Constraints on the application of carbon isotope thermometry in high- to ultrahigh-temperature metamorphic terranes   总被引：7，自引：0，他引：7  

M. Satish-Kumar  H. Wada  M. Santosh 《Journal of Metamorphic Geology》2002,20(3):335-350

Nine marble horizons from the granulite facies terrane of southern India were examined in detail for stable carbon and oxygen isotopes in calcite and carbon isotopes in graphite. The marbles in Trivandrum Block show coupled lowering of δ¹³C and δ¹⁸O values in calcite and heterogeneous single crystal δ¹³C values (? 1 to ? 10‰) for graphite indicating varying carbon isotope fractionation between calcite and graphite, despite the granulite facies regional metamorphic conditions. The stable isotope patterns suggest alteration of δ¹³C and δ¹⁸O values in marbles by infiltration of low δ¹³C–δ¹⁸O‐bearing fluids, the extent of alteration being a direct function of the fluid‐rock ratio. The carbon isotope zonation preserved in graphite suggests that the graphite crystals precipitated/recrystallized in the presence of an externally derived CO₂‐rich fluid, and that the infiltration had occurred under high temperature and low f_O2 conditions during metamorphism. The onset of graphite precipitation resulted in a depletion of the carbon isotope values of the remaining fluid+calcite carbon reservoir, following a Rayleigh‐type distillation process within fluid‐rich pockets/pathways in marbles resulting in the observed zonation. The results suggest that calcite–graphite thermometry cannot be applied in marbles that are affected by external carbonic fluid infiltration. However, marble horizons in the Madurai Block, where the effect of fluid infiltration is not detected, record clear imprints of ultrahigh temperature metamorphism (800–1000 °C), with fractionations reaching <2‰. Zonation studies on graphite show a nominal rimward lowering δ¹³C on the order of 1 to 2‰. The zonation carries the imprint of fluid deficient/absent UHT metamorphism. Commonly, calculated core temperatures are > 1000 °C and would be consistent with UHT metamorphism.  相似文献   

Rare earth elements in waters from the albitite-bearing granodiorites of Central Sardinia, Italy   总被引：1，自引：0，他引：1  

Riccardo BiddauRosa Cidu  Franco Frau 《Chemical Geology》2002,182(1):1-14

With the aim of contributing to the knowledge of the geochemical behaviour and mobility of the rare earth element (REE) in the natural water systems, the ground and surface waters of the Ottana-Orani area (Central Sardinia, Italy) were sampled. The study area consists of albititic bodies included in Hercynian granodiorites. The waters have pH in the range of 6.0-8.6, total dissolved solid (TDS) of between 0.1 and 0.6 g/l, and major cation composition dominated by Ca and Na, whereas predominant anions are Cl and/or HCO₃.The pH and the major-element composition of the waters are the factors affecting the concentration of REE in solution. The concentrations of ∑REE+Y in the samples filtered at 0.4 μm vary between 140 and 1600 ng/l, with La of between 14 and 314 ng/l, and Yb of between <6 and 12 ng/l. A negative Ce anomaly, especially marked at high pH, is observed in the groundwaters. The surface waters show lower REE concentrations, which are independent of pH, and negligible Ce anomaly.Speciation calculations, carried out with the EQ3NR computer program, showed that the complexes with the CO₃²⁻ ligand are the dominant REE species at pH in the range of 6.7-8.6. The REE³⁺ ions dominate the speciation at pH <6.7 and only in the light REE (LREE).The relative concentrations of REE in water roughly reflect those in the aquifer host rocks. However, when concentrations of REE in water are normalised relative to the parent rocks, a preferential fractionation of heavy REE (HREE) into the water phase can be observed, suggesting the greater mobility and stability of HREE in aqueous solution.  相似文献   

Timing of Fracture Formation and Duration of Mineralization at the Hishikari Deposit, Southern Kyushu, Japan     

Ryota Sekine    Eiji Izawa  Koichiro Watanabe 《Resource Geology》2002,52(4):395-404

Abstract. The Hishikari epithermal gold deposit consists of the Honko-Sanjin zone and Yamada zone. On the basis of observed crosscutting relationships of veins, vein system in the Hishikari deposit was classified into the early and late veins. They differ from orientation, width, control by unconformity, the amount of displacement and structural features, but have similarity in gold grade and Au/Ag ratios. K-Ar ages are presented for the classified veins to clarify timing of fracturing and duration of mineralization.
Age determination revealed that the early veins in the Honko-Sanjin zone range from 0.86 to 1.11 Ma and that the late veins range from 0.73 to 0. 84 Ma. The economically most important mineralization in the Hishikari deposit occurred around 0.90 Ma in a very short period (about 0.05 million years).
The distribution of mineralization age in the whole Hishikari deposit, occurrences of slickensides and ground water temperatures imply that mineralization lasted longer in the southern part of the deposit. As compared the early veins with late veins, structural changes including width, strike, dip and vein characteristics occurred at around 0.85 Ma.  相似文献   

Validation through HVSR measurements of a method for the quick detection of site amplification effects from intensity data: an application to a seismic area in Northern Italy     

Vera D'Amico  Marco Mucciarelli   《Soil Dynamics and Earthquake Engineering》2002,22(6)

An instrumental validation is attempted of an innovative approach devoted to the quick individuation, from macroseismic data, of site amplification phenomena able to significantly modify seismic hazard levels expected on the basis of average propagation effects only. According to this methodology, two evaluations of hazard are performed at each investigated locality: the former, obtained by epicentral intensity data ‘reduced’ at the site through a probabilistic attenuation function and, the latter, computed by integrating such data with seismic effects actually observed at the site during past earthquakes. The comparison, for each locality, between these two hazard estimates allow to orientate the identification of those sites where local amplifications of earthquake ground motion could be significant. In order to check such methodology, indications obtained in this way from macroseismic data are compared with the estimates of transfer functions performed through the HVSR technique applied to microtremors. Results concerning municipalities located in a seismic area of Northern Italy indicate a good agreement between macroseismic and instrumental estimates.  相似文献   

Gravity evidence for a larger Limpopo Belt in southern Africa and geodynamic implications   总被引：2，自引：0，他引：2  

R. T. Ranganai  A. B. Kampunzu  E. A. Atekwana  B. K. Paya  J. G. King  D. I. Koosimile  E. H. Stettler 《Geophysical Journal International》2002,149(3):F9-F14

  相似文献   

Virtual vegetables and adopted sheep: ethical relation, authenticity and Internet-mediated food production technologies   总被引：2，自引：1，他引：2  

Lewis Holloway 《Area》2002,34(1):70-81

Associating ideas related to cultural geographies of 'quality' food production and consumption with recent discussion of Internet technologies, virtuality and simulation, this paper examines two newly constituted Internet enterprises offering customers 'virtual' experiences of food production, and 'quality' food products in which they have invested. The paper shows how these enterprises are associated with particular types of geographical and ethical relation, and a search for 'authentic', connected, relationships with food, farming, locality and 'nature'. These relationships are constituted in an assemblage of things held together by flows of food, products, money and electronic communication. The paper ends by suggesting a number of theoretical ideas that might usefully be explored in empirical research into Internet-mediated food production.  相似文献   

华南地区地壳速度结构分析   总被引：18，自引：0，他引：18       下载免费PDF全文

郑圻森  朱介寿  宣瑞卿  蔡学林 《沉积与特提斯地质》2003,23(4):9-13

笔者利用地球物理综合剖面上获取的P波速度值，对岩石圈地壳进行分层研究，划分出上、中、下地壳。按照大地构造单元进行数据的归类总结，计算出地壳各层平均速度和厚度值，以及地壳的平均速度和厚度值，最终通过所取得的数据资料的分析研究，探讨地球内部结构的动力学过程。  相似文献   

西藏南部郎杰学群碎屑物质来源的古水流证据   总被引：8，自引：0，他引：8  

李祥辉  曾庆高  王成善 《地质论评》2003,49(2):132-137

新近对西藏山南琼果和贡嘎地区(特提斯喜马拉雅北亚带)弱变质的上三叠统深海—半深海沉积地层——郎杰学群地质填图调查,在出露槽模沉积构造的37个古水流点获得了43组数据。赤平投影数据恢复后发现,这一地区主力古水流有南东140°～160°和南西190°～210°两个方向。这一分析结果为郎杰学群沉积物来自北边(未知块体)而非印度次大陆的观点提供了有力证据。  相似文献   

Anomalous Gadolinium,Cerium, and Yttrium Contents in the Adige and Isarco River Waters and in the Water of Their Tributaries (Provinces Trento and Bolzano/Bozen,NE Italy)     

Peter Mller  Giulio Morteani  Peter Dulski 《洁净——土壤、空气、水》2003,31(3):225-239

Rare earth patterns of surface and groundwaters near big cities often show anthropogenic Gd (Gd_ant) anomalies in addition to geogenic Ce and Y anomalies. The Gd_ant anomaly is caused by very stable organic complexes, one of which is gadopentetic acid, Gd‐DTPA. Derivatives of this and similar compounds are used as contrast agents in magnetic resonance imaging (MRI) of the human blood system. The organic Gd complexes are stable enough to pass nearly unaffected through sewage treatment plants and are, thereafter, discharged into surface water systems. Water of the rapidly flowing Isarco/Eisack and Adige/Etsch rivers (Provinces of Trento and Bolzano/Bozen, NE Italy) and their tributaries show remarkable variations in anthropogenic Gd contents (Gd_ant). Low Gd_ant values are found on Monday and Tuesday, whereas high values are observed during the remaining weekdays. Reliable Gd_ant balances are calculated for the river system at the confluence of the Adige and its tributaries. At two places local decrease of Gd_ant indicates exfiltration of groundwater. It is demonstrated that Gd_ant can be used as a reliably conservative tracer to study the water budget in rapidly flowing alpine river systems. The studied different river waters show considerable negative Ce and positive Y anomalies. Negative Ce anomalies are caused by scavenging of Ce(III) by FeO(OH) precipitates and subsequent oxidation to CeO₂. Y anomalies are attributed to less sorption of Y than REE onto particulate matter. Thus, Y moves faster than REE. Both, Ce and Y anomalies, are of geogenic origin.  相似文献   

Mechanisms of riverbank failure along the Arno River,central Italy     

Stefano Dapporto  Massimo Rinaldi  Nicola Casagli  Pietro Vannocci 《地球表面变化过程与地形》2003,28(12):1303-1323

Riverbanks along the Arno River have been investigated with the aims of de?ning the main mechanisms of failure and retreat, their spatial distribution, and their causes. Geomorphological aspects were investigated by a reconnaissance of riverbank processes, for a number (26) of representative sites. Laboratory and in situ tests were then performed on a selected number of riverbanks (15). Based on the material characteristics, six main typologies of riverbanks have been de?ned, with homogeneous ?ne‐grained and composite banks representing the most frequent types. Slab‐type failures are the most frequent mechanism observed on ?ne‐grained banks, while cantilever failures prevail on composite banks. The role of river stage and related pore water pressure distributions in triggering the main observed mechanisms of failure has been investigated using two different types of stability analysis. The ?rst was conducted for 15 riverbanks, using the limit equilibrium method and considering simpli?ed hypotheses for pore water pressure distribution (annulment of negative pore pressures in the portion of the bank between low water stage and peak stage). Stability conditions and predicted mechanisms of failure are shown to be in reasonably good agreement with ?eld observations. Three riverbanks, representative of the main alluvial reaches of the river, were then selected for a more detailed bank stability analysis, consisting of: (a) de?nition of characteristic hydrographs of the reach with different return periods; (b) modelling of saturated and unsaturated ?ow using ?nite element seepage analysis; and (c) stability analysis with the limit equilibrium method, by adopting pore water pressure values derived from the seepage analysis. The results are compared to those obtained from the previous simpli?ed analysis, and are used to investigate the different responses, in terms of stability, to different hydrological and riverbank conditions. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献