干旱区绿洲土壤共存重金属元素形态变化及生物有效性实验分析——以Cd、Zn、Ni元素为例   总被引：3，自引：0，他引：3  

赵转军  南忠仁  王胜利  刘晓文  陶燕 《地球科学进展》2008,23(11):1194-1200

采用盆栽试验,初步研究了干旱区绿洲土壤—胡萝卜系统中镉、锌、镍3种重金属的形态变化特征及其生物有效性问题。结果表明:供试绿洲土壤原状土中,Cd、Zn、Ni均以稳定的残渣态形式存在,而处理土壤中重金属被钝化的量有限,Cd的存在形式主要以碳酸盐态为主,Zn、Ni则主要以铁锰氧化态为主;3种元素的活性大小依次为Cd>Ni>Zn。根据回归分析,元素Zn对胡萝卜块茎和茎叶吸收Zn量贡献最大的分别是Zn的碳酸盐结合态和铁锰氧化态;元素Ni对胡萝卜各部位吸收贡献最大的均为Ni的铁锰氧化态。  相似文献   

基于矿物学方法评价浙江省土壤中Pb污染状况     

郑喜珅  鲁安怀  汪庆华  郑佳  朱朝晖  于芳 《地质科技情报》2008,27(3):77-82

利用土壤重金属元素环境质量矿物学评价方法,对淅江省全境土壤中不同土壤类型(或亚类)表层、不同母质表层和剖面中的Pb进行环境质量评价的结果表明,土壤中Pb的实测量和土壤对Pb的固持量决定了土壤中Pb的环境质量,浙江省土壤中Pb的污染度有正负值,说明土壤中的Pb对有些地区产生了污染,而对有些地区则没有产生污染.研究结果揭示,土壤矿物对Pb具有一定的固定与容纳能力,超过其固定与容纳能力,土壤中的Pb会对环境造成污染.这一旨在揭示土壤中重金属元素与各种矿物之间环境平衡关系的方法,可为评价土壤环境质量提供科学依据和技术支撑.  相似文献   

成都经济区黄壤土壤剖面Pb形态分布特征及其影响因素   总被引：3，自引：1，他引：2  

杨晓燕  侯青叶  杨忠芳  杨艳  赵志丹 《现代地质》2008,22(6)

土壤剖面中不同形态铅迁移转化及其影响因素的研究对于了解Pb的土壤地球化学行为具有非常重要的意义。以四川省成都经济区农田生态系统黄壤剖面中不同形态Pb分布特征为例,探讨黄壤剖面中不同形态Pb的迁移转化影响因素及其生态危害性。结果表明:在黄壤剖面中,Pb总量表现为表层富集、深层稳定的特点;弱有机结合态含量表现为表层富集、深层稳定的特点,其他形态Pb含量剖面分布特征不明显;土壤中的Pb主要是以铁锰氧化态和残渣态为主,其他形态Pb含量所占比例较小;成土过程中,随着Pb总量的增加,稳定态Pb含量增加,而活动态相对减少;土壤pH值对各形态Pb含量分布影响较大,尤其是对碳酸盐结合态的影响显著;土壤总有机碳也是影响土壤中各形态Pb含量分布的重要因素之一,尤其是对有机结合态Pb含量影响显著;而随着土壤熟化程度的增加,黄壤剖面中的活动态含量增加,稳定态减少;剖面中的Pb迁移系数和生物可利用系数均较小,说明Pb不易向下迁移,容易在表层富集,对植物及人类有一定的危害。  相似文献   

西湖茶园茶叶铅污染铅同位素示踪     

郦逸根  路远发 《物探与化探》2008,32(2):180-185

通过对西湖茶园的植物和土壤样品进行一系列的调查,以着力寻找茶叶的铅污染源。利用铅同位素技术对西湖茶园的土壤、茶叶和城区的燃煤、大气气溶胶、汽车尾气进行铅同位素示踪研究。研究表明,茶园土壤铅物质的可溶相具同源性和残查态偏于多源性。清洗后的茶叶铅含量显著降低,但其同位素组成不发生明显改变,显示出茶叶中的铅与叶面空气沉降物中的铅同源。不同介质铅同位素对比值平均值呈现表土、大气(气溶胶)、煤的w(²⁰⁶Pb)/w(²⁰⁷Pb)与茶叶趋于相近,汽油低之;表土、大气(气溶胶)、汽油的w(²⁰⁸Pb)/〔w(²⁰⁶Pb)+w(²⁰⁷Pb)〕与茶叶趋于相近,煤略高之。不同区域茶叶铅物质具同源性,与种植的农业地质背景无关。在煤燃烧、气化过程中,Pb进入大气,通过大气沉降或被茶树吸收或附着在茶叶叶面;汽车尾气的排放是茶树铅污染的重要原因之一。  相似文献   

甚低频电磁法在哈尔楚鲁图银-多金属矿区控矿构造特征分析中的应用   总被引：1，自引：1，他引：0  

徐毅  张寿庭  高阳 《大地构造与成矿学》2008,32(2):212-217

以哈尔楚鲁图银-多金属矿床为例,阐述了甚低频电磁法(VLF-EM)在覆盖区控矿构造特征分析及隐伏矿体找矿预测中的应用。VLF-EM测量和地质解释成果表明:矿区内断裂构造主要有NWW、NNW及NE三个方向。其中,NNW和NWW向断裂为主要含矿构造,二者构成菱形网格状或雁列式控矿构造基本格局,断裂交汇地段为形成较大矿体的有利地段;NE向断裂未见工业矿体产出,对矿体起到错断和破坏作用。  相似文献   

粤东成矿地质背景及银-铜-铅-锌成矿物质来源探讨     

郭锐  曾国光 《矿产与地质》2008,22(3):236-240

通过对粤东地区地层和岩石中成矿元素含量和区域地质背景的分析,认为粤东地区铜铅-锌-银成矿作用与燕山期的构造-岩浆作用关系密切,成矿物质中银-铜-锌以下地壳来源为主,铅则以上地壳及沉积地层来源为主。  相似文献   

Laser ablation coupled with ICP-MS applied to U–Pb zircon geochronology: A review of recent advances   总被引：2，自引：2，他引：0  

Alain Cocherie  Michle Robert 《Gondwana Research》2008,14(4):597

Improvements in the technology of laser ablation and ICP-MS instruments make LA-MC-ICPMS a rapid, precise and accurate method for U–Pb zircon geochronology. In this review we describe the main stages of the evolution of this in situ approach from the early 1990s to the present time. Some key points have been progressively improved. The crater size has been reduced to achieve real in situ measurements. The laser wavelength has been reduced as well as the duration of each pulse in order to lower inter-element fractionation. The blank from the gas has to be lowered as far as possible. Double focusing instruments and magnetic field sectors allow flat-topped peaks required for precise isotope ratio measurement to be obtained. The use of a multi-ion counting system significantly improves the sensitivity of the method and the static mode of integration favours the precision of measurement of the transient signal originating from a noisy laser ablated particle beam.Combining the use of a 213 nm UV laser and a MC-ICPMS equipped with a multi-ion counting system operating in static mode, the common precisions achieved for the key ratios ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁶Pb/²³⁸U are better than 1% and 3% (2σ) respectively, including error propagation associated with standard normalization. Until now, the use of a zircon standard has remained necessary to ensure the accuracy of the calculated age. A strategy for common-Pb correction is proposed according to the age of the zircon and according to the Th/U ratio of the grains. After recording sixteen to twenty spot analyses the precision usually achieved on the age is about 1% and even significantly better for Proterozoic samples.In order to show the performance achieved by modern LA-MC-ICPMS geochronology, we tested four zircon samples covering a wide age range from 290 to 2440 Ma. These new age determinations can be compared in term of precision and accuracy since they have already been dated by reference methods (ID-TIMS and SHRIMP). Further developments in the technology of ion counters equipping modern MC-ICPMS and in laser systems will certainly be applied to a large field of geochronology studies in the near future as an alternative to SIMS for in situ age determination.  相似文献   

New age constraints on emplacement of the Cévenol granitoids, South French Massif Central     

Stéphanie Brichau  Jean-Patrick Respaut  Patrick Monié 《International Journal of Earth Sciences》2008,97(4):725-738

During the development of the Variscan orogeny, large amounts of granitic melt were produced, giving rise to the intrusion of granitoids at different structural levels. Despite numerous studies, ages available from previous work on the Cévennes granites remain largely imprecise. In order to better constrain the age and emplacement mode of these granites, we have combined U–Pb dating on monazites and zircons and ⁴⁰Ar/³⁹Ar dating on biotites with petrological observations, major element chemical analysis and SEM zircon imaging on five samples from the Aigoual–St Guiral–Liron and Mont Lozère granitic massifs. The results revealed that granitic intrusions and cooling in Southern Cévennes occurred in a short time span at ∼306 Ma after the main episode of regional metamorphism. Petrological and chemical data suggest that they result from a mixing between mantle-derived basic magmas (lamprophyres) and lower crust acid magmas. At a regional scale the production of these melts occurred at the end of crustal thickening induced by nappe stacking, at the same time as the late anatectic events recorded further north in the Velay dome and the granulite facies metamorphism recorded in metasedimentary granulite enclaves brought up by Tertiary volcanoes of the Velay area (Bournac).  相似文献   

Zircon M257 ‐ a Homogeneous Natural Reference Material for the Ion Microprobe U‐Pb Analysis of Zircon     

Lutz Nasdala  Wolfgang Hofmeister  Nicholas Norberg  James M. Martinson  Fernando Corfu  Wolfgang Dörr  Sandra L. Kamo  Allen K. Kennedy  Andreas Kronz  Peter W. Reiners  Dirk Frei  Jan Kosler  Yusheng Wan  Jens Götze  Tobias Häger  Alfred Kröner  John W. Valley 《Geostandards and Geoanalytical Research》2008,32(3):247-265

We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for ²⁰⁶pb/²³⁸U and 0.7392 ± 0.0003 for ²⁰⁷pb/²³⁵U. Its ²⁰⁶pb/²³⁸U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g^?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 10¹⁸ g^?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.  相似文献   

陆丰南地区断拗转换界面厘定及其地质意义     

阙晓铭  雷永昌  张向涛  邱欣卫 《地质学报》2022,96(11):3943-3954

珠江口盆地经历裂陷阶段向拗陷阶段的转变，同期沉积地层记录了该构造变革和沉积演化过程，为厘定断拗转换界面提供了可能。基于地震反射、沉积旋回特征，识别出陆丰南地区恩平组内部存在全区可追踪对比的构造沉积转换面——T72界面，也是区分上下恩平组界面。对陆丰13洼洼间隆钻井LFA开展上下恩平组碎屑锆石U- Pb 定年、重矿物组分、元素分析，提出恩平组T72界面上下地层物源体系发生转变。结合区域沉积充填特征，表明陆丰南地区T72界面为断- 拗转换界面。具体表现为：下恩平组沉积期湖盆继承文昌期裂陷盆地特征，湖盆水体较深，物源主要为盆地内部的中生代基底凸起，沉积层序明显受盆内低凸起控制，在盆内低凸起四周发育一系列近源的辫状河三角洲，井区主要接受来自惠陆低凸起物源;上恩平组沉积期间，湖盆进入断拗过渡期，湖盆扩大、水体变浅，盆内低凸起四周的断裂活动减弱，沉积层序逐渐向盆内低凸起超覆，盆外太古宙—古生代物源组分供给不断加强，近源的三角洲砂体逐渐向远源的浅水三角洲砂体转化，同时发育宽广的滨浅湖环境，原供给物源的惠陆低凸起为水体淹没，井区接受了北部隆起外的物源。  相似文献