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101.
Basalts interbedded with oil source rocks are discovered frequently in rift basins of eastern China, where CO2 is found in reservoirs around or within basalts, for example in the Binnan reservoir of the Dongying Depression. In the reservoirs, CO2 with heavy carbon isotopic composition (δ13C>-10‰ PDB) is in most cases accounts for 40% of the total gas reserve, and is believed to have resulted from degassing of basaltic magma from the mantle. In their investigations of the Binnan reservoir, the authors suggested that the CO2 would result from interactions between the source rocks and basalts. As the source rocks around basalts are rich in carbonate minerals, volcanic minerals, transition metals and organic matter, during their burial history some of the transition metals were catalyzed on the thermal degradation of organic matter into hydrocarbons and on the decomposition of carbonate minerals into CO2, which was reproduced in thermal simulations of the source rocks with the transition metals (Ni and Co). This kind of CO2 accounts for 55%-85% of the total gas reserve generated in the process of thermal simulation, and its δ13C values range from -11‰- -7.2‰ PDB, which are very similar to those of CO2 found in the Binnan reservoir. The co-generation of CO2 and hydrocarbon gases makes it possible their accumulation together in one trap. In other words, if the CO2 resulted directly from degassing of basaltic magma or was derived from the mantle, it could not be accumulated with hydrocarbon gases because it came into the basin much earlier than hydrocarbon generation and much earlier than trap formation. Therefore, the source rocks around basalts generated hydrocarbons and CO2 simultaneously through catalysis of Co and Ni transition metals, which is useful for the explanation of co-accumulation of hydrocarbon gases and CO2 in rift basins in eastern China. 相似文献
102.
爆裂法作为快速测定流体包裹体中二氧化碳(和其它气体)含量的手段及其在勘探中的使用:以中国山东和河北省金矿为例 总被引:1,自引:0,他引:1
Kingsley Burlinson 《岩石学报》2007,23(1):65-71
The acoustic decrepitation method heats a small monomineralic sample and counts pressure impulses as the inclusions burst when they develop high internal pressures.For aqueous fluids,the decrepitation temperature is correlated with the homogenisation temperature,but gas rich fluids give a distinct and characteristic low temperature decrepitation peak which can be used to recognize gas rich fluid inclusions.This information is useful in exploration for Au deposits,which are frequently associated with CO_2 rich and sometimes CH_4 rich fluids. This distinctive decrepitation occurs because the CO_2 rich inclusion fluids expand according to the gas law and develop internal pressures high enough to burst the host mineral grain at temperatures well below their homogenisation temperatures.In contrast,aqueous fluids condense to a liquid and vapour phase during post-entrapment cooling.Upon subsequent heating their internal pressures do not increase significantly until after homogenisation to a single phase occurs and hence they do not decrepitate"prematurely"as gas rich inclusions do. This behaviour is usually regarded as an annoyance in conventional microthermometric homogenisation studies,but can readily be used as an exploration aid to find mineralisation deposited from such gas rich fluids.Decrepitation results on samples from Cowra Ck, NSW,Australia,which have also been microthermometrically measured for CO_2 content,show that amounts of less than 5 mole % CO_2 are easily distinguished by decrepitation and amounts as low as 1 mole % CO_2 may be determinable. Examples of the use of acoustic decrepitation in the study of 6 gold mines in the Shandong and Hebei provinces of China are discussed. 相似文献
103.
104.
二氧化碳捕集与地下埋存国际进展 总被引:7,自引:0,他引:7
本文论述了我国温室气体减排的严峻形势,说明了二氧化碳地下埋存是温室气体减排的重要手段,介绍了世界主要发达国家开展的二氧化碳地下埋存调查评价活动以及实施项目的进展情况和经验,这些对于我国今后开展二氧化碳地下埋存具有很好的借鉴意义。 相似文献
106.
土壤中的CO2及其对岩溶作用的驱动 总被引:50,自引:1,他引:49
作者以桂林岩溶试验场和陕西鱼洞河两个观测站为例,分析了我国南、北方土壤CO2的动态、差异及其对岩溶作用的驱动规律,进一步结合气候条件(气温、降水)等的分析,揭示了南、北方岩溶发育差异的根源。 相似文献
107.
利用旋转盘实验装置和高分子生物催化剂技术,笔者研究了流动CO2-H2O系统中方解石溶解动力学及其控制机制。实验发现,方解石的溶解既受到固-液界面间扩散边界层(DBL)的控制,还受到扩散边界层内CO2慢速转换反应(CO2+H2O←→H^++HCO^)的控制。然而,高CO2分压(Pco2〉0.01atm)时,溶解主要为CO2慢速转换控制,而低CO2分压(Pco2〈0.01atm)时,溶解主要为扩散为边 相似文献
108.
温室效应是当今世界上许多国家及其政府关注的重要问题之一。从地质角度研究全球最大碳库--碳酸盐岩在其岩溶发育过程中对温室气体CO2的调节能力,从而为更全面,定量地考察温室气体CO2循环提供新思路及依据。 相似文献
109.
全球气候变暖正在并将继续对我国经济、社会和生态环境产生深远影响。我国干旱与土地退化呈扩大发展趋势、水资源短缺形势严峻、洪涝灾害、水土流失、滑坡、泥石流等灾害以及海岸带灾害将加剧等。因此,未来我国环境地质工作应主要加强四个方面的工作:一是加强海岸带地质调查评价工作,并纳入到沿海经济带发展规划之中;二是加强地球表层水循环系统“碳汇”作用研究,开展碳地下埋存调查评价,为温室气体减排奠定基础;三是提高地质灾害风险防治水平;四是加大地下水资源勘查力度,提高地下水资源保护水平。 相似文献
110.