Natural organics as fluorescent tracers of river-sea mixing     

Janet E. Dorsch  Terry F. Bidleman   《Estuarine, Coastal and Shelf Science》1982,15(6)

The use of dissolved organic matter fluorescence as a tracer of river-sea mixing was examined in two South Carolina estuaries. Fluorescence declined linearly with seawater dilution in laboratory mixing studies, and also behaved conservatively in an estuary where a single river emptied into a bay. Fluorescence-salinity relationships were also studied in another estuary where a piedmont river (high suspended sediment, low fluorescence) and a coastal plains river (low sediment, high fluorescence) mixed with ocean water. The factor of 2 or greater difference in fluorescence between the two rivers allowed their relative contribution to the estuarine water mass to be distinguished. Petroleum hydrocarbons, measured in estuarine water at 0·7-1·8 μg l⁻¹ concentrations, contributed negligibly to water fluorescence.  相似文献   

The past, present and future of the East/Japan sea in change: a simple moving-boundary box model approach     

Dong-Jin Kang  Kuh Kim  Kyung-Ryul Kim 《Progress in Oceanography》2004,61(2-4):175

The East/Japan Sea is a mid-latitude marginal sea that has undergone dramatic changes during the last 50–60 years. One of the most prominent characteristics of these changes is a rapid decrease in the amount of dissolved oxygen in deep waters. As a consequence of these changes, some investigators have even argued that the East/Japan Sea might become an anoxic sea in the next 200 years. While the causes of these changes are still under investigation, it has been shown that they are mainly due to modifications in the mode of the deep water ventilation system in the East/Japan Sea: a slowdown and complete cessation of bottom water formation accompanied by an enhancement of upper water formation instead. A simple moving-boundary box model (MBBM) was developed in order to analyze and quantify the processes involved in such changes over the last 50–60 years. Using a MBBM, we estimated the levels of several conservative chemical tracers (CFCs, Tritium, SF₆, ¹³⁷Cs) and bioactive tracers (oxygen and phosphate) in the deep water masses of the East/Japan Sea, comparing these with the historical data available, and making predictions for the near future. The model predicts that the East/Japan Sea should remain well-oxygenated, despite recent rapid oxygen decreases in its deep waters, accompanied by such structural changes as a shrinking of its oxygen-depleted deeper waters and an expansion of its oxygen-rich upper waters over the next few decades.  相似文献   

Net Sand Transport Direction in a Tidal Inlet, using Foraminiferal Tests as Natural Tracers     

Shu Gao  Michael Collins 《Estuarine, Coastal and Shelf Science》1995,40(6)

The relationship between the flux of exotic benthic foraminiferal tests (i.e. tests which are supplied from open-sea sources alone) in a tidal inlet and that of bulk sediment was analysed, which can be expressed as two first-order linear equations. According to this relationship, in order to determine net sediment transport directions in the entrance, the test concentration in surficial sediments of the tidal basin can be compared against a ‘ critical level ’. The critical level is determined for the conditions that no net transport of bulk sediment is present within the entrance. If the observed concentration (averaged over the tidal basin) is higher than the simulated critical level, then the net sediment transport is directed to landward. This method is applied to the analysis of net sand transport at Christchurch Harbour, a tidal inlet system located in southern England. In this investigation, concentrations of exotic foraminiferal tests in the surficial sediments of the tidal basin and ebb tidal delta area were obtained from the analysis of sea-bed sediment samples. A series of probable critical levels were calculated based upon the data sets with regard to: (1) sediment discharge from the rivers; (2) magnitude of sediment discharge within the entrance during the ebb; (3) the test concentration outside the harbour; (4) the thickness of the moving layer; and (5) two parameters associated with dispersive processes. The results show that the concentration in the tidal basin sediment is higher than a number of simulated critical concentrations for representative cases. Consequently, the high level of the concentration of exotic benthic foraminiferal tests within the harbour should be explained as a result of landward net transport of sands within the entrance.  相似文献   

氯离子质量平衡法应用问题刍议   总被引：6，自引：0，他引：6       下载免费PDF全文

袁瑞强  龙西亭  王鹏  宋献方 《水文》2015,35(4):7-13

氯离子质量平衡法(CMB)利用惰性示踪剂Cl-可以揭示区域地下水平均补给速率,补给事件和环境、气候变化事件等信息,可为相关研究提供可靠的信息。虽然该方法简单、有效,已经得到大量应用,但是也具有明显的局限性。综述了基于CMB法的相关研究,回溯了该方法的提出和演化,讨论了其主要假设条件和应用的局限性,阐明为了准确地应用该方法需要加强的方面。首先要重视氯离子干沉降的观测和研究。其次要加强氯离子沉降空间变化的观测和研究。在方法上要注意综合采用多种示踪剂、土壤理化性质和平行钻孔等手段来研究。最后要加强对氯离子平衡过程,及其相关的自然过程和人类活动的研究。对促进氯离子质量平衡法在地下水研究方面的应用和发展,具有一定的参考价值。  相似文献   

Disentangling late-Holocene climate and land use impacts on an Austrian alpine lake using seasonal temperature anomalies,ice-cover,sedimentology, and pollen tracers   总被引：1，自引：0，他引：1  

Roland Schmidt  Monika Roth  Richard Tessadri  Kaarina Weckström 《Journal of Paleolimnology》2008,40(1):453-469

Major and trace elements, minerals and grain-size were analysed from a sediment core covering the last 4,000 years of an Austrian Alpine lake (Oberer Landschitzsee, ObLAN, 2,076 m a.s.l.). These analyses were combined with autumn and spring temperature anomalies and ice-cover estimated from a diatom and chrysophyte cyst, thermistor-based regional calibration dataset and selected pollen markers published previously. Diatom-inferred pH (Di-pH) and DOC (Di-DOC) completed the multi-proxy approach, which, together with ordination techniques (PCA and RDA), helped (1) to confirm proposed climatic patterns and hypotheses, and (2) to disentangle the complex interactions between climatic and anthropogenic impacts. Shifts in chemical and physical weathering, erosion, production, lake stratification, redox potentials and air pollution were the major processes that have affected Oberer Landschitzsee in relation to climate, lake/catchment interactions, and human impact. Geochemistry supported the finding that the four waves of high-altitude land use (Early to Middle Bronze, ca. 1,800–1,300 B.C.; Late Bronze to Hallstatt, ca. 1,000–500 B.C.; Celtic to Roman, ca. 300 B.C.–400 A.D.; and Medieval, ca. 1,000–1,600 A.D.) were coupled mainly with warm periods. Increased production, onset of lake stratification, and the deterioration of hypolimnetic oxygen conditions were the major changes governing in-lake processes during climate warming. They resulted in specific element assemblages associated with organic matter accumulation (Br), oxygen depletion (As, Ga, Cu, S), and changes in redox (Fe/Mn). The Se/Di-DOC ratio was introduced to track shifts between in-lake production and allochthonous sources. Nutrient loading from pastures, coupled with climate warming, could explain that in-lake production was highest during Roman and Medieval land use. Lithogenic elements mainly originated from chemical weathering of silicate bedrock and they increased when intense land-use was coupled with climate deterioration and/or increased humidity. These perturbations were highest during a High Medieval climate fluctuation around 1,000 A.D. The association of sand with LOI and C/N and the decoupling of sand from quartz and feldspar separates erosion from physical weathering. Di-DOC, S, and C/N showed hybrid characters in relation to climate and human impact. The mineral proportions indicated gradients in relation to weathering, snow-cover and running waters, as well as vegetation. Air pollution by metallurgic industries, starting during the High Medieval and culminating during the Late Medieval, caused lead accumulation and could have contributed to As and S enrichment. Corresponding features in the distribution of selected elements and pollen tracers, as well as changes in mineral proportions, supported the hypotheses of shifts in seasonal climate and an overall trend towards more continental climate conditions since Medieval times.  相似文献   

Arsenic variability and groundwater age in three water supply wells in southeast New Hampshire     

Joseph P.Levitt  James R.Degnan  Sarah M.Flanagan  Bryant C.Jurgens 《地学前缘(英文版)》2019,10(5):1669-1683

Three wells in New Hampshire were sampled bimonthly over three years to evaluate the temporal variability of arsenic concentrations and groundwater age.All samples had measurable concentrations of arsenic throughout the entire sampling period and concentrations in individual wells had a mean variation of more than 7 μg/L.The time series data from this sampling effort showed that arsenic concentrations ranged from a median of 4 μg/L in a glacial aquifer well(SGW-65)to medians of 19μg/L and37 μg/L in wells(SGW-93 and KFW-87)screened in the bedrock aquifer,respectively.These high arsenic concentrations were associated with the consistently high pH(median≥8)and low dissolved oxygen(median0.1 mg/L)in the bedrock aquifer wells,which is typical of fractured crystalline bedrock aquifers in New Hampshire.Groundwater from the glacial aquifer often has high dissolved oxygen,but in this case was consistently low.The pH also is generally acidic in the glacial aquifer but in this case was slightly alkaline(median = 7.5).Also,sorption sites may be more abundant in glacial aquifer deposits than in fractured bedrock which may contribute to lower arsenic concentrations.Mean groundwater ages were less than 50 years old in all three wells and correlated with conservative tracer concentrations,such as chloride;however,mean age was not directly correlated with arsenic concentrations.Arsenic concentrations at KFW-87 did correlate with water levels,in addition,there was a seasonal pattern,which suggests that either the timing of or multiple sampling efforts may be important to define the full range of arsenic concentrations in domestic bedrock wells.Since geochemically reduced conditions and alkaline pHs are common to both bedrock and glacial aquifer wells in this study,groundwater age correlates less strongly with arsenic concentrations than geochemical conditions.There also is evidence of direct hydraulic connection between the glacial and bedrock aquifers,which can influence arsenic concentrations.Correlations between arsenic concentrations and the age of the old fraction of water in SGW-65 and the age of the young fraction of water in SGW-93 suggest that water in the two aquifers may be mixing or at least some of the deeper,older water captured by the glacial aquifer well may be from a similar source as the shallow young groundwater from the bedrock aquifer.The contrast in arsenic concentrations in the two aquifers may be because of increased adsorption capacity of glacio-fluvial sediments,which can limit contaminants more than fractured rock.In addition,this study illustrates that long residence times are not necessary to achieve more geochemically evolved conditions such as high pH and reduced conditions as is typically found with older water in other regions.  相似文献   

Detection of anthropogenic gadolinium in the Brisbane River plume in Moreton Bay, Queensland, Australia     

Michael G. Lawrence 《Marine pollution bulletin》2010,60(7):1113-1885

Wastewater effluent is known to contain macro and micropollutants, which may be deleterious to environmental health. One such class of micropollutants is chelated gadolinium, which are used as MRI contrast agents. As these MRI contrast agents can be assumed to behave conservatively during estuarine mixing, it is possible to calculate how much wastewater is represented in any particular sample. In this study, the percentage contribution of wastewater at specific locations in Moreton Bay, Qld, were determined by calculating the additional anthropogenic gadolinium contribution to the total rare earth element concentrations. Wastewater contributions were measured at concentrations as low as 0.2%, demonstrating the applicability of this technique for wastewater effluent plume mapping.  相似文献   

Approximating groundwater age distributions using simple streamtube models and multiple tracers     

《Advances in water resources》2014

We use a streamtube based decomposition and a recently developed, simple relationship between tracer concentrations and ages to estimate groundwater age distributions. The decomposition assumes that an age distribution can be approximated using a superposition of linearly independent streamtubes. Transport in each streamtube is modeled with inverse Gaussian functions, the parameters of which are inferred from radiometric tracer concentrations. Three simple sampling methods are considered for weakly and moderately heterogeneous aquifers and the method gives reasonable approximations in both systems. The method is sensitive to errors in the measured concentrations but some of these errors are easily identifiable and a range of plausible age distributions can still be found. The method was then tested in a highly heterogeneous system and reasonable estimates of the age distribution were also obtained. The simplicity of this method and its insensitivity to the heterogeneity structure suggest that this approach may be an effective tool for obtaining estimates of age distributions in natural systems.  相似文献   

ROAD SALT ACCUMULATION IN HIGHWAY SNOW BANKS AND TRANSPORT THROUGH THE UNSATURATED ZONE OF THE OAK RIDGES MORAINE,SOUTHERN ONTARIO     

C. F. LABADIA  J. M. BUTTLE 《水文研究》1996,10(12):1575-1589

Pathways and fate of road deicing salt (NaCl) applied during the 1994–1995 winter were studied for a 14-km section of a major highway that crosses the Oak Ridges Moraine in southern Ontario. Total salt applications over the winter ranged from 29 to 74 kg m⁻¹ of highway, and NaCl concentrations in snow banks adjacent to the roadway reached 9400 mg l⁻¹ during the later stages of snow cover development. This salt was released to the ground surface during snowmelt. Sodium chloride (NaCl) loadings to soil from snow cover during the final melt phase were relatively uniform along the study section (3–5 kg NaCl m⁻¹ of highway). However, the snowpack at all transects retained <50% of applied NaCl, and this shortfall probably reflected direct runoff and infiltration of saline meltwater from the road surface into the adjacent shoulder and right-of-way. Cation exchange with Ca²⁺ in near-surface soils most likely resulted in preferential retention of Na⁺ relative to Cl⁻, although total storage of NaCl in upper soil horizons by winter's end was <15% of deicing salt applications. An environmental tracer (¹⁸O) was used to trace movement of saline meltwater through the unsaturated zone underlying the highway. Average meltwater particle velocities at a site underlain by loam soils were 0.02 m d⁻¹, and ca. 280 mm of water was displaced below a depth of 1.86 m over a 78-day period in the spring and summer of 1995. Sodium ion and chloride ion concentrations in water sampled in late summer 1995 at depths >2 m exceeded 500 mg l⁻¹ and 1000 mg l⁻¹, respectively. Approximately 75% of the net flux of NaCl below the upper soil was retained in the 0–2.8 m depth interval at this site, and results from more permeable soils traversed by the highway indicate an even greater penetration of the annual NaCl application into the unsaturated zone along the moraine. This saline water likely recharges groundwater in this portion of the Oak Ridges Moraine.  相似文献   

Characterizing the heterogeneity of karst critical zone and its hydrological function: An integrated approach   总被引：1，自引：0，他引：1       下载免费PDF全文

Xi Chen  Zhicai Zhang  Chris Soulsby  Qinbo Cheng  Andrew Binley  Rui Jiang  Min Tao 《水文研究》2018,32(19):2932-2946

Spatial heterogeneity in the subsurface of karst environments is high, as evidenced by the multiphase porosity of carbonate rocks and complex landform features that result in marked variability of hydrological processes in space and time. This includes complex exchange of various flows (e.g., fast conduit flows and slow fracture flows) in different locations. Here, we integrate various “state‐of‐the‐art” methods to understand the structure and function of this poorly constrained critical zone environment. Geophysical, hydrometric, and tracer tools are used to characterize the hydrological functions of the cockpit karst critical zone in the small catchment of Chenqi, Guizhou Province, China. Geophysical surveys, using electrical resistivity tomography (ERT), inferred the spatial heterogeneity of permeability in the epikarst and underlying aquifer. Water tables in depression wells in valley bottom areas, as well as discharge from springs on steeper hillslopes and at the catchment outlet, showed different hydrodynamic responses to storm event rainwater recharge and hillslope flows. Tracer studies using water temperatures and stable water isotopes (δD and δ¹⁸O) could be used alongside insights into aquifer permeability from ERT surveys to explain site‐ and depth‐dependent variability in the groundwater response in terms of the degree to which “new” water from storm rainfall recharges and mixes with “old” pre‐event water in karst aquifers. This integrated approach reveals spatial structure in the karst critical zone and provides a conceptual framework of hydrological functions across spatial and temporal scales.  相似文献