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1.
INTRODUCTIONQuantitativebasinmodelinghasbecomeoneofthefrontiersinsedimentarybasinanalySis.Alargevarietyofnumericalmodelsconcerningbasinformation,basinfillingprocess,thermalhistory,hydrocarbongenerationandaCCUmulationhavebeenformulatedoverthelastdecadetondAnctheprocessesandevollltionofsedimentarybasins(Mckenzie,1978,signeretal.,1990;Ungereretal.,1990).Thebasinmodeling,utilizingcomputersimulationtechnique,isapowerfultoolforbasinanalySisandhasincreasinglybeenintegratedintoconventionalbasi…  相似文献   

2.
德兴矿区内普遍存在伊利石 ,其多型特征表明 ,矿化围岩与区域围岩 (>2km)中伊利石的矿物结构与矿化流体有关。经长期埋藏变质作用 ,区域围岩中形成了结晶程度完好的 2M1伊利石 ,K櫣bler指数为 0 .1 6°,Ir=1 ,无膨胀层 ,是浅变质作用的产物。与发育热液成因 1M伊利石的花岗闪长斑岩一样 ,矿化围岩发育了具有较高K櫣bler指数 (平均值为 0 .5 5°)、含少量的膨胀层 (1 %~ 5 % )、1M型伊利石 ,它是热液流体作用下伊 /蒙矿物逆向退化的结果 ,且受热液流体量及水 /岩比制约。在此 ,斑岩铜矿中伊利石多型可能成为有效的矿化晕指示剂。  相似文献   

3.
E.Schill    E.Appel    P.Gautam  WT  ”BX 《地学前缘》2000,(Z1)
TERTIARY BLOCK ROTATIONS AND PYRRHOTITE/ MAGNETITE GEOTHERMOMETRY IN THE TETHYAN HIMALAYA(SHIAR KHOLA,CENTRAL NEPAL)1 AppelE ,M櫣llerR ,WidderRW .PalaeomagneticresultsfromtheTibetanSedimentarySeriesoftheManangarea (northcentralnepal) [J].GeophysJInt ,1991,10 4:2 5 5~ 2 6 6 . 2 AppelE ,PatzeltA ,ChoukerC .SecondarypalaeoremanenceofTethyansedimentsfromtheZanskarRange (NWHimalaya)[J].GeophysJInt,1995 ,12 2 :2 2 7~ 2 42 . 3 B…  相似文献   

4.
1 Introduction Much attention has been paid to the structure, magmatism and sedimentation associated with the Indosinian Orogeny within the South China Block (SCB) since Deprat (1914) and Fromagat (1932) proposed the term “Indosinian movement” based on two unconformities between pre-Norian and pre-Rhaetian times during the early Triassic in Vietnam. However, this timing has been debated in terms of the Indosinian tectonic evolution within the SCB (Guo et al., 1983; Hsü et al., 1990…  相似文献   

5.
伊利石结晶度及其在低温变质研究中若干问题的讨论   总被引:4,自引:0,他引:4  
王河锦  陶晓风  M.Rahn 《地学前缘》2007,14(1):151-156
文中介绍与伊利石结晶度相关的伊利石矿物新的定名方案;讨论了伊利石结晶度的结晶学基础与Scherrer方程式的关系;讨论了三个重要的伊利石结晶度指数Weaver、K櫣bler和Weber指数的关系,并介绍推导的Weaver、K櫣bler和Weber指数的理论关系式;评价了衍射仪测量条件对结晶度数值的影响和三套伊利石结晶度标样的作用以及成岩带、变质带与葡萄石-绿纤石相、沸石相、绿纤石-阳起石亚相对比的依据。建议(1)停用绢云母一词;(2)建立可供各实验室使用的具有晶体结构和晶体化学参数和多型参数的伊利石结晶度标样;(3)建议多开展规范的可进行国际对比的低温变质研究,划分出与国际上一致的成岩带和近变质带,不仅利于低温变质作用理论的研究,而且由于成岩带到近变质转变带是重要的煤气油的生成带,也利于中国煤气油资源的勘探与开发,利于国民经济的长远持续发展。  相似文献   

6.
SEISMIC GEOLOGY     
(3),1 998,P.255一260,2 graPhs,12 ref,with English abstroet)981609 Chen Yuhua(Seismologieal Bureau ofQinghai Provinee,Xining,Qinghai);ZhangMin Diseussion on众ismogenie Fault for theGonghe Ms7.0 Earthquake in 1990(North-western Seismologieal Journal,ISSN 1000一0844,CN62一1048/P,20(3),1998,P.39一43,6 graPhs,6 ref) Seism吃enie strueture of the GongheMs7.0 earthquake on APr.26,1990 inQinghai Provinee 15 studied by using data ongeology,seismology and deformation.It 15possiblethat the W…  相似文献   

7.
建立了多接收器电感耦合等离子体质谱仪对Cd标准溶液同位素组成进行分析的实验方法。仪器的质量分馏校正采用Standard-Sample Bracketing法。实验结果用δ114/110Cd来表达。在此研究基础上,以SPEX Cd标准溶液为参考标准,对国外4种Cd标准溶液进行了测定。结果表明,实验测定的精度在0.07‰~0.13‰(δ114/110Cd),与目前文献报道的结果具有相似的精度。以最新SPEX Cd标准样品(δ114/110Cd=0)为基准,计算的δ114/110CdJMC、δ114/110CdSPEX-1、δ114/110CdBAM1012和δ114/110CdM櫣nster的值分别为0.55‰、0.56‰、-0.65‰和5.14‰,说明不同批次SPEX标准溶液的Cd同位素组成是明显不同的,最新的SPEX Cd标准溶液与SPEX-1 Cd的δ114/110Cd值存在着0.56‰的差别。将以SPEX Cd为参考标准的δ114/110CdBAM1012和δ114/110CdM櫣nster转化为以SPEX-1或JMC为参考标准后,得到的结果与文献报道的结果在误差范围内一致。  相似文献   

8.
罗德传 《物探与化探》1993,17(5):391-395
EL-5100型袖珍式电子计算器,比一般的计算器多10个记忆存贮器(A-J),可进行手控程序运算。在计算过程中不必用任何算法语言,只要按照键盘上按键的功能直接键入数学表达式和数据即  相似文献   

9.
为了使野外队的广大职工更好地使用和掌握EL-5002型计算器,本期刊登了这篇普及通俗读物,供初学者学习和参考。一、EIJ一5002计算器的一般介绍 (一)计算器的组成 EL一5002计算器与一般的电子计  相似文献   

10.
Overpressurehasbeenfoundinabout 180sedimentarybasins(LawandSpencer,1998;Hunt,1990 ) .Themechanismsfortheoverpressuredgenerationandthefluidflowactivitiesinoverpres suredbasinshavebeenthesubjectsofanumberofstudies (Hunt,1996 ;Ortoleva ,1994) .Probably ,themostimportantasp…  相似文献   

11.
The bulk composition of organic matter and saturated and aromatic hydrocarbons extracted from 16 samples collected from two Kuperschiefer profiles in the Rudna mine,Southwest Poland has been analyzed to study the role of organic matter during base metal enrichment in the Kupferschiefer shale.The results indicated that the extract yields and saturated hydrocarbon yields decreased with increasing base metal contents.GC and GC/MS analyses indicated that n -alkanes and alkylated aromatic compounds were depleted and may have served as hydrogen donators for thermochemical sulfate reduction.The enrichment of base metal is closely connected with the destruction of hydrocarbons.  相似文献   

12.
Previous studies have shown that the ascending, oxidizing brines play a very important role in Kupferschiefer mineralization. Fractures could be the pathway of the brines. In order to clarify the influences of the brines on bulk organic matter, aromatic hydrocarbons and Kupferschiefer mineralization, one veinlet Kupferschiefer profile from the Lubin mine, southwestern Poland was studied with the microscopic, geochemical and Rock-Eval methods. The microscopic results indicate that organic matter of the veinlet sample consists dominantly of bitumen. Its extract content is higher than in other samples. The dominant aromatic compounds are naphthalene and alkylated naphthalenes (Na-PAH), which have migrated into the veinlet sample from other sediments. The content of phenanthrene and its methylated derivatives (Ph-PAH) is much lower than in other samples. The reason may be due to their heavier mass than Na-PAH. It is more difficult for Ph-PAH to migrate. The Na-PAH was probably removed from the shale by dist  相似文献   

13.
Molecular biomarkers are the important maturity parameters for sedimentary organic matter.They have also been widely used for determining the maturity of organic matter in ore deposits. However,during the study of organic matter in the Kupferschiefer from the Lubin mine, it had been found that the biomarkers were influenced by sulfide formation. In order to probe into the degree of influence on biomarkers, seven samples collected from a Kupferschiefer section from the Lubin mine were analyzed by various geochemical methods. The results indicated that in the samples with higher copper contents, the values of biomarkers are lower than in the samples with lower copper contents. In highly mineralized samples, hydrogen donation for thermochemical sulfate reduction (TSR) occurred in alkylated phenanthrenes and naphthalenes, leading to the decrease of 12 biomarker parameters during the Kupferschiefer mineralization.  相似文献   

14.
A study of the influences of the basin brines on hydrocarbon generation of the Kupferschiefer in southwestern Poland has been carried out.The samples from the Konrad and Polkowics mines were analyzed by orgainc geochemical,microscopic and FTIR methods.The results indicate that organic matter of Kupferschiefer tends to decrease with the ascending,oxidizing brines,In the Konrad profile,the Kupferschiefer was strongly oxidized.The extract yields were depleted up to 50mg Ext/g Corg.Gas chromatography(GC) and gas chromatography-mass spctrometry(GC/MS) data indicate that the depletion occureed predominantly in saturated hydrocarbon compounds.The identified n-alkanes in smpale KD1 were depleted at least to 5000μg/g Corg.The aromatic compounds show a fidderent trend of variation.The concentrations of phenanthrene alkylphenanthrenes(Ph-PAH) and naphthalene alkylnaphthalenes(Na-PAH) show a decrease,whereas sulfur polyaromatic hydrocarbons(S-PAH)and oxygen polyaromatic hydrocarbons(O-PAH) show an incrase under the influences of oxidizing brines,In the Polkowice profile,organic matter under the influences of oxidizing fluids shows a simlar trend of varation as in the Konrad mine.Analyses of polar compounds shed light on the oxidation processes at the molecule level.The dominant products of oxidation are aliphatic acid.alcohol and ester.FTIR results indicate that the oxidation of organic matter led to a decrease in aliphatic CH3 and an increase in C-O,C=O bands.  相似文献   

15.
max vs the present depth of the Kupferschiefer, soluble organic matter (SOM) yields, and relative proportions of saturated and aromatic hydrocarbons of the SOM provide evidence for an oxidative alteration of organic matter in highly mineralized Kupferschiefer samples near the Rote F?ule zones. This is confirmed by differences in the composition of the saturated and aromatic hydrocarbon fractions of the soluble organic matter: Saturated hydrocarbons from Rote F?ule samples are dominated by short-chain n-alkanes and higher abundances of pristane and phytane relative to heptadecane (n-C17) and octadecane (n-C18), respectively, compared with samples more distant to the Rote F?ule zone. Compositional changes of the aromatic hydrocarbon fractions with decreasing distance to that zone are characterized by the occurrence of polycyclic aromatic hydrocarbons and elevated ratios of phenanthrene to methylphenanthrenes that are attributed to demethylation reactions and resulted in a decrease of the methylphenanthrene index (MPI 1). Kupferschiefer samples from the barren zone of the Polish Basin do not show these alteration patterns. The observed variations in organic matter composition with burial depth are consistent with changes due to increasing thermal maturation. Maturity assessment is achieved from MPI 1 and the methyldibenzothiophene ratio (MDR). From the relationship between the maturity of organic matter in terms of vitrinite reflectance values and depth of the Kupferschiefer strata, a continuous increase in reflectance of vitrinite is obtained within the Polish Basin. The alteration pattern of organic matter related to base metal mineralization of the Kupferschiefer corresponds to changes in the isotopic composition of organic carbon and calcite. Kerogen within, or close to, Rote F?ule zone is enriched in 13C caused by the preferential release of isotopically light organic compounds through progressive degradation of organic matter. The opposite tendency towards lower δ 13C and δ 18O values of calcite provides evidence for isotopic exchange between carbonate and the oxidizing, ore-bearing solutions and for organic matter remineralization. In contrast, organic matter and calcite from the Kupferschiefer do not show regular trends in δ 13C with increasing thermal maturation. Received: 25 June 1999 / Accepted: 1 December 1999  相似文献   

16.
Previous studies have shown that the oxidizing brines from the Early Permian Rotliegende sequence have influences on the organic matter of Kupferschiefer. However, inside the Rotliegende sequence there are two other black shales: the Lower and Upper Antracosia shales, which have not been studied as much in detail as in Kupferschiefer. In the present study 12 samples from the Lower and Upper Antracosia shales were analyzed by organic geochemical methods in order to clarify the influences of the oxidizing brines on organic matter. The results indicate that the organic matter of the samples from the Upper Antracosia shale and the bottom of the Lower Antracosia shale was oxidized under the influences of the oxidizing brines. The oxidation resulted in a depletion of saturated hydrocarbons and the alky Is of the aromatic compounds.  相似文献   

17.
Within the Central European Zechstein Basin the Permian Kupferschiefer has been deposited under anoxic conditions. In most parts of the basin, the metal content does not exceed values commonly observed in black shales. However, in areas near to the Zechstein sea-shore which are simultaneously related to rift zones a significant base metal enrichment is observed. Organic geochemical analyses of the copper-mineralized sections in the Kupferschiefer from Southwest Poland show that significant changes in the composition of organic matter are associated with the metal enrichment processes. Porphyrins, commonly abundant constituents of the shale, have been decomposed by oxidizing fluids. Additionally, aliphatic hydrocarbons have been largely removed from the bitumen and alkylated aromatic systems were affected by side-chain degradation. This particular type of alteration is explained by ascending oxidizing solutions which transported high amounts of base metals from Lower Permian red beds into the Kupferschiefer horizon acting as a geochemical trap. The metal precipitation is suggested to be a result of thermochemical sulphide production with organic matter acting as hydrogen source. In areas such as the Lower Rhine Basin in the bottom section of the Kupferschiefer the base metals lead and zinc as well as barium have been accumulated from basinal Carboniferous formation waters. Copper enrichment is not observed because potential source rocks are missing in this area. However, the observed compositional changes of the organic matter do not point towards thermochemical redox processes.  相似文献   

18.
王水溶样-氢醌容量法测定碳酸盐地质样品中的金   总被引:1,自引:1,他引:0       下载免费PDF全文
张志刚  刘凯  黄劲  高晶  陈泓  魏晶晶 《岩矿测试》2014,33(2):236-240
应用王水溶样-活性炭富集金-氢醌容量法测定岩石、土壤等一般地质样品中的金时,王水溶样后经布氏漏斗抽滤后剩余的不溶物残渣中金含量小于金总量的4%,通常不计入分析结果。而碳酸盐地质样品经焙烧后在王水溶解过程中因为钙和镁的硅酸盐含量较高,形成了不溶于王水的二氧化硅凝胶及大量钙镁胶状物,包裹和吸附样品溶液中的金,造成分析过程中金的损失。本文将抽滤后的滤液和不溶物残渣分别处理,收集王水分解样品抽滤步骤后的不溶物残渣,用氢氟酸-硫酸除硅,王水溶解测定残渣中的金含量,滤液和残渣两次测试合量为样品中金含量。实验研究了不溶物残渣中的金量、金的来源以及样品中硅钙镁的含量对金测定的影响。结果表明,不溶物残渣吸附和包裹的金量占样品金总量的18%~22%,残渣中金的主要来源是已被王水溶解但被二氧化硅等胶状物包裹吸附而未进入溶液的金,其次是未被王水溶解的单质金。胶状物的形成与样品中钙镁硅含量有直接的关系,当CaCO3、MgCO3含量达到30%以上时,必须考虑残渣中的金,以保证金的测试结果准确。  相似文献   

19.
Mining heaps are used as archives for the investigation of weathering processes. Aim of this work was to investigate the different weathering behavior of heap materials derived from Kupferschiefer mining with respect to environmental hazard. For this purpose, Kupferschiefer and slag material of two heaps of different age were examined regarding to the radionuclide distribution and geochemical composition. By measuring of the local dose rate, performing digital autoradiography and gamma spectrometry the radiological load of the heaps and the heap materials was determined. The geochemical characterization of the samples was performed by XRF, ICP–OES and ICP–MS. The results show a clear higher radionuclide load of the younger slag heap. A depletion of chalcophile and lithophile elements in the older slag was determined. Apart from a homogeneous radionuclide distribution, considerable radionuclide enrichments in fossil fragments could be proven. The results reveal a different weathering behavior of slag material in comparison to the Kupferschiefer depending on the chemical binding of the elements on organic and inorganic species. Natural organic matter as well as apatite in Kupferschiefer act as retention barrier for some metals.  相似文献   

20.
甘肃省阳山超大型金矿床的有机地球化学特征研究   总被引:7,自引:4,他引:3  
秦艳  周振菊 《岩石学报》2009,25(11):2801-2810
甘肃省文县阳山金矿是我国地质勘查储量最大的卡林-类卡林型金矿床,赋矿地层为泥盆系一套碳-硅-泥质地层.矿区发育了大量碳质千枚岩,富含有机碳.本文研究了矿石和围岩可溶有机质的生物标志物、有机质的来源和成熟度、干酪根的碳同位素等,论述了阳山金矿床的有机地球化学特征及有机质与成矿的关系,查明了参与成矿的有机质主要是菌藻类等低等生物.生物标志化合物参数和干酪根的H/C-O/C原子比值指示阳山金矿有机质成熟度较高,达到了无烟煤的演化阶段.在热演化的过程中,有机质裂解产生的CH_4和C-2H_6等进入成矿流体中,参与了成矿过程.阳山金矿赋矿地层中含有生物成因的草莓状黄铁矿,显示生物-有机质参与了地层的预富集作用.有机碳含量、有机质的类型和金的丰度之间相关性不明显,说明在阳山金矿的成矿过程中有机质对金的沉淀贡献不大,但是有机质可能参与了金的预富集和运移.  相似文献   

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