Impact of Human Activities on Depositional Process of Tidal Flat in Quanzhou Bay of China   总被引：2，自引：0，他引：2  

WANG Aijun 《中国地理科学(英文版)》2007,17(3):265-269

As a very important component of a coastal system,tidal flats come to be a focus of the studies on land-ocean interaction in the coastal zone because those areas are subjected to intense human activities and are highly sensitive to the global change.The Quanzhou Bay,located along the middle part of Fujian coast of China,covers about 136.4km2,and the area of coastal wetland in the entire bay from intertidal to subtidal with 6m of water depth accounts for 96% of the total area.Seven short cores were collected and divided in situ with the interval of 5cm on the coastal wetlands of Quanzhou Bay on April 19,2006.The sediment samples were scattered and the grain sizes were measured by using Mastersizer 2000.Human beings' activities on tidal flat have disturbed the vertical distribution of sediments in stratigraphic sequence and accelerated the sedimentation rates.Grain size analysis results show that the grain size diameters increase and sediment becomes worse sorted towards the sea under the strong human disturbance;Spartina alterniflora can play a role of trapping the fine sediment;but near the bank,the sediment becomes coarse and there are two peak values on frequency curve influenced by the sandpile.The trough formed by human activities along the coastline changes the transport path of water and suspended sediment.The sediments are transported through the trough and deposit in it during the flood;the ebb flow is retarded by the flow output through the adjacent trough,and the deposited sediment can not be re-suspended;then,the sedimentation rate increases.In situ observation show that the sedimentation rate is about 8-10cm/yr.  相似文献   

Member 1 of Yongji Formation (Ey1) sedimentary characteristics and its origin analysis in Yitong Graben     

Changwei CHEN  Linfu XUE  Hongbing DAI  Jian WANG  Xingke XU  Qinglong MENG 《世界地质(英文版)》2007,10(1)

Ey1 has the unique desultory-weak or gap seismic reflection structure as its one of the most important characteristics. It is very important to clarify sedimentary characteristics and its origin for Yitong Graben and its sedimentary facies and tectonic evolution. On the basis of the research of core analyses, well logging data analyses, sedimentary facies analyses and seismic reflection structure analyses, the authors have concluded the sedimentary characteristics of Ey1, and have carried out Ey1 sedimentary environments and its origin. The result shows that Ey1 desultory-weak or gap seismic reflection may be a series of small scale secondary sediment fans superimposition.  相似文献   

Further discussion on the intercomparison of the trace metal concentrations and particle size of fluvial sediment recovered from two centrifuge systems     

S. Santiago  R. L. Thomas  J.-L. Loizeau  P.-Y. Favarger  J.-P. Vernet 《水文研究》1990,4(3):283-287

A single large volume water sample taken at the mouth of the Upper Rhone River on Lake Geneva was processed directly in parallel through two continuous flow centrifuges, a Westphalia and an Alfa-Laval. Sediment was recovered from the Westphalia, and separately from the bowl and brass core of the Alfa-Laval. The three sediment samples were analyzed for particle size and the following elements: Zn, Cu, Mn, Cr, P, Co, B, V, Be, Sr, Na, Pb, Ni, Ba, Fe, Ca, and Mg. Results indicate that the particle size recovery of both machines is similar when sediment from the brass core and bowl of the Alfa-Laval are combined, and that the recovery for all elements other than Cu, V, B, and Pb are the same when the particle size differences are taken into account. Sediment from the Alfa-Laval brass core is clearly contaminated by Cu, B and is also elevated in V and Pb but not to a significant extent. The sediment recovered from the bowl of the Alfa-Laval is contaminated only with Cu, with a 10 ppm increase over the 52 ppm recovered in the Westphalia sediment. Operating procedures involve the discarding of the brass core sediment and the mixing of the Alfa-Laval bowl sediment with that from the Westphalia. The consequent increase in Cu is estimated at less than 5 ppm or within the confidence level of the analysis. These procedures are recommended to all operators of non modified Alfa-Laval units.  相似文献   

Fundamental study for morphodynamic modelling: Sand mounds in oscillatory flows     

P.K. Stansby  J. Huang  D.D. Apsley  M.I. García-Hermosa  A.G.L. Borthwick  P.H. Taylor  R.L. Soulsby 《Coastal Engineering》2009

Experiments on sand mounds in oscillatory flow, undertaken in controlled, large-scale laboratory conditions, have produced well-defined data sets for model comparison. Three bathymetries with different levels of submergence, including a surface-piercing case, were tested. The maximum slope was about 1:5.5. Sediment transport is due to bed load with ripple formation. The principal time-dependent bulk parameters are the vertical distance of the centre of gravity above the base and the volume of the mound. A semi-implicit finite-volume depth-averaged hydrodynamic model is used to drive morphodynamics, using van Rijn's sediment flux model generalized to take account of bed slope, and some justification is given for depth-averaged modeling in these conditions. Starting the model runs with the conditions at the end of the first cycle avoided initial atypical physical behaviour. In general good predictions were obtained with an angle of repose reduced from the standard value of about 30° for stationary beds to 15°. For these situations, morphodynamics was largely unaffected by a hydrodynamic roughness height in the range 2.5D₅₀ to 51D₅₀, with larger values accounting for ripple roughness. The reduced angle of repose may be physically expected with mobile beds but this specific value is only expected to be suited to this form of bed motion. In one case an exaggerated ripple formed near the top of the mound reducing agreement with experiment. For the submerged case with normal ripple structure excellent predictions were obtained. For the initially surface-piercing mound, the time of submergence was better predicted with a 30° angle of repose, presumably due to the prominent influence of the near stationary bed near the wet/dry interface, although long term predictions were better predicted with 15°. The occurrence of vortex shedding in the first cycle modeled was in agreement with experimental observation.  相似文献   

Sediment budget of the Napo River,Amazon basin,Ecuador and Peru     

A. Laraque  C. Bernal  L. Bourrel  J. Darrozes  F. Christophoul  E. Armijos  P. Fraizy  R. Pombosa  J. L. Guyot 《水文研究》2009,23(25):3509-3524

The upstream‐downstream sediment budget along the Napo River (100 520 km², 6300 m³ s^?1) was studied in the Andean foothills of Ecuador, at the west of the Amazon basin. A comparative study was made during four hydrological cycles (2001–2005) for three hydrological stations located upstream, and during one hydrological cycle (2004–2005) for the fourth one located near the mouth of the Napo River (region of Iquitos in Peru). This analysis showed an unusual increase in the concentration of suspended sediment recorded for the western part of the Amazon plain. Like the runoff (81 l s^?1 km²), which is a world's maximum, the erosion rate (1160 t km^?2 year^?1, i.e. 47% of total suspended solid (TSS) export at the exit of Ecuador), one of the highest for a floodplain basin is the result of a stepper slope than in the rest of the Andean foothills, where typically sedimentation phenomena are predominant, and can be explained in part by a greater tectonic activity. Similar phenomenes were evidenced in small mountainous rivers in New Guinea (Milliman and Syvitski, 1992; Milliman, 1995). On the headwaters of the Napo River drainage basin, the tectonic uplift causes the Pastaza Megafan's existence. This progressively diverts the course of Napo River towards north and also provokes the remobilization of fine fluvial deposits. Moreover, this geodynamic trend is completed by the impact of volcanic eruption, earthquakes and landslides. The combination of these phenomena, so common in the region, has provided a large sediment transfer, not only at present but also in the past, as can be confirmed by the presence of incised terraces, mainly formed by volcanic materials. Then, these results were compared with a similar study carried out further south in the Madeira basin at the Bolivian foothills. These studies show the spatio‐temporal variability of the relation between sediment transfer and geodynamic processes at the Andean Piedmont. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献