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41.
Summary The gas permeability of a coalbed, unlike that of conventional gas reservoirs, is influenced during gas production not only by the simultaneous changes in effective stress and gas slippage, but also by the volumetric strain of the coal matrix that is associated with gas desorption. A technique for conducting laboratory experiments to separate these effects and estimate their individual contribution is presented in this paper. The results show that for a pressure decrease from 6.2 to 0.7 MPa, the total permeability of the coal sample increased by more than 17 times. A factor of 12 is due to the volumetric strain effect, and a factor of 5 due to the gas slippage effect. Changes in permeability and porosity with gas depletion were also estimated using the measured volumetric strain and the matchstick reservoir model geometry for flow of gas in coalbeds. The resulting variations were compared with results obtained experimentally. Furthermore, the results show that when gas pressure is above 1.7 MPa, the effect of volumetric strain due to matrix shrinkage dominates. As gas pressure falls below 1.7 MPa, both the gas slippage and matrix shrinkage effects play important roles in influencing the permeability. Finally, the change in permeability associated with matrix shrinkage was found to be linearly proportional to the volumetric strain. Since volumetric strain is linearly proportional to the amount of gas desorbed, the change in permeability is a linear function of the amount of desorbing gas. 相似文献
42.
通过对碳酸锰氧化实验的结果分析和讨论，建立了一种适合于锰氧化过程的非平衡热力学模型，并利用此模型对硫酸锰氧化过程作了热力学可行性分析，研究结果表明，碳酸锰氧化过程是矿物组合的变化过程，也是锰自身价态的转为过程，整个过程既存在平衡状态，又存在非平衡状态，是一个不可逆的，多相的复杂反应。 相似文献
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Ralph Lehmann 《Journal of Atmospheric Chemistry》2004,47(1):45-78
When the output of a complex chemical model is analysed, a typical topic isthe determination of pathways, i.e., reaction sequences, that produce ordestroy a chemical species of interest.A representative example is the investigation of catalytic ozone destruction cycles in the stratosphere.An algorithm for the automatic determination of pathways in any given reactionsystem is presented. Under the assumption that reaction rates are known, it finds all significant pathways, i.e., all pathways with a rate above a prescribed threshold.The algorithm forms pathways step by step, starting from single reactions.The chemical species in the system are consecutively considered as `branching points'.For every branching-point species, each pathway producing it is connected witheach pathway consuming it.Rates proportional to `branching probabilities' are calculated.Pathways with a rate that is smaller than a prescribed threshold arediscarded.If a newly formed pathway contains sub-pathways, e.g., null cycles, it is split into these simpler pathways.In order to demonstrate the performance of the algorithm, it has been applied to the determination of catalytic ozone destruction cycles and methaneoxidation pathways in the stratosphere. 相似文献
44.
填埋场粘性土防渗层中强化微生物对垃圾污染物的净化作用 总被引：3，自引：0，他引：3
如何铺设价廉物关的防渗层,又不需对垃圾渗滤液进行处理,达到环保效果好、成本低的目的,是填埋场防渗衬垫铺设所追求的,但由于科学理论及技术条件的限制,这个目的一直没有达到。通过添加营养菌液强化厌氧微生物对污染物的净化作用,在实验室用土柱进行模拟实验及天然的土柱淋滤净化对比实验,研究了粘性土垫层土中添加营养菌液后,厌氧微生物对垃圾污染物的净化能力的变化,得出了加入厌氧微生物菌液后,可显著地提高微生物在土中对垃圾污染物的净化能力的结论。这为开发价廉物美的垃圾场防渗衬垫打开了思路,为有污染问题的垃圾场提供了一种用微生物治理的方法。 相似文献
45.
Development characteristics of interlayer oxidation zone type of sandstone uranium deposits in the southwestern Turfan-Hami basin 总被引：3，自引：0，他引：3
YANG Dianzhong XIA Bin & WU Guogan Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou China 《中国科学D辑(英文版)》2004,47(5)
The known uranium ore and anomaly occur-rences are distributed mainly in the southwestern part of the Turfan-Hami basin. The focus of current explo-ration is placed on the leachable interlayered oxidation zone type of sandstone uranium deposits. Uranium deposits in the sedimentary basin can be classified into three types in accordance with their host rock types, i.e. the sandstone-type uranium deposits, the coal rock-type uranium deposits and the mud-stone-type uranium deposits. The sandstone… 相似文献
46.
YU Yunmei ZHU Yongxuan & GAO Zhenmin Key Laboratory of Ore Deposit Geochemistry Chinese Academy of Sciences Guiyang China 《中国科学D辑(英文版)》2004,47(5)
Arsenopyrite is one of the most important pri-mary arsenic mineral. In the Eh-pH diagram of the As-O2-S-H2O system, if the total arsenic concentration (TAs) is taken to be 0.75 mg/L, the total sulfur con-centration, 32 mg/L, the temperature, 25℃and the pressure, one atmosphere pressure for the discrimina-tion of arsenic species, it may be found that under hy-pergene conditions, arsenopyrite is a moderately stable mineral. Only in the strongly alkaline and reducing environment can arsenopy… 相似文献
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主要介绍了近 2 0年来稻田甲烷排放的模式研究和排放量的估算以及减少稻田甲烷排放的措施。数值模式是估算稻田甲烷排放量的一条有效途径 ,模式的研究现在正处于发展阶段。介绍了几个主要的模型 ,既有物理过程模型也有经验模型。年排放量的估算范围为 6 79～ 4 1 4Tg ,随着技术的发展和大量实验的进行估算值的精度正得到不断的提高。减排措施是减少稻田甲烷排放的必要手段 ,但是目前的减排技术均处于研究阶段 ,应用还不成熟 相似文献
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