The Silurian of Gotland (Sweden): facies interpretation based on stable isotopes in brachiopod shells     

Chr Samtleben  A. Munnecke  T. Bickert  J. Pätzold 《International Journal of Earth Sciences》1996,85(2):278-292

The Silurian of Gotland, Sweden, consists of 440 m of carbonate deposits. Repeatedly, uniform sequences of micritic limestones and marls are interrupted by complex-structured reefs and by adjacent platform sediments. Generally, the alteration of facies is interpreted as the result of sea-level fluctuations caused by a gradual regression with superimposed minor transgressive pulses. The purpose of this study is a facies interpretation based on both field observations and stable isotope measurements of brachiopod shells. Approximately 700 samples from stratigraphically arranged localities in different facies areas have been investigated. The carbon and oxygen isotopes show principally parallel curves and a close relationship to the stratigraphic sequence. Lower values occur in periods dominated by deposition of marly sequences. Higher values are observed in periods dominated by reefs and extended carbonate platforms. The oxygen isotope ratios are interpreted to reflect paleosalinity changes due to varying freshwater input, rather than to paleotemperature. Carbon isotope ratios are believed to have been connected to global changes in the burial of organic carbon in black shales during periods of euxinic deep water conditions. Consequently, the facies succession on Gotland results from global paleoclimatic conditions. Changes in terrigenous input due to different rates of weathering and freshwater runoff, rather than sea-level fluctuations, control the carbonate formation of the Silurian on Gotland.  相似文献   

青藏高原东北地区现代降水中δD与δ^18O的关系研究   总被引：11，自引：0，他引：11  

章新平  姚檀栋 《冰川冻土》1996,18(4):360-365

根据对取自青藏高原东北地区部分降水样中氢氧稳定同位素比率的分析，得到沱沱河站的大气水线（ＭＷＬ）为：δＤ＝８．２５δ＾１８Ｏ＋９．２２‰，与全球平均ＭＷＬ的差别较小；德令哈、西宁站的ＭＷＬ分别为：δＤ＝５．８６δ＾１８Ｏ－２７．２８‰和δＤ＝６．９６δ＾１８Ｏ－３０．１９‰，均与全球平均ＭＷＬ差别较大。这主要归因于水汽源地的非平衡蒸发和凝结物在非饱和大气中降落时的非平衡蒸发。上述地区的过量氘Ｅｘｄ  相似文献   

树轮──流域径流变化的记录     

刘广深  戚长谋  林学钰 《吉林大学学报(地球科学版)》1997,(3)

根据树轮稳定碳同位素组成（δ１３Ｃｔ）序列可较灵敏地记录降水变化的事实，利用长白山红松树轮δ１３Ｃｔ序列与松花江年径流量之间的平行变化关系，重建了近２００年来松花江年径流量的变化：年径流量变化有明显的准２２年周期；１９００年之前，径流量在周期波动中呈上升趋势，１９００年之后，波动中呈下降趋势  相似文献   

杭州地区石笋稳定同位素古气候探索   总被引：1，自引：0，他引：1  

王兆荣  支霞臣  张汉昌 《沉积学报》1997,(1)

用１４Ｃ测年技术和稳定同位素地球化学古温度方法，对浙江省临安瑞晶洞穴的石笋进行了１４Ｃ的测年和碳、氢、氧同位素测试，获得５～１万年间杭州地区古气候演化记录、该记录表明，在５～１万年间有三次较明显的周期性古温度变化，最高温度为１４．９℃，最低温度为６．６℃，最大温差为８℃左右，平均温差３～５℃。这段时期正处在大理冰期后期，但大理冰期并不是一个持续的低温阶段，它至少有３次温度波动。与我们获得的石笋同位素古温度相一致。另外，我们将５～１万年间杭州地区古气候变化与同期东南沿海的海平面变化进行了对比，在时间上也较为吻合，也就是温度上升、海平面也上升，温度下降、海平面也随之下降  相似文献   

不同岩溶动力系统的碳稳定同位素和地球化学特征及其意义——以我国几个典型岩溶地区为例   总被引：7，自引：0，他引：7       下载免费PDF全文

刘再华  袁道先  何师意 《地质学报》1997,71(3)

结合水化学的野外观测及室内计算,作者对桂林岩溶试验场、四川黄龙风景区和贵州乌江渡坝区3个岩溶动力系统的碳稳定同位素特征进行了分析,进而对系统的性质、系统中CO_2的来源、碳酸盐沉积过程中的碳同位素动力分馏、水化学和钙华的成因及热水钙华的~(14)C测年等地球化学问题作了探讨。结果表明,桂林岩溶试验场属于表层岩溶作用动力系统,其中的侵蚀动力主要来源于大气降水溶解土壤中的CO_2;四川黄龙风景区属于深部岩溶动力系统,侵蚀动力来自大气降水溶解幔源的CO_2;贵州乌江渡坝区岩溶系统,虽然属于表层岩溶动力系统,但其中一部分的同位素和水化学特征已受到人类活动的重大影响。  相似文献   

西秦岭三个典型金矿床稳定同位素地球化学特征   总被引：15，自引：2，他引：15       下载免费PDF全文

冯建忠汪东波  王学明邵世才 《中国地质》2004,31(1):78-84

据八卦庙金矿、李坝金矿、小沟里金矿稳定同位素研究,金矿床δ34S比正常沉积岩变化范围窄,比岩浆-火山岩型矿床宽,硫源是海水硫酸盐还原硫与深部热液来源硫所组成的混合硫。石英包裹体流体氢、氧同位素分布于岩浆水、大气降水的重叠过渡区,更靠近岩浆水区,岩浆水的同位素特征更明显。八卦庙金矿石英脉3He/4He高于地壳3He/4He值(n×10-8),低于地幔3He/4He值(n×10-5),为壳-幔混合源。上述同位素地球化学证据表明,金成矿与岩浆岩有一定的成因关系。岩浆岩与金矿床空间关系密切,矿区内脉岩发育,脉岩为矿体的上下盘。含矿岩石中发育斑点构造,斑点为黄铁矿、磁黄铁矿、毒砂、绿泥石、石英、绢云母、黑云母、堇青石、红柱石、电气石、碳酸盐等热变质矿物和热液交代矿物,表明花岗岩为成矿提供热动力。据八卦庙金矿、李坝金矿、小沟里金矿稳定同位素地球化学研究,结合成矿地质背景分析和区域成矿地质特征对比,认为凤太、西成、礼岷地区金矿与微细浸染型(卡林型)金矿有明显的差别,该区金矿类似于岩浆热液矿床。  相似文献   

Formation of Carbon and Hydrogen Species in Magmas at Low Oxygen Fugacity   总被引：5，自引：0，他引：5  

KADIK  A.; PINEAU  F.; LITVIN  Y.; JENDRZEJEWSKI  N.; MARTINEZ  I.; JAVOY  M. 《Journal of Petrology》2004,45(7):1297-1310

Studies of iron-bearing silicate melt (ferrobasalt) + iron metallicphase + graphite + hydrogen equilibria show that carbon andhydrogen solubilities in melts are important for the evolutionof the upper mantle. In a series of experiments conducted at3·7 GPa and 1520–1600°C, we have characterizedthe nature (oxidized vs reduced) and quantified the abundancesof C- and H-compounds dissolved in iron-bearing silicate melts.Experiments were carried out in an anvil-with-hole apparatuspermitting the achievement of equal chemical potentials of H₂in the inner Pt capsule and outer furnace assembly. The fO₂for silicate melt–iron equilibrium was 2·32 ±0·04 log units below iron–wüstite (IW). Theferrobasalt used as starting material experienced a reductionof its iron oxides and silicate network. The counterpart wasa liberation of oxygen reacting with the hydrogen entering thecapsule. The amount of H₂O dissolved in the glasses was measuredby ion microprobe and by step-heating and was found to be between1 and 2 wt %. The dissolved carbon content was found to be 1600ppm C by step-heating. The speciation of C and H componentswas determined by IR and Raman spectroscopy. It was establishedthat the main part of the liberated oxygen was used to formOH^– and to a much lesser extent H₂O, and only traces ofH₂, CO₂ and  相似文献   

A Reflection on Mg, Cd, Ca, Li and Si Isotopic Measurements and Related Reference Materials   总被引：6，自引：1，他引：6  

Jean Carignan  Damien Cardinal  Anton Eisenhauer  Albert Galy  Mark Rehkamper  Frank Wombacher  Nathalie Vigier 《Geostandards and Geoanalytical Research》2004,28(1):139-148

This contribution aims to report the reflections we had with the scientific community during two international workshops on reference materials for stable isotopes in Davos (2002) and Nice (2003). After evaluating the isotopic homogeneity of some existing reference materials, based on either certificates, literature data or specific inter-laboratory rounds, we confirm these as primary reference materials or propose new ones relative to which stable isotope compositions should be reported. We propose DSM-3 for Mg, NIST SRM 915a for Ca, L-SVEC for Li and NBS28 for Si. Cadmium does not yet have a well identified delta zero material, although three commercial mono-elemental Cd solutions have yielded the same isotopic composition relative to one another. In order to scale the linearity of any mass spectrometer, some secondary reference materials are also proposed: Cambridge-1 solution for Mg, the "Münster-Cd" and JEPPIM Cd solutions for Cd and the "Big Batch" silicate for Si. The team from Nancy propose to prepare a mixed spike solution for Li isotopes. Well-characterised natural samples such as ocean or continental waters, diatoms, sponges, rocks and minerals are needed to validate the entire analytical procedure, particularly to take into account the effect of sample mineralisation and of chemical manipulations for elemental separation prior to analysis.  相似文献   

Comparisons on seasonal and annual variations of δ~(18)O in precipitation     

ZHANG Xinping  YAO Tandong 《地理学报(英文版)》2004,(2)

interpretationofpaleoclimaticrecordsinicecore(Dansgaardetal.,1969;Rozanskietal.,1997;Yao,1999;Thompsonetal.,2000).SincethefirstdeepicecorewasdrilledinGreenlandin1966(Dansgaardetal.,1969),hundredsoficecoreswereobtainedsuccessivelyfromicesheetsinAntarcticaandArctic,andmountainglaciersatmid-highlatitudes,fundedbynumerousresearchprogramsonglobalclimateandenvironmentalchange.Theseicecoresprovideuniqueandvaluablefirst-handinformationinrecoveringglobalpaleoenvironmentalrecordsandforecastingfuturecl…  相似文献   

Modern stable isotopic (δ18O, δ2H, δ13C) variation in terrestrial,fluvial, estuarine and marine waters from north‐central Sarawak,Malaysian Borneo     

Mark Stephens  James Rose 《地球表面变化过程与地形》2005,30(7):901-912

Stable isotope data on humid tropical hydrology are scarce and, at present, no such data exist for Borneo. Delta¹⁸O, δ²H and δ¹³C were analysed on 22 water samples from different parts of the Sungai (river) Niah basin (rain, cave drip, rainforest pool, tributary stream, river, estuary, sea) in north‐central Sarawak, Malaysian Borneo. This was done to improve understanding of the modern stable isotope systematics of the Sungai Niah basin, essential for the palaeoenvironmental interpretation of the Late Quaternary stable isotope proxies preserved in the Great Cave of Niah. The Niah hydrology data are put into a regional context using the meteoric water line for Southeast Asia, as derived from International Atomic Energy Agency/World Meteorological Organization isotopes in precipitation network data. Although the Niah hydrological data‐set is relatively small, spatial isotopic variability was found for the different subenvironments of the Sungai Niah basin. A progressive enrichment occurs towards the South China Sea (δ¹⁸O ?4·6‰; δ²H ?29·3‰; δ¹³C ?4·8‰) from the tributary stream (δ¹⁸O ?8·4‰; δ²H ?54·7‰; δ¹³C ?14·5‰) to up‐river (δ¹⁸O c. ?8‰; δ²H c. ?51‰; δ¹³C c. ?12‰) and down‐river values (δ¹⁸O c. ?7·5‰; δ²H c. ?45‰; δ¹³C c. ?11‰). This is thought to reflect differential evaporation and mixing of different components of the water cycle and a combination of depleted biogenic δ¹³C (plant respiration and decay) with enriched δ¹³C values (due to photosynthesis, atmospheric exchange, mixing with limestone and marine waters) downstream. Cave drip waters are relatively enriched in δ¹³C as compared to the surface waters. This may indicate rapid degassing of the cave drips as they enter the cave atmosphere. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献