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地球上很多矿产资源都是在十几亿年前积累储藏的,当时的地球化学循环在很大程度上与今天是不尽相同的.利用岩石中所反映的约30多亿年前的地球化学线索,来自于卡耐基科学学院的Andrey Bekker和Doug Rumble等科学家给人们带来了惊人的发现--镍矿的沉积中一个最重要的元素硫磺,就是与当时大气的缺氧环境密切相关. 相似文献
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Thorjorn Larssen 《中国地球化学学报》2006,25(B08):49-49
Acid rain is one of China＇s major environmental problems and emissions of sulphur and nitrogen are still increasing. The acid rain situation in China is somewhat different from what is seen in Europe and North America. Sulfur deposition is very high, but there is also very high deposition of calcium and other base cations. The sources of atmospheric Ca are not well understood, although it is important for understanding long term impacts of acid deposition. The fate of S, N and Ca^2＋ in the catchment is crucial for the future development of the acidification situation of soils and waters in China. Very few studies presenting catchment input-output ion budgets in Chinese natural environments exist and there are several unknown factors regarding processes. Here, we present annual input-output budgets for three years （2001-2003） for major ions for four forested catchments in China receiving different loads of acid deposition. For the two sites receiving the highest SO4^2- inputs, the input-output budget for the upper 50 cm of soil is approximately balanced. For the most remote site the soil is a net sink for SO4^2-, suggesting that the pool of adsorbed SO4^2- in the soil is building up. This is in agreement with the fact that the site so far has received only moderate SO4^2- inputs. For the southemmost, the subtropical site there is a loss of SO4^2- in the soil, which at least partly may be related to high uptake from the dense and highly productive forest at the site. The Ca^2＋ budgets for the upper 50 cm of soil show large variations both within and between sites. For most locations there is production of Ca^2＋ in the soil that can be explained by weathering, and variation between years related to hydrology that can be explained by ion exchange. However, at some plots at the site receiving very high inputs of both SO4^2- and Ca^2＋, there is an unknown sink of Ca^2＋ in the soil at some plots. 相似文献
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SYNTHESIS AND PROPERTIES OF SULFHYDRYL CHITOSAN 总被引：1，自引：0，他引：1
A new adsorbent for heavy metal ions, sulfhydryl chitosan (S-chitosan), was produced by treatment of chitosan with sulhydryl acetic acid in the presence of sulfuric acid as a catalyst. Its structure was confrrmed by elemental analysis and FI‘-IR spectra analysis. The adsorption properties of sulthydryl chitosan for Cu(Ⅱ ), Cd(Ⅱ ), Pb(Ⅱ), Cr(Ⅲ) and Ni(Ⅱ) were investigated, and the effect of pH value on adsorption, adsorption kinetics, and selective adsorption was examined. It was shown that S-chitosan has good adsorption for Pb(Ⅱ), Cu(Ⅱ) and Cd(Ⅱ) like chitosan, is also insoluble in acid solution; has good adsorption kinetic properties for heavy metal ions; and can be used in acid solution. The adsorption capacities of S-chitosan can be affected by media acidity. The adsorbed Cu(Ⅱ) Cd(Ⅱ) and Pb(Ⅱ) could be eluted by diluted chlorhydric acid. 相似文献
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美国海军陆战队信条:“一日为陆战队员,终生为陆战队员!”——题记美国首都华盛顿阿灵顿国家公墓有一座巨型雕像——6名海军陆战队士兵正奋力插起一面美国国旗.这座雕像是根据美联社记者乔·罗森塔尔拍摄的一张二战著名照片——《国旗插在琉璜岛上》塑成的,而这张照片表现的正是太平洋战争中发生在硫磺岛上的血战. 相似文献
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本文简述全球硫生产、消费和贸易概况,揭示硫磺价格变化,预计未来10年内全球硫产量大于需求量,提出了保障我国硫供应平稳的对策建议。 相似文献
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1INTRODUCTION ORGANICALLY BOUNDSULFURCOMPOUNDSWEREPREVI OUSLYDETECTEDINTHEKUPFERSCHIEFER(P櫣TTMANNAND GO EL,1990;ROSPONDEKETAL.,1994).P櫣TTMANN ANDGO EL(1990)INVESTIGATEDTHEEXTRACTABLEORGANIC MATTERINTHEKUPFERSCHIEFERFROMTHENORTH SUDETIC SYNCLINEANDPROPOS… 相似文献
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东天山硫磺山铜多金属矿床成岩成矿作用同位素地质年代学 总被引：5，自引：1，他引：5
前人根据矿体的产出受碳酸盐岩层位控制和Pb同位素模式年龄资料,多认为硫磺山铜多金属矿床为层控型铜铅锌多金属矿床,其形成时代为奥陶纪.基于矿区石英斑岩体见矿化和矿化蚀变,矿体与围岩呈渐变关系等特点,笔者主张该矿床属斑岩型铜铅锌多金属矿床.年代学研究表明,含矿石英脉Rb-Sr等时线年龄(346±30 Ma)与石英斑岩的锆石U-Pb年龄(340～360 Ma)在测定误差范围内一致,表明成岩与成矿作用均发生在早石炭世-晚泥盆世,成矿作用无论从空间上和时间上都与石英斑岩有关. 相似文献
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MA Shengfeng WANG Changqiu LU Anhuai GUO Yanjun HE Hongliao 《《地质学报》英文版》2007,81(2):330-334
High-concentrated sulfur wastewater with sodium and COD （chemical oxygen demand） up to 26000 mg/L from a chemical plant, Jiangsu Province of China has been treated by deposition of natrojarosite in lab. The results indicated that the COD of the wastewater was decreased sharply from 26000 mg/L to 1001 mg/L, with removal rate of COD up to 96% by twice precipitations of natrojarosite and twice oxidation of H202. The treated sulfur wastewater reached the requirement of subsequent biochemical treatment to water quality. The optimal operational parameters should be controlled on pH value between 2.50 and 3.20 and 50 g FeCly6H2O solid added in per liter wastewater. The study provided an experimental basis for pretreatment of high-concentrated sulfur wastewater and proposed a new mineralogical method on treatment of other wastewaters. Depositing process of jarosite and its analogs should be able to be used to treat wastewater from mine and other industries to remove S, Fe and other toxic and harmful elements, such as As, Cr, Hg, Pb, etc. in the water. 相似文献