一个干旱地区毛矾石矿氧化带的矿物组合     

张耀华 《新疆地质》1992,(3)

在陆相古火山角砾岩筒中由火山热液蚀变产生的含黄铁矿次生石英岩中的硫化物,在特别干旱的条件下生成了以毛矾石及黄钾铁钒为主的13种钒类矿物组成的硫化矿床氧化带,并在其中聚集了毛矾石矿体。毛钒石矿是由反复进行的氧化-渗透淋滤作用而富集形成的。  相似文献   

Elucidation of the Alum Shale kerogen structure using a multi-disciplinary approach     

Sunil Bharati  Richard L. Patience  Steve R. Larter  Guy Standen  Iain J. F. Poplett 《Organic Geochemistry》1995,23(11-12)

The significance and validity of integrating data obtained from a variety of analytical techniques to understand, elucidate and model kerogen's complex chemical structure is reported here using degradative (open and closed system pyrolysis, chemical oxidation), non-degradative (¹³C CP/MAS NMR) and optical (incident white light and blue light) methods. Seven Cambrian Alum Shale samples, ranging in maturity from immature to post-mature with respect to petroleum generation, were studied and were chosen for their simple geological history, uniform organic matter type and high organic carbon content. The Alum Shale kerogens, which primarily consist of algal organic matter, liberate low molecular weight gaseous and aromatic compounds on pyrolysis and give mostly branched dicarboxylic acids on chemical oxidation. ¹³C NMR spectroscopy shows that the Alum Shale kerogens are anomalously rich in oxygen-bearing functional groups (such as C = O, ArCO, CHO, CH_xO), most of which apparently remain intact within the kerogen macro-molecule (KMM) through the diagenetic and catagenetic stages. Fragments released by different degradative techniques are quantified and the aromaticity (f_a), O/C and relative proportions of various carbon types estimated by ¹³C NMR. A synthesis of these data has allowed us to better understand the chemistry of the Alum Shale kerogen.  相似文献   

The behaviour of dissolved arsenic in the estuary of the River Beaulieu     

A.G. Howard  M.H. Arbab-Zavar  S. Apte 《Estuarine, Coastal and Shelf Science》1984,19(5):493-504

The chemical forms and distribution of dissolved arsenic species in the estuary of the River Beaulieu (Hampshire, U.K.) are reported. ‘Inorganic arsenic (V)’ in both the marine and riverine estuary inputs are in true solution, passing through ultrafiltration membranes having a nominal molecular weight cut-off of 500 daltons. Extensive removal of dissolved ‘inorganic arsenic (V)’ is apparent from the distribution of arsenic in the estuary, with laboratory mixing experiments indicating that removal is favoured in the low salinity region. ‘Inorganic arsenic (III)’ and methylated arsenic species account for up to 41% and 70% of the dissolved arsenic, respectively, but are only found during the warmer months when water temperatures exceed ca. 12°C.  相似文献   

The Influence of Oxalate on Fe-Catalyzed S(IV) Oxidation by Oxygen in Aqueous Solution     

A. Wolf  F. Deutsch  P. Hoffmann  H. M. Ortner 《Journal of Atmospheric Chemistry》2000,37(2):125-135

This study demonstrates that oxalate has a strong inhibiting effect onFe-catalyzed S(IV) oxidation by oxygen in aqueous solution. While thepseudo-first order rate constant of S(IV) oxidation was determined to be1.6 × 10³ M^-1 s^-1 in experimentswithout oxalate, the oxidation of S(IV) was totally inhibited at a molarconcentration ratio of iron:oxalate = 1:5 at an oxalate concentration of 4M. Under these conditions, the Fe(II)/Fe(III) ratio remained nearlyconstant during the observed reaction time. The determined rate constants wereindependent of the initial oxidation state of iron. However, with increasingconcentrations of oxalate, a longer induction period is observed forexperiments with iron initially in the Fe(II) oxidation state.  相似文献   

新疆伊犁盆地511砂岩型铀矿床成矿作用机理研究   总被引：5，自引：1，他引：5  

王正其  李子颖  管太阳  张国玉 《矿床地质》2006,25(3):302-311

为探讨511铀矿床的形成机理,通过野外岩心观察和系统样品采集,结合室内化学分析、扫描电镜、电子探针等方法,详细研究了赋存于Ⅴ旋回砂体的铀矿地质特征,对砂岩铀的成矿作用展开了初步讨论。认为Ⅴ旋回层间氧化带可划分为氧化带、氧化_还原过渡带(包括褪色亚带和铀矿石亚带)和还原带;铀矿赋存在过渡带砂岩中,空间展布严格受层间氧化带控制;铀主要以显微浸染状铀矿物(沥青铀矿 铀石)形式散布于炭屑木质细胞腔内壁和砂岩碎屑颗粒的填隙物中,部分以吸附形式赋存于粘土矿物和炭屑;层间氧化带发育是含氧层间承压水与砂岩之间水岩作用的结果。伴随砂岩中有机质、S2-和Fe2 被氧化,形成的有机酸类、SO2-4和Fe3 等组分部分迁移至过渡带沉淀,也是砂岩中铀元素活化迁移、沉淀富集,再活化、再富集的循环过程;层间氧化带及其砂岩铀成矿作用发生于表生环境,始于喜马拉雅早期(66Ma),具有长期性和滚动式向前发展的特点;铀成矿可能与微生物细菌活动及其还原作用密切相关。  相似文献   

公婆泉盆地下白垩统新民堡群层序地层和铀成矿特点     

龚斌利  王金平 《铀矿地质》2006,22(1):17-22

本文论述了公婆泉盆地下白垩统新民堡群的层序地层特点———层序分布和时代、界面特征和内部构成、沉积相,以及层间氧化带和铀矿化特点。认为该盆地在公婆泉地段具有一定的找铀矿远景,但北骆驼泉地段铀成矿条件不佳,那林疏怀地段不具备铀成矿远景。  相似文献   

含铜、铋和银的金精矿堆浸工艺综合回收试验研究     

程东会  何江涛  王金祥  李国斌  沈照理 《现代地质》2006,20(2):322-328

采用生物氧化技术和化学方法,利用堆浸工艺分步提取,对含Au 140~150 g/t、Ag 900~1 000 g/t、B i 9.0%~10.0%、Cu14%~17%的多金属浮选金精矿的综合回收工艺进行了研究。经小型搅拌试验,确定了生物氧化浸铜—氰化浸金、NaC l-FeC l3-HC l体系(氯盐法)浸出铋和银的技术方法。通过柱浸试验,研究了利用该方法分步浸取Au、Ag、Cu和B i在堆浸工艺中的可行性。在10 t精矿的扩大试验验中,验证了柱浸试验所取得的工艺指标和参数。试验中掺入骨架材料,解决了精矿在堆浸中的渗透问题;生物氧化过程中,菌种在含高浓度铜离子浸出液中反复驯化,对铜的耐受力提高到30 g/L;在NaC l-FeC l3-HC l体系浸出B i和Ag时,用H2O2将浸出液中的Fe2+氧化成Fe3+,使浸出液能循环使用,且B i和Ag同时浸出。Au、Ag、Cu和B i的最终浸出率分别为92.98%、65.09%、45.33%和53.49%。  相似文献   

氯化钠盐土壤介电虚部特性的初步研究   总被引：4，自引：0，他引：4  

熊文成  邵芸 《遥感学报》2006,10(2):279-286

含水含盐土壤的介电虚部模型是土壤含水量含盐量的函数。通过一系列关系研究：介电常数虚部ε＂，土壤导电率σa，土壤溶液导电率σw，土壤溶液离子浓度SMv，含盐量S，最终得到介电常数虚部ε＂和土壤含水量Mv。含盐量S的关系，即土壤介电模型。通过微波网络仪，对150组具有不同含水含盐量的土壤，在频率范围0．2-20GHz（频率取样间隔为0．05GHz）进行介电常数测量。在不同频率下，利用这些实测数据通过最佳拟合的方法确定土壤介电模型中的待定参数，从而得到不同频率时土壤介电虚部经验模型。另外，利用吉兰泰地区41个含盐土壤样品进行模型验证，结果表明，模型计算值与测量值高度相关。最后得出：（1）含盐量对介电常数虚部的影响随频率增大而降低；（2）土壤类型和介电常数虚部几乎没有相关性。  相似文献   

非地转湿Q矢量在台风“云娜”暴雨过程中的分析应用   总被引：10，自引：3，他引：10  

颜琼丹  蔡亲波 《热带气象学报》2006,22(5):505-509

应用非地转湿Q矢量理论,对2004年8月12-15日台风“云娜”登陆后造成的大范围持续暴雨过程进行诊断分析。结果表明,非地转湿Q矢量能比较清楚地揭示台风暴雨的演变过程,非地转湿Q矢量的散度负值区和流场辐合区与未来12小时的强降水落区有较好的对应关系；非地转湿Q矢量的散度的垂直分布能够反映台风外围对流发展的深度,对判断台风在陆地上的维持有一定的意义。  相似文献   

Product study of the reaction of OH radicals with isoprene in the atmosphere simulation chamber SAPHIR     

M. Karl  H.-P. Dorn  F. Holland  R. Koppmann  D. Poppe  L. Rupp  A. Schaub  A. Wahner 《Journal of Atmospheric Chemistry》2006,55(2):167-187

Atmospheric oxidation of isoprene and its oxidation products methacrolein (MACR) and methyl vinyl ketone (MVK) have an important impact on the photochemical activity in the boundary layer, in particular in forested areas. The oxidation of isoprene by OH radicals was investigated in chamber experiments conducted under tropospheric conditions in the atmosphere simulation chamber SAPHIR at the Research Center Jülich. The aim was to determine the product yield of MVK and MACR in the OH-induced isoprene oxidation and the rate constant of their reaction with OH under real atmospheric conditions. The recently published updated degradation scheme for isoprene from Geiger et al. (2003) was used to determine rate constants and product yields. The fractional yields in the isoprene peroxy radical reaction with NO were found to be 0.41±0.03 for MVK and 0.27±0.03 for MACR. The rate coefficient for MACR with OH was found to be in very good agreement with the recommended value of IUPAC Atkinson (Atkinson et al., 2005). while the rate coefficient for MVK with OH was 27% lower.  相似文献