Possible chemical structures and biological precursors of different vitrinites in coal measure in Northwest China     

Dayong Liu  Ping'an Peng   《International Journal of Coal Geology》2008,75(4):204-212

Chemical structure of Jurassic vitrinites isolated from the coals in basins in NW China have been checked using solid state ¹³C NMR and flash pyrolysis-GC/MS. Study shows some Jurassic collodetrinites are rich in aliphatic products in pyrolysates, consisting with the high amount of methylene carbon in ¹³C NMR spectra. In contrast, pyrolysates of Jurassic collotelinites are rich in phenols and alkylbenzenes. Also one Pennsylvanian and one Permian vitrinite selected from the Ordos basin, NW China have been checked for comparison. The proportion of aliphatics is low in pyrolysates, and aliphatic carbon peak in ¹³C NMR spectrum of Permian vitrinite is mostly composed of gas-prone carbons compared with collodetrinites in those Jurassic basins. But both pyrolysis and ¹³C NMR data shows the Pennsylvanian vitrinite is not only gas-prone but also oil-prone. Relatively high proportion of long chain aliphatic structure of some Jurassic vitrinite in Junggar, Turpan-Hami basins may be due to the contribution of liptodetrinites, which may be included during the formation of vitrinites. And it seems that suberinite is the most possible precursor of long chain aliphatics in the structure of Jurassic collodetrinite.  相似文献   

赣南崇义—大余—上犹矿集区不同类型含矿石英中白云母40Ar/39Ar年龄及其地质意义   总被引：14，自引：0，他引：14  

刘善宝  王登红  陈毓川  李建康  应立娟  许建祥  曾载淋 《地质学报》2008,82(7):932-2008-01-30

崇义—大余—上犹矿集区是世界著名的黑钨矿床集中区,本文选择钨锡多金属硫化物石英脉型（柯树岭和漂塘矿床）和锡钨石英脉型（仙鹅塘矿床）3个矿床石英中的白云母开展40Ar/39Ar年代学研究,测得坪年龄分别是：钨锡多金属硫化物石英脉型是 158.9 ± 1.4 Ma（漂塘）、158.8 ± 1.2 Ma（柯树岭）;钨锡石英脉型的是231.4 ± 2.4 Ma（仙鹅塘）,在反等时线图上,其对应的截距年龄分别是158.8 ± 1.6 Ma、158.7 ± 1.9Ma和232.5 ± 2.4 Ma。由此表明,在崇余犹矿集区内存在两个不同成矿时期,即以黑钨矿为主的多金属硫化物石英脉型矿床形成于中侏罗世,集中于160~150Ma之间,与南岭地区钨锡矿床的主成矿期是一致的;而以锡石为主的,并含有大量白钨矿的石英脉型矿床可形成于印支期  相似文献   

赣南淘锡坑钨多金属矿床花岗岩和云英岩岩石特征及云英岩中白云母40Ar/39Ar定年     

guochunli 《地质学报》2008,82(1):1274-1284

赣南崇义县淘锡坑钨矿位于南岭东西向构造带东段,属于以黑钨矿石英脉型为主的钨多金属矿床。矿床形成与燕山期中酸性岩浆作用有密切关系,石英矿脉受一组北西向断裂控制,穿切新元古界。本文在淘锡坑钨矿区3个揭露到花岗岩体顶部的中段（206、106、56中段）采集到岩体顶部云英岩样品,利用40Ar/39Ar同位素定年测得云英岩中的白云母的坪年龄分别为152.7 ± 1.5 Ma（206中段）,153.4 ± 1.3 Ma（106中段）,155.0 ± 1.4 Ma（56中段）。与前人用其他方法测定的花岗岩成岩和成矿年龄几乎一致。花岗岩和云英岩全岩稀土元素均具有M型四分组效应和强烈的Eu亏损特征,反映出花岗质岩浆经历了高度分异演化及其岩体结晶晚期流体/熔体相互作用。综合前人在南岭地区同类矿床的研究资料,可知南岭地区160～150Ma成岩成矿作用主要分布于南岭中-东段,可能为大陆边缘弧后岩石圈伸展的构造动力学背景的产物。  相似文献   

安徽铜陵狮子山矿田岩浆岩锆石SHRIMP定年及其成因意义   总被引：36，自引：4，他引：32  

徐晓春  陆三明  谢巧勤  柏林  储国正 《地质学报》2008,82(4):500-509

铜陵狮子山矿田发育大量岩浆岩,且与矿田中的铜金多金属成矿关系密切。锆石SHRIMP同位素精确定年表明,矿田中的岩浆侵位年龄在132.4～142.9Ma之间,即晚侏罗世—早白垩世,属燕山早期晚阶段。矿田岩浆岩体是在同期岩浆活动中多次侵位形成的,岩浆侵入活动可以划分为分别起始于140Ma前后和约136Ma的早晚两次。从岩浆上升侵位到冷却结晶的时间间隔均较短,但其中白芒山辉石二长闪长岩冷却史相对较长,且经历了早期深部岩浆房中的分离结晶作用和后期构造脉动、岩浆上升侵位、减压受热、早期晶体再熔蚀及冷却结晶的过程。结合主量元素和微量元素地球化学研究认为,狮子山矿田岩浆演化的后期,即起源于上地幔或下地壳的原生岩浆在同化了壳源物质并聚集到岩浆房中以后,在滞留的过程中发生了一定程度的分离结晶作用,但尚未固结,成分上显示了一定的带状分布,在区域构造应力松弛及构造事件诱发下,随机地沿发育的构造裂隙先后上升侵位,冷凝结晶。  相似文献   

西藏东巧蛇绿岩中辉长岩锆石SHRIMP定年及其地质意义   总被引：9，自引：0，他引：9  

夏斌  徐力峰  韦振权  张玉泉  王冉  李建峰  王彦斌 《地质学报》2008,82(4):528-531

东巧蛇绿岩位于分割羌塘地块和拉萨地块的班公湖—怒江缝合带中段,是该带最著名的产铬铁矿床的蛇绿岩残片之一。该蛇绿岩遭受构造肢解,恢复后的蛇绿岩剖面各岩石单元齐全。本文应用SHRIMPⅡ锆石UPb法,对东巧蛇绿岩中堆晶辉长岩进行了测年,获得辉长岩年龄为187.8±3.7 Ma。该年龄代表了东巧洋盆的形成时代,为确定研究区特提斯洋盆的古构造格局及其发育演化过程等提供了重要的年代学制约。  相似文献   

云南个旧老厂-卡房花岗岩体成因：锆石U-Pb年代学和岩石地球化学约束   总被引：20，自引：2，他引：18  

程彦博  毛景文 《地质学报》2008,82(11):1478-1493

在云南个旧地区发育大量与成矿时空密切相关的侵入岩。个旧东区的老厂-卡房花岗质岩体为一隐伏的花岗岩体,侵入于三叠纪个旧组灰岩和碳酸盐地层中,岩性主要为中细粒黑云母花岗岩,是个旧地区与成矿关系最为密切的花岗岩体之一。岩石的ACNK值大多在1.0以上,属于高钾钙碱性系列岩石;U、Th含量较高,应归属于HHP花岗岩;岩石类型属于S型花岗岩,但经历了高度的分异和演化;n(Rb)/n(Sn)- n(Rb)/n(Ba)与n(CaO)/n(Na2O)-n(Al2O3)/n(TiO2)图解均暗示岩石的源区性质为由粘土岩所派生的岩浆。锆石LA-ICP-MS定年结果表明,老厂-卡房岩体形成于85±0.85Ma,相当于晚白垩世。根据区域地质和花岗岩的地球化学特征,暗示个旧地区燕山晚期处于伸展构造背景。  相似文献   

西天山达巴特火山岩的形成环境及对斑岩型矿化的制约     

张作衡 《地质学报》2008,82(11):1494-1503

本文通过对西天山地区比较典型的达巴特斑岩铜钼矿床矿区范围内出露上的英安岩和花岗斑岩进行了系统的岩石地球化学分析,对英安岩和流纹斑岩中的锆石进行了SHRIMP U-Pb定年研究,分别获得了315.9±5.9Ma和278.7±5.7Ma。岩石化学、微量以及稀土元素特征表明从英安岩到花岗斑岩,岩体具有明显的分异演化特征和很好的继承性。火山岩和次火山岩的精确定年为准确厘定火山岩形成的时限和地球动力学背景提供了依据。结合已有的Re-Os法获得的矿化年龄,表明晚石炭世末-早二叠世初（278.7±5.7Ma）,西天山地区进入板块碰撞-板内伸展阶段,由于板内幔根的部分熔化,造成深源斑岩岩浆侵位,在达巴特矿区形成了由花岗斑岩、流纹斑岩和流纹质凝灰熔岩组成的椭圆形火山机构,并导致相关矿床的形成。  相似文献   

江西省武功山地区浒坑钨矿床的Re-Os年龄及其地质意义   总被引：2，自引：0，他引：2  

刘珺 《地质学报》2008,82(11):1572-1579

浒坑钨矿床是位于江西省中部武功山成矿带的大型石英脉型黑钨矿床。为了确定该矿床的成矿时代,笔者选取了浒坑含钨石英脉中与黑钨矿共生的辉钼矿进行了高精度Re-Os同位素定年,并获得5个辉钼矿样品的Re-Os等时线年龄和模式加权平均年龄分别为150.2±2.2Ma和149.82±0.92Ma。测年数据表明浒坑钨矿床的成矿时代为150Ma左右,是华南地区中生代大规模成岩成矿作用高峰期的产物。辉钼矿含铼较低,表明成矿物质可能来自壳源,与形成浒坑花岗岩体的燕山期重熔S型花岗岩岩浆活动有关。该矿床形成于燕山期岩石圈伸展减薄环境。  相似文献   

History of crustal growth and recycling at the Pacific convergent margin of South America at latitudes 29°–36° S revealed by a U–Pb and Lu–Hf isotope study of detrital zircon from late Paleozoic accretionary systems     

A.P. Willner  A. Gerdes  H.-J. Massonne 《Chemical Geology》2008,253(3-4):114-129

Detrital zircon provides a powerful archive of continental growth and recycling processes. We have tested this by a combined laser ablation ICP-MS U–Pb and Lu–Hf analysis of homogeneous growth domains in detrital zircon from late Paleozoic coastal accretionary systems in central Chile and the collisional Guarguaráz Complex in W Argentina. Because detritus from a large part of W Gondwana is present here, the data delineate the crustal evolution of southern South America at its Paleopacific margin, consistent with known data in the source regions.Zircon in the Guarguaráz Complex mainly displays an U–Pb age cluster at 0.93–1.46 Ga, similar to zircon in sediments of the adjacent allochthonous Cuyania Terrane. By contrast, zircon from the coastal accretionary systems shows a mixed provenance: Age clusters at 363–722 Ma are typical for zircon grown during the Braziliano, Pampean, Famatinian and post-Famatinian orogenic episodes east of Cuyania. An age spectrum at 1.00–1.39 Ga is interpreted as a mixture of zircon from Cuyania and several sources further east. Minor age clusters between 1.46 and 3.20 Ga suggest recycling of material from cratons within W Gondwana.The youngest age cluster (294–346 Ma) in the coastal accretionary prisms reflects a so far unknown local magmatic event, also represented by rhyolite and leucogranite pebbles. It sets time marks for the accretion history: Maximum depositional ages of most accreted metasediments are Middle to Upper Carboniferous. A change of the accretion mode occurred before 308 Ma, when also a concomitant retrowedge basin formed.Initial Hf-isotope compositions reveal at least three juvenile crust-forming periods in southern South America characterised by three major periods of juvenile magma production at 2.7–3.4 Ga, 1.9–2.3 Ga and 0.8–1.5 Ga. The ¹⁷⁶Hf/¹⁷⁷Hf of Mesoproterozoic zircon from the coastal accretionary systems is consistent with extensive crustal recycling and addition of some juvenile, mantle-derived magma, while that of zircon from the Guarguaráz Complex has a largely juvenile crustal signature. Zircon with Pampean, Famatinian and Braziliano ages (< 660 Ma) originated from recycled crust of variable age, which is, however, mainly Mesoproterozoic. By contrast, the Carboniferous magmatic event shows less variable and more radiogenic ¹⁷⁶Hf/¹⁷⁷Hf, pointing to a mean early Neoproterozoic crustal residence. This zircon is unlikely to have crystallized from melts of metasediments of the accretionary systems, but probably derived from a more juvenile crust in their backstop system.  相似文献   

The double solid reactant method: II. An application to the shallow groundwaters of the Porto Plain,Vulcano Island (Italy)     

Matteo Lelli  Roberto Cioni  Luigi Marini 《Environmental Geology》2008,56(1):139-158

This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.

Luigi Marini (Corresponding author)Email:

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