Heat capacity and phase equilibria of wadeite-type K2Si4O9     

Wenjun Yong  E. Dachs  A. C. Withers  E. J. Essene 《Contributions to Mineralogy and Petrology》2008,155(2):137-146

The low-temperature heat capacity (C _p) of Si-wadeite (K₂Si₄O₉) synthesized with a piston cylinder device was measured over the range of 5–303 K using the heat capacity option of a physical properties measurement system. The entropy of Si-wadeite at standard temperature and pressure calculated from the measured heat capacity data is 253.8 ± 0.6 J mol⁻¹ K⁻¹, which is considerably larger than some of the previous estimated values. The calculated phase transition boundaries in the system K₂O–Al₂O₃–SiO₂ are generally consistent with previous experimental results. Together with our calculated phase boundaries, seven multi-anvil experiments at 1,400 K and 6.0–7.7 GPa suggest that no equilibrium stability field of kalsilite + coesite intervenes between the stability field of sanidine and that of coesite + kyanite + Si-wadeite, in contrast to previous predictions. First-order approximations were undertaken to calculate the phase diagram in the system K₂Si₄O₉ at lower pressure and temperature. Large discrepancies were shown between the calculated diagram compared with previously published versions, suggesting that further experimental or/and calorimetric work is needed to better constrain the low-pressure phase relations of the K₂Si₄O₉ polymorphs. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Room-temperature equation of state of Li<Subscript>2</Subscript>VOSiO<Subscript>4</Subscript> up to 8.5 GPa     

Serena C. Tarantino  Michele Zema  Tiziana Boffa Ballaran  Paolo Ghigna 《Physics and Chemistry of Minerals》2008,35(2):71-76

High-pressure single-crystal X-ray diffraction measurements of lattice parameters of the compound Li₂VOSiO₄, which crystallises with a natisite-type structure, has been carried out to a pressure of 8.54(5) GPa at room temperature. Unit-cell volume data were fitted with a second-order Birch-Murnaghan EoS (BM-EoS), simultaneously refining V ₀ and K ₀ using the data weighted by the uncertainties in V. The bulk modulus is K ₀ = 99(1) GPa, with K′ fixed to 4. Refinements of third order equations-of-state yielded values of K′ that did not differ significantly from 4. The compressibility of the unit-cell is strongly anisotropic with the c axis (K ₀(c) = 49.7 ± 0.5 GPa) approximately four times more compressible than the a axis (K ₀(a) = 195 ± 3 GPa).  相似文献   

新疆库车新生代前陆褶皱冲断带的变形特征、时代和机制   总被引：18，自引：4，他引：14       下载免费PDF全文

李日俊  吴根耀  雷刚林  张敬洲  王月然  刘亚雷 《地质科学》2008,43(3):488-506

库车前陆褶皱冲断带自北向南可分为基底冲断带、箱状背斜带、梳状背斜带和挠曲褶皱带,东西方向上可分为西段、中段和东段。本文分段叙述了各变形带的变形特征,指出东段箱状背斜带不发育,秋里塔格山脉(构造带)东延未进入东段,因而总体看自西向东变形强度减弱,地形上趋于夷平。该冲断带的形成经历了两次重大的冲断活动,分别发生在中新世和早(-中)更新世;相应地,该带可分为南、北两个"盆""山"亚系统,两者在地层记录、变形期次和变形机制上尚有若干差异。库车前陆褶皱冲断带的发育,除了受南天山的冲断和向南扩展引起的近南北向挤压应力场控制外,还受到基底断裂在新生代的活化和膏盐层底辟的制约,前者以近北西向的构造变换带及其共轭发育的近北东向断层最为重要,后者既控制了秋里塔格山脉的形成(主要受垂直的挤压应力场作用),也在库车前陆褶皱冲断带东西方向的变形分段中起了重要作用。文章还讨论了变形与地貌发育的关系和在油气勘探中的指导意义。  相似文献   

Nonlinear Analysis of Local Site Effects on Seismic Ground Response in the Bam Earthquake   总被引：1，自引：0，他引：1  

M. H. T. Rayhani  M. H. El Naggar  S. H. Tabatabaei 《Geotechnical and Geological Engineering》2008,26(1):91-100

The influence of local geologic and soil conditions on the intensity of ground shaking is addressed in this study. The amplification of the ground motion due to local site effects resulted in severe damage to dwellings in the Bam area during the 2003 Bam Earthquake. A unique set of strong motion acceleration recordings was obtained at the Bam accelerograph station. Although the highest peak ground acceleration recorded was the vertical component (nearly 1 g), the longitudinal component (fault-parallel motion) clearly had the largest maximum velocity as well as maximum ground displacement. Subsurface geotechnical and geophysical (down-hole) data in two different sites have been obtained and used to estimate the local site condition on earthquake ground motion in the area. The ground response analyses have been conducted considering the nonlinear behavior of the soil deposits using both equivalent linear and nonlinear approaches. The fully nonlinear method embodied in FLAC was used to evaluate the nonlinear soil properties on earthquake wave propagation through the soil layer, and compare with the response from the equivalent linear approach. It is shown that thick alluvium deposits amplified the ground motion and resulted in significant damage in residential buildings in the earthquake stricken region. The comparison of results indicated similar response spectra of the motions for both equivalent and nonlinear analyses, showing peaks in the period range of 0.3–1.5 s. However, the amplification levels of nonlinear analysis were less than the equivalent linear method especially in long periods. The observed response spectra are shown to be above the NEHRP building code design requirements, especially at high frequencies.  相似文献   

手掘式顶管在市政排水工程中的应用          下载免费PDF全文

刘会 《探矿工程》2008,35(10):52-54

从混凝土管材的选定、工作坑的设计及施工、顶管顶进中若干关键问题入手,介绍了手掘式顶管施工技术在成都市中心城水环境综合整治工程G标段管道排水工程中的应用。  相似文献   

大同盆地孔隙地下水化学场的分带规律性研究   总被引：2，自引：0，他引：2  

苏春利  王焰新 《水文地质工程地质》2008,35(1):83-89

本文通过对大同盆地2004年孔隙地下水水化学资料的分析发现,盆地内孔隙地下水的水化学特征在水平方向上具有以盆地中部为中心,呈环状分布的特点,且与盆地水动力分区具有很好的一致性。由山前冲洪积倾斜平原到中部冲湖积平原,地下水依次经历了补给区、径流区和排泄区,相应的主要水化学类型分别为HCO3型、HCO3.SO4型和HCO3.SO4.Cl型。与中深层孔隙水相比,浅层孔隙水由于水位埋深浅,蒸发浓缩强烈,易受人类活动的影响,各组分的含量较高,变化幅度较大,水化学类型也相对复杂。浅层地下水的水质呈好转趋势,深层地下水水质基本保持稳定。  相似文献   

陕西白河县月儿潭绿松石与次生磷钙铝矾研究     

石振荣  蔡克勤 《岩石矿物学杂志》2008,27(2):164-170

对陕西省白河县月儿潭风化严重的绿松石样品进行了岩石薄片观察、化学成分测试、X射线粉晶衍射和红外吸收光谱分析等研究.结果表明,绿松石风化分解由天蓝色退色成黄绿色,最后变成白色,结构也由致密细腻变得松散多孔,主要原因是发生了硫酸根对磷酸根的交代作用,最终的交代产物主要是磷钙铝矾.  相似文献   

西天山特克斯达坂库勒萨依序列埃达克岩的确立及钼找矿意义   总被引：9，自引：6，他引：3  

李永军  辜平阳  庞振甲  栾新东  佟丽莉 《岩石学报》2008,24(12):2713-2719

库勒萨依序列斑岩体δ平均3.05,属于钙碱性系列岛弧浅成岩。 SiO₂含量为57.06％~70.74％,高Al₂O₃、Na₂O、Sr和相对富集LREE,低MgO、Y、Yb,强烈亏损HREE。Na₂O/K₂O＞1,Sr/Y平均57.67,正Eu异常,因而具有典型O型埃达克岩特征。库勒萨依序列斑岩体与Mo异常套合好,已发现钼矿体,找矿前景良好。该埃达克岩的确立,对深化西天山区域成矿规律和指导今后找矿具有借鉴和指导意义。  相似文献   

Re-Os同位素对峨眉山大火成岩省成因制约的探讨   总被引：6，自引：3，他引：3  

史仁灯  郝艳丽  黄启帅 《岩石学报》2008,24(11):2515-2523

峨眉山大火成岩省（ELIP）主要由玄武岩、玄武质火山碎屑岩及少量的苦橄岩（包括越南的科马提岩）、长英质岩石以及层状岩体和岩墙组成,其物质来源直接关系到其成因是否与地幔柱活动有关。Re-Os同位素体系是地核、地幔和地壳物质的最佳示踪剂。前人对ELIP内的Re-Os同位素研究表明,低Ti玄武岩的Os含量为0．006&#215;10^-9-0．40010^-9,^187Os／^188Os初始值为0．1371～1．403,并提出其与地幔柱活动有关;而高Ti玄武岩的Os含量为0．00410^-9～0．56010^-9,^187Os／^188Os初始值为0．1271～5．19,认为起源于大陆岩石圈地幔或地幔柱上升过程中受到大量岩石圈地幔“混染”（xu JF et al．,2007）;科马提岩的0s含量为1．2410^-9～7．0010^-9,^187Os／^188Os初始值为0．1251～0．1261,苦橄岩的Os含量为0．3210^-9～2．32910^-9,^187Os／^188Os初始值为0．1233～0．1266,指示苦橄岩和科马提岩均来自亏损地幔源区（Hanski et al．,2004;陈雷等,2007）。本文利用Os含量最低、^187Os／^188Os最高的高Ti玄武岩作为地壳端员,用铁质陨石、原始上地幔（PUM）和亏损地幔（DMM）作为地核和各种地幔端员,分别做二元混合计算,结果显示绝大多数玄武岩和所有苦橄岩及科马提岩均落在地壳和DMM混合曲线附近,并且邻区特提斯洋地幔岩与DMM具有相近的Os含量和^187Os／^188Os组成,据此推测峨眉山火成岩的形成与特提斯洋的活动有关,主要受控于地壳和亏损地幔的相互作用。  相似文献   

浙江省小流域山洪灾害临界雨量确定方法分析   总被引：12，自引：2，他引：10  

叶勇  王振宇  范波芹 《水文》2008,28(1):56-58

小流域山洪灾害具有突发性,预测预警难度较大.本文结合浙江省小流域山洪灾害防御的实践经验,研究提出了以水位反推法计算临界雨量,简单实用,具有较好的实践价值和推广意义.  相似文献