应用电子微探针-扫描电镜-拉曼光谱-电子背散射衍射研究一种未知Ti-Zr-U氧化物的矿物学特征   总被引：3，自引：2，他引：1  

刘亚非  王立社  魏小燕  周宁超  来志庆  杨文强  李智明  赵慧博 《岩矿测试》2016,35(1):48-55

本文应用电子微探针(EPMA)、扫描电镜(SEM)在阿尔金地区的榴闪岩中发现了一种微米级含铀氧化物矿物,结合光学显微镜、拉曼光谱和电子背散射衍射(EBSD)技术对该矿物的化学成分、赋存状态、物理及光学性质、晶体结构等矿物学特征进行了研究。结果表明,该矿物在空间上与钛铁矿关系密切且主要产于其边部,为一种不透明矿物;主要化学组成为TiO2、ZrO2和UO2,实验化学式为(Zr,U)Ti2O6,其中U与Zr互为类质同象替代;具独特的拉曼光谱特征,初步确定为斜方晶系且具有序的铌钙矿结构。通过电子微探针U-Th-Pb定年获得等时线年龄为451±49Ma,可能代表了寄主岩石的退变质年龄。将该矿物与化学成分类似的晶体进行对比,发现与斯里兰卡石等已知天然矿物存在差异,而与一种人工合成晶体Zr5Ti7O24在化学成分和晶体结构上较为相似,可以初步推断Ti-Zr-U氧化物为一种未被人们发现的新矿物。  相似文献   

Caribbean island-arc rifting and back-arc basin development in the Late Cretaceous: Geochemical, isotopic and geochronological evidence from Central Hispaniola     

J. Escuder Viruete  M. Joubert  P. Urien  R. Friedman  D. Weis  T. Ullrich  A. Prez-Estaún 《Lithos》2008,104(1-4):378-404

We present new regional petrologic, geochemical, Sr–Nd isotopic, and U–Pb geochronological data on the Turonian–Campanian mafic igneous rocks of Central Hispaniola that provide important clues on the development of the Caribbean island-arc. Central Hispaniola is made up of three main tectonic blocks—Jicomé, Jarabacoa and Bonao—that include four broad geochemical groups of Late Cretaceous mafic igneous rocks: group I, tholeiitic to calc-alkaline basalts and andesites; group II, low-Ti high-Mg andesites and basalts; group III, tholeiitic basalts and gabbros/dolerites; and group IV, tholeiitic to transitional and alkalic basalts. These igneous rocks show significant differences in time and space, from arc-like to non-arc-like characteristics, suggesting that they were derived from different mantle sources. We interpret these groups as the record of Caribbean arc-rifting and back-arc basin development in the Late Cretaceous. The> 90 Ma group I volcanic rocks and associated cumulate complexes preserved in the Jicomé and Jarabacoa blocks represent the Albian to Cenomanian Caribbean island-arc material. The arc rift stage magmatism in these blocks took place during the deposition of the Restauración Formation from the Turonian–Coniacian transition (~ 90 Ma) to Santonian/Lower Campanian, particularly in its lower part with extrusion at 90–88 Ma of group II low-Ti, high-Mg andesites/basalts. During this time or slightly afterwards adakitic rhyolites erupted in the Jarabacoa block. Group III tholeiitic lavas represent the initiation of Coniacian–Lower Campanian back-arc spreading. In the Bonao block, this stage is represented by back-arc basin-like basalts, gabbros and dolerite/diorite dykes intruded into the Loma Caribe peridotite, as well as the Peralvillo Sur Formation basalts, capped by tuffs, shales and Campanian cherts. This dismembered ophiolitic stratigraphy indicates that the Bonao block is a fragment of an ensimatic back-arc basin. In the Jicomé and Jarabacoa blocks, the mainly Campanian group IV basalts of the Peña Blanca, Siete Cabezas and Pelona–Pico Duarte Formation, represent the subsequent stage of back-arc spreading and off-axis non-arc-like magmatism, caused by migration of the arc toward the northeast. These basalts have geochemical affinities with the mantle domain influenced by the Caribbean plume, suggesting that mantle was flowing toward the NE, beneath the extended Caribbean island-arc, in response to rollback of the subducting proto-Caribbean slab.  相似文献   

Heavy metal pollution assessment in various industries of Pakistan   总被引：1，自引：0，他引：1  

Wajid Rehman  Akif Zeb  Nayyara Noor  Mohsan Nawaz 《Environmental Geology》2008,55(2):353-358

Water pollution is a source of danger to the health of people living in developing countries such as Pakistan. The main industries located at various industrial zones of Pakistan cause water pollution, which ultimately result in various diseases. The aim of the present study was to study the concentrations of essential and toxic metals (Na, K, Cu, Zn, Fe, Ca, Pb and As) in the drained water of three main industrial estates of Pakistan, i.e., Industrial Estate No. 1 Peshawar, Small Industrial Estate No. 2 Gujranwala, Industrial Estate Hattar Haripur, and in Warsak Canal (industrially pure water) with the help of atomic absorption spectroscopy and flame emission spectroscopy. The study showed high Pb and As levels originating from industries. The concentrations of Pb and As ranged from 0.04 to 0.942 mg/L in all the samples. These have been extensively used for irrigation since the last five decades. The elevated concentrations of heavy metals are continuously entering into the food chain through agriculture leading to serious health hazards and a threat to the sustainability of local ecosystem.  相似文献   

生物挥发性有机物研究进展   总被引：4，自引：1，他引：3  

石明洁  延晓冬  贾根锁 《地球科学进展》2008,23(8):866-873

生物挥发性有机物(BVOCs)作为大气中的一种痕量气体,积极参与着大气中各类化学反应。植物BVOCs排放的影响机制,以及BVOCs与大气其他化学成分之间的反馈作用是目前全球变化研究的热点内容之一。描述了BVOCs的排放机理及其排放控制因子;综述了近年来BVOCs地表观测试验和计算方法的研究进展以及植被BVOCs排放的模拟研究现状,并对BVOCs研究的不足和发展趋势作了进一步讨论。  相似文献   

Volcanic and Tectonic Framework of the Hydrothermal Activity of the Izu–Bonin Arc     

Osamu Ishizuka 《Resource Geology》2008,58(3):206-219

In the Izu–Bonin Arc, hydrothermal activities have been reported from volcanoes along present‐day volcanic front, a rear arc volcano and a back‐arc rift basin as well as a remnant arc structure now isolated from the Quaternary arc. It is widely known that characteristics of hydrothermal activity (mineralogy, chemistry of fluid etc.) vary depending upon its tectonic setting. The Izu–Bonin Arc has experienced repeated back‐arc or intra‐arc rifting and spreading and resumption of arc volcanism. These characteristics make this arc system a suitable place to study the tectonic control on hydrothermal activity. The purpose of the present paper is, therefore, to summarize volcanotectonic setting and history of the Izu–Bonin Arc in relation to the hydrothermal activity. The volcanotectonic history of the Izu–Bonin Arc can be divided into five stages: (i) first arc volcanism (boninite, high‐Mg andesite), 48–46 Ma; (ii) second arc volcanism (tholeiitic, calc‐alkaline), 44–29 Ma; (iii) first spreading of back‐arc basin (Shikoku Basin), 25–15 Ma; (iv) third arc volcanism (tholeiitic, calc‐alkaline), 13–3 Ma; and (v) rifting in the back‐arc and tholeiitic volcanism along the volcanic front, 3–0 Ma. Magmas erupted in each stage of arc evolution show different chemical characteristics from each other, mainly due to the change in composition of slab‐derived component and possibly mantle depletion caused by melt extraction during back‐arc spreading and prolonged arc volcanism. In the volcanotectonic context summarized here, hydrothermal activity recognized in the Izu–Bonin Arc can be classified into four groups: (i) present‐day hydrothermal activity at the volcanic front; (ii) active hydrothermal activity in the back arc; (iii) fossil hydrothermal activity in the back‐arc volcanoes; and (iv) fossil hydrothermal activity in the remnant arc. Currently hydrothermal activities occur in three different settings: submarine caldera and stratocones along the volcanic front; a back‐arc rift basin; and a rear arc caldera. In contrast, hydrothermal activities found in the back‐arc seamount chains were associated with rear arc volcanism in Neogene after cessation of back‐arc spreading of the Shikoku Basin. Finally, sulfide mineralization associated with boninitic volcanism in the Eocene presumably took place during forearc spreading in the initial stage of the arc. This type of activity appears to be limited during this stage of arc evolution.  相似文献   

从科学和政策视角看碳预算对全球气候治理的作用     

陈晓婷  陈迎 《气候变化研究进展》2018,14(6):632-639

IPCC第五次评估报告进一步阐述和明确了全球平均地表温升与累积CO₂排放之间的近似线性关系。尽管在科学上仍存在一定的不确定性,国际社会对2℃温升目标及所对应的全球累积碳排放空间(即全球碳预算目标)已达成一定的科学认知和政治共识。但如何将碳预算从目标要求转变为各国决策和实际行动,仍是政策制定者们所面临的一个重要问题。在此背景下,提出建立一个有效的碳预算综合管理框架,努力避免人为温室气体排放导致气候系统危害,并利用其科学和政策的双重内涵,来推动谈判进程和加大行动力度,在新型气候治理模式下推动全球减排目标的实现。  相似文献   

Rapid vertical motions and formation of volcanic arc gaps: Plateau collision recorded in the forearc geological evolution (Costa Rica margin)     

《Basin Research》2018,30(5):863-894

The collision of bathymetric features with modern convergent margins has been investigated with the full range of tools used in geosciences. Hence, a comprehensive picture exists of the characteristic effects of collision events on the evolution of convergent margins. In contrast, much less studies documented past collisions of bathymetric features with convergent margins, as colliding features were generally lost to subduction. The arc‐trench system of southern Central America provides modern and past textbook examples of active margin interaction with incoming bathymetric reliefs. Here, we propose a synthesis which combines basin and terrane analysis of the forearc of northern Costa Rica and takes up the challenge of documenting past episodes of plateau accretion to the active margin. As illustrated in modern examples, our study shows that kilometric uplift of the overriding plate and termination of the volcanic arc activity are the most profound effects of colliding/accreting oceanic plateaus. Kilometric uplift of the forearc is documented by short‐lived (ca. 3 m.y.) occurrences of shallow‐water deposits in an overall deep‐water forearc record. These shallow deposits contain material reworked from underlying sedimentary and basement lithologies. The development of spatial gaps in arc volcanism is deduced from the transition from arc‐derived turbidites to pelagic sediments. Eventually, end of the collision event is evidenced by the subsidence of the whole forearc to deep‐water environments. Basin subsidence is accompanied or followed by renewed volcanic arc activity and coeval arc‐derived sedimentation, which may occur 1–7 m.y. after plateau collision. These past episodes of plateau accretion are archetypal for the following reasons: (a) they may be studied in outcrop, whereas most of the modern collisions of plateaus largely occur underwater; (b) no tectonic or metamorphic imprint has significantly complicated the forearc geological record; (c) the colliding feature and the sedimentary response to its collision are both preserved in the forearc geology; (d) they may be used as analogues for any setting where a bathymetric feature is suspected to have caused rapid forearc uplift and cessation of the volcanic arc activity.  相似文献   

主要发达经济体从碳达峰到碳中和的路径及启示     

樊星  李路  秦圆圆  高翔 《气候变化研究进展》2023,19(1):102-115

随着气候变化影响加剧,全球气候治理进程加速,实现碳达峰已经成为全球气候行动的核心,各国也相继制定碳中和目标并开展行动。中国在第75届联合国大会一般性辩论上提出了碳达峰碳中和目标,部分已实现碳达峰的发达经济体也提出了各自的碳中和承诺。文中从“整体-阶段”及“焦点-公平”视角分析了欧盟和美国等主要发达经济体碳达峰的历程和特点,以及其碳中和目标和规划。研究发现,发达经济体在碳达峰过程中普遍经历了较长的爬坡期（58~136年）和平台期（4~20年),在碳达峰时,发达经济体的能源结构以油气为主,油气占一次能源消费比重为57%~77%,其人均排放量、历史累计排放以及人均GDP也都处于较高水平,在碳达峰前后总体处于经济与碳排放脱钩状态。各发达经济体的碳中和路径均以能源转型为重点,采用了多元化的政策工具,并且注重低碳和负碳技术的革新。根据发达经济体的政策展望,在实现碳中和时,均难以将绝对排放量降为零,都需要通过碳移除手段进行抵消。通过对比分析,发现中国的碳达峰和碳中和目标是具有雄心的气候承诺,相较其他发达经济体需要付出更大努力。建议运用全面综合的政策工具支撑碳中和目标的有效落实,加快中国的气候立法,在兼顾公正转型的同时推动能源结构调整,注重可再生能源和能效方面的新技术开发应用。  相似文献   

Kinematic metrics of the Loop Current in the Gulf of Mexico from satellite altimetry     

《Dynamics of Atmospheres and Oceans》2016

We analyzed a 20-year time series (January 1st, 1993 through December 31st, 2012) of Loop Current (LC) surface area derived from satellite altimetry in the eastern Gulf of Mexico to estimate kinematical metrics of this potent flow. On average the LC intrudes to its maximum northward position about 216 ± 126 days after the previous eddy separation; and ∼30 ± 31 days later sheds a large anticyclonic eddy. When the northern extent of the LC intrusion following the previous eddy separation is greater than 27°N, the current retreats very quickly until it sheds another eddy with the entire separation process occurring on the order of 30 days. To first order the change in areal extent of the LC during intrusion into the Gulf occurs at an average rate of 225 km² day⁻¹, which corresponds to an intrusion velocity of 1.7 cm s⁻¹ of the LC front, and adds Caribbean water to the Gulf at a rate of 2.6 ± 0.7 Sv.  相似文献   

Applying seismic geomorphology to delineate switched sequence stratigraphic architecture in lacustrine rift basins: An example from the Pearl River Mouth Basin,northern South China Sea     

《Marine and Petroleum Geology》2016

Switched sequence stratigraphic architectural units were developed in the Eocene Wenchang Formation stratigraphic section of the Pearl River Mouth Basin (PRMB), northern South China Sea. Utilizing a high-quality 3D seismic data set, well logs and restored paleogeomorphology, the architecture and genesis of switched sequence stratigraphic units have been systematically investigated. The Wenchang Formation, a second-order sequence, can be subdivided into seven third-order sequences (from base to top: SQ1, SQ2, SQ3, SQ4, SQ5, SQ6, and SQ7). The sequence stratigraphic architecture of the Wenchang Formation is characterized by continuous lateral stacking patterns from sequences SQ1 to SQ7. Sequences SQ1–SQ4 mainly developed in the HZ26 sag, whereas sequences SQ5–SQ7 mainly developed in the XJ24 sag. The depositional centres of the Wenchang Formation appear to have migrated from the HZ26 sag to the XJ24 sag-along the northwest direction from sequences SQ1 to SQ7. Multiple tectonic activation episodes or alternating tectonic subsidence of the HZ26 and XJ24 sags resulted in the distinctive geomorphological features that effected the development of the switched sequence stratigraphic architecture in the study area. The switched sequence stratigraphic architecture presented in this study may provide new insights into a better understanding of sequence stratigraphic stacking patterns in continental lacustrine rift basins.  相似文献