热带深对流云对CO、NO、NOx和O3的垂直输送作用   总被引：2，自引：1，他引：1  

银燕  曲平  金莲姬 《大气科学》2010,34(5):925-936

利用2005年11月至2006年2月ACTIVE (Aerosol and Chemical Transport in tropIcal conVEction) 外场试验期间在澳大利亚北部达尔文地区取得的CO、O3、NO和NOx飞机探测资料, 并结合HYSPLIT后向轨迹模式结果, 分析这几种气体成分在对流卷云砧内外的分布情况, 并探讨热带深对流云对于污染气体的垂直输送作用。分析结果显示, 在孤立对流云卷云砧中, 云砧内部O3、NO、NOx浓度均大于云外; 而CO则不同, 只有在近地面浓度高时才如此, 在近地面浓度较小时, 卷云砧内部的浓度反而小于云外。进一步分析造成这两类气体分布差异的原因, 发现CO主要借助深对流云将对流层下层以及对流云周围环境中的CO夹卷并动力垂直输送到对流云顶部卷云砧中, 而对于O3、NO和NOx来说, 除了上述作用以外, 还可能与对流云内部其他物理机制(如闪电), 造成新的O3、NO和NOx有关, 这些新生气体随着风暴内部强烈的上升气流被最终输送进云砧中。  相似文献   

鹤壁井煤燃烧的水氡效应分析   总被引：1，自引：0，他引：1  

杜广仁 《地震》1994,(5):92-96

本文通过鹤壁深井煤层特大火灾热源的影响导致的井水氡变化实例，验证了鹤壁井水氡化学组分在温压条件发生变化时具有灵敏的反映。水氡变化曲线图象表现为氡值下降，并讨论了其形成机制。  相似文献   

在低pH值下尿素水解速度规律的研究   总被引：5，自引：0，他引：5  

王廷吉  周萍华 《华东地质学院学报》1994,17(1):94-97

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^1^4C—样品制备方法比较研究     

李树真 《中国沙漠》1994,14(3):86-91

本文比较了防爆氧燃烧，酸性湿氧化及碱性湿氧化。结果表明，防爆氧燃烧技术有快速，安全可靠，１４Ｃ回收率高，计数体系淬灭小，不分相，计数稳定，无化学发光（ＲＣＭ％＝０）等优点，可作为１４Ｃ的常规探测法。  相似文献   

Partitioning and Hydrolysis of Nb and Ta and Their Implications with Regard to Mineralization   总被引：4，自引：0，他引：4  

Yurong Wang  Fu Gu  Ziqiang Yuan 《中国地球化学学报》1993,12(1):84-91

K₂NbOF₅ · H₂O and K₂TaF₇ were prepared through melting Nb₂O₅ and Ta₂O₅ respectively with KHF₂ · 2H₂O, followed by recrystallizing. The hydrolysis properties of K₂NbOF₅ and K₂TaF₇ were determined again by using a rapidly quench vessel. As temperature (from 250 to 550 °C) and pressure (from 500 to 1500 bars) increase, the degree of hydrolysis of both K₂NbOF₅ and K₂TaF₇ will increase. Nb- and Ta-fluorine complex compounds are instable in supercritical aqueous fluids. The degree of hydrolysis of both K₂NbOF₅ and K₂TaF₇ decreases with increasing concentration of HF, independent of the concentration of NaF. The partition coefficients of Nb and Ta between granitic melt and fluid phase are less than 0.15, i.e., most of Nb and Ta are left in granitic melt. The partition coefficient of Ta is more dependent on the concentration of HF than that of Nb. The significance of hydrolysis in Nb- and Ta- mineralization is also discussed in the present paper.  相似文献   

高效净水剂—聚氯化铝制造方法探讨   总被引：1，自引：0，他引：1  

邸尚志  张润梅 《西北地质》1993,14(3):30-36

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Chemical characteristics of fine particles during spring dust storm dominant period in two Chinese cities, Baotou and Wuwei     

Min HU Fan YANG Dingli YUE Song GUO Mengting WEN Wenting ZHANG Feng TIAN 《中国地球化学学报》2006,25(B08):221-221

Mineral dust, including dust storm, fugitive and floating dust are the most important components of ambient aerosol in northern China during spring. Meanwhile, it goes through heating period when fossil fuel combustion acts as a dominant source. In order to understand the chemical characteristics of fine particles in North China, two sampling sites was established in Baotou City in the west of Inner Mongolia Autonomous Region and Wuwei City near the edge of Gobi to collect fine particles （PM 2.5） samples in the spring of 2004 and 2005, and analyze mass concentrations, ionic species and some element components of PM 2.5. The results indicated that dust events elevated the mass concentrations of particulate matter significantly, not only for coarse particles, but also for fine particles. Crustal components, organic matter and sulfates are three major compositions in fine particles, their mass concentrations and relative abundances are closely related with the frequency of dust events and coal combustion. The characteristics of fine particles are obviously diverse under different atmospheric conditions. （1） When the dust storms take place, the wind speeds are often higher than 10 m/s. A plenty of mineral aerosol is input from long distance, and also local soil dust is blown up to suspend in the air as particles. Therefore, the concentrations of PM 2.5 are enhanced dramatically. Mass concentrations and relative percentages of crustal components in PM 2.5 increased significantly during dust events. The mineral dust may help gas to particle conversation by heterogeneous reactions. Increases in mass concentrations of SO4^2-, NO3^- and NH4^＋ and organic matter in PM 2.5 were observed evidently. But their fractions in PM 2.5 do not increase simultaneously due to dilution of storing wind. （2） When wind velocity is lower （〈3 m/s）, air pollutants are accumulated, both mass concentrations of SO4^2-, NO3^- and NH4^＋ and organic matter, and their fractions in PM 2.5 increase, indicating severe anthropogenic pollution. The chemical characteristics of PM 2.5 in Baotou and Wuwei are also influenced by their industrial structure, topography and meteorological conditions.  相似文献   

Votalization of selenium in selenium-rich black rock series in Yutangba     

Shujuan SHI Yuegang TANG 《中国地球化学学报》2006,25(B08):48-48

Votalization of selenium in selenium-rich black rock series in Yutangba is discussed at 400, 500, 600, 700, 800 and 900℃.Votalization of selenium tends to increase when the temperature is high. So environmental influence of selenium-rich black rock series combustion needs to be considered.  相似文献   

Study on the distribution of PAHs in fly ash from coal and residual char combustion in a pressurized fluidized bed     

Hongcang ZHOU 《中国地球化学学报》2006,25(B08):54-55

Direct coal combustion not only has a low utilizing efficiency, but also produces a large amount of pollutants such as particulate, CO2, SO2, NOx, polycyclic aromatic hydrocarbons （PAHs）, PCDD/PCDFs, and so on. Coal gasification is a clean coal technology that presents good prospects for coal use, mainly for producing electricity with a high coal conversion efficiency and low environmental impact. However, there is a problem about the minimization of PAHs in coal gasification or direct coal combustion. PAHs are harmful to the environment and human health due to their high degree of mutagenicity and carcinogenicity when they enter human bodies through breathing, eating, and drinking. It is said that about 75%-90% cancers of human beings are mainly caused by PAHs. So the US EPA has prioritized 16 PAH compounds as hazardous air pollutants; these compounds are naphthalene （NAP）, acenaphthylene （AcPy）, acenaphthene （AcP）, fluorene （Flu）, phenanthrene （PhA）, anthracene （ANT）, fluoranthene （FluA）, pyrene （Pyr）, benzo （a） anthracene （BaA）, chrysene （Chr）, benzo （b） fluoranthene （BbF）, benzo （k） fluoranthene （BkF）, benzo （a） pyrene （BaP）, indeno（1,2,3,-cd） pyrene [In（1,2,3-cd） P], dibenzo （a,h） anthracene （DbA）, and benzo （ghi） perylene （BghiP）. The residual char is one of the main products during coal gasification, and then it is brought into the combustion chamber to combust. To investigate the distribution of PAHs in fly ash, the combustion of coal and residual char was tested in a pressurized spouted fluidized bed. After Soxhlet extraction and K-D concentration, the contents of 16 PAHs recommended by US EPA in coal, residual char, and fly ash, were analyzed by a HPLC coupled with fluorescence and diode-array detection.  相似文献   

Open burning of wastes as the source of environmental contamination by POPs     

Sergey V. Kakareka Tamar I. Kukharchyk 《中国地球化学学报》2006,25(B08):177-178

In the paper the procedure for and results of a test study of a few persistent organic pollutants - polycyclic aromatic hydrocarbon （PAH）, polychlorinated biphenyls （PCB） and hexachlorobenzene （HCB） emission from the open burning of different types of wastes （domestic wastes, agricultural debris, landscape cleating debris, etc.） are discussed. The open burning of agricultural debris and landscape-clearing debris is widely applied in rural areas and small towns and in allotment gardens for the recovery of that part of wastes that can not be utilized for compost preparation. This process is most typical during the autumn season and to a lesser degree during spring. Burning occurs usually in bon fires. Burning modes differ depending on the volume of material burnt, the waste moisture content, the weather conditions, etc. During this process part of domestic wastes （polluted wood, paper, chipboard, films, plastics, etc.） are burned also. Investigations included the collection and preparation of combustible material, the simulation of open burning processes, particulate and gas emission sampling, chemical analysis of sample and data processing. Sampling procedures and sample preparation were agreeable to the emission sampling standards. The aerosol and vapour phases of POPs were collected by ordinary sampling train with pumping of waste gases through filter and solid sorbent （polyurethane foam）. For the measurements of PAH in emission, gas chromatography and mass spectrometry were used which make it possible to identify and determine 16 PAH compounds in the samples; this method was used for HCB determination also. Gas chromatography with ECD detector was used for PCB measurement. It was detected that the levels of PAH emission from wastes uncontrolled burning of wastes vary greatly. Influencing factors are composition and properties of refuse, temperature and mode of burning, level air supply. Generally, the increase of content of wood leads to the increase of PAH in emission. PAH emission also increased with increasing temperature of burning. The highest PAH values are characteristic of emissions from domestic refuse burning. Practically, all naphthalene, acenaphthylene, acenaphthene （from 60% to 100% of their total mass） and fluorene （14%-99%） were emitted in gaseous form.  相似文献