金伯利岩型金刚石矿床研究及其成矿模式探讨——以辽宁瓦房店地区金刚石原生矿矿床为例     

刘礼广  吴大天  韩双  万方来  林少全  杨献忠 《地质学报》2020,94(9):2650-2665

辽宁南部瓦房店金刚石矿是国内最大的金刚石矿产区,现已发现4处金刚石成矿带、120个岩体。其中金伯利岩岩管24个、岩脉89个、可疑岩体7个,累计提交1221万克拉储量,占全国金刚石储量52%。本文主要对该矿床的金刚石母岩—金伯利岩的岩石地球化学特征进行了全面系统分析,发现金伯利岩中MgO、NiO、Cr 2O 3的含量与TiO 2、Al 2O 3、Na 2O、K 2O、CaO、P 2O 5等偏碱性组分呈正相关关系;Ni、Cr、Co含量与金刚石含量呈正相关,而Ti、Zr、Ba元素含量与金刚石含量呈负相关。通过对瓦房店矿区金刚石中石榴石及单斜辉石包裹体、橄榄石- 石榴石矿物对、石榴石微量元素、尖晶石- 橄榄石等多种地质温、压计归纳得出金刚石矿的来源深度为150~210 km,压力5~7 GPa,温度1083~1261℃,在上述温、压条件下,结合岩浆化学组成,估算金伯利岩具有低氧逸度(fO 2=2. 913×1. 01325×10-6Pa)的特点。结合野外勘查工作,总结了该矿床的地质特征、控矿构造、矿体空间分布规律等要素,认为NEE向和NE向断裂控制着金伯利岩体的展布方向和矿体形态。脉状金伯利岩体一般呈NEE 70°~80°方向展布,严格受NEE至近EW向的密集节理或裂隙控制。提出了金刚石母岩—金伯利岩是由源于上地幔岩浆,在一定的封闭条件下,受构造与岩性双重控制,多期性的爆发与侵入交替作用所形成,并建立了具有较高氧逸度和较高密度的流变性软流圈,通过渗滤熔体浸蚀岩石圈形成金刚石的理想成因模式,希望为下一步找矿工作提供参考。  相似文献   

榍石LA-ICP-MS U-Pb定年中元素分馏的影响及校正研究     

靳梦琪  李艳广  王鹏  汪双双  黎卫亮 《岩矿测试》2020,39(2):274-284

同位素地质年代学是探索地质体时空演化及地球动力学等问题的基础学科,应用最为广泛的当属含铀副矿物的U-Pb定年技术。榍石具有相对较低的U-Pb体系封闭温度,并广泛发育于岩浆岩、各类变质岩、热液成因岩石以及少量沉积岩中,是一种理想的中高温地质事件定年矿物。利用电感耦合等离子体质谱法(ICP-MS)测定榍石U-Pb年龄时,不可避免地要解决高普通铅以及元素分馏效应对测试的影响。本文对榍石LA-ICP-MS实验过程中的元素分馏行为进行研究,采用相同基体的标准样品与未知样品对比,发现了榍石不同颗粒之间元素分馏行为不一致的现象;同时采用不同的元素分馏校正方法,分别应用于锆石、独居石和榍石进行对比研究,认为分馏行为一致的副矿物定年可以采用"指数法"和"均值法"对数据进行校正,但是对于榍石这种分馏行为不一致的副矿物,定年时只有采用"截距法"对数据进行校正才可以获得正确的年龄。进而将此结论应用于秦岭造山带老牛山地区岩浆成因榍石样品,得到的结果与锆石年龄一致,表明"截距法"可以避免分馏行为不一致导致的校正不准确的问题。本研究成果为榍石LA-ICP-MS U-Pb定年方法的完善提供了一种思路。  相似文献   

GBW10010a大米标准物质复(研)制及数据特征     

杨榕  顾铁新  潘含江  刘妹  周国华 《岩矿测试》2020,39(6):866-877

随着我国对生态文明建设的重视,自然资源综合调查势在必行,对生物标准物质亦提出了新的需求。当前相关调研工作已经大面积开展,自然资源综合调查、农产品与食品安全评价都需要对生物样品元素组成进行准确测试,需要以生物标准物质作为生物成分测试量值比对和溯源的基础,因此对生物基体标准物质的需求量大幅增加。大米作为主要粮食之一,其食品安全日益受到重视,对大米中的化学成分进行准确的分析测试具有重要的现实意义,因而对大米标准物质的需求量尤为突出,但目前大米成分分析标准物质已供不应求。本文严格按照《标准物质定值的通用原则及统计学原理》（JJF 1343—2012）和《地质分析标准物质的研制》（JJF 1646—2017）等相关规范要求,开展了GBW10010a大米成分分析标准物质的复（研）制工作,包括样品采集、加工制备、均匀性检验、稳定性检验、多家实验室协作定值测试及不确定度评定等关键环节。结果表明：本次复（研）制的大米标准物质定值成分多样、量值准确可靠,符合国家一级标准物质的要求。GBW10010a共定值54项主微量元素,包括Ag、Al、As、B、Ba、Be、Bi、Ca、Cd、Ce、Co、Cr、Cs、Cu、Dy、Er、Eu、Fe、Gd、Ge、Hg、Ho、K、La、Li、Ho、Mg、Mn、Mo、N、Na、Nb、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Sc、Se、Si、Sm、Sr、Tb、Th、Tl、Tm、U、V、Y、Yb、Zn,其中的39项元素给出了标准值及不确定度,包括Ag、Al、As、B、Ba、Ca、Cd、Ce、Co、Cs、Cu、Dy、Er、Fe、Hg、K、Li、Mg、Mn、Mo、N、Na、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Se、Si、Sm、Sr、Tb、Tl、Y、Yb、Zn;15项元素提供参考值,包括Be、Bi、Cr、Eu、Gd、Ge、Ho、Ho、La、Nb、Sc、Th、Tm、U、V。与原有GBW10010大米标准物质相比较,GBW10010a中As、Cd、Co、Cr、Cu、Hg、Mn、Mo、Ni、Zn等重金属元素含量显著下降,其中Cd、Cu、Zn降幅较大,分别下降约39%、43%、38.7%,一定程度上反映了农田生态环境的改善。本批标准物质定值元素总数量增加了6项,新增定值元素Ag、Nb（Nb给出参考值）,并且各项元素不确定度范围整体上有所缩小,如Al、Cd、Cu、Fe、K、Mg、Mo、Na、P、Pb、Se、Zn等对生物易有影响的重要元素,表明了地质分析测试方法技术的进步及定值水平的提高。本批标准物质定值元素涵盖了具有生物效应的大部分主微量元素,适用于农业生态环境地球化学调查与评价、生物样品测试、农产品质量与食品安全评价样品测试时的分析仪器校正、分析方法评价和分析质量监控等多个领域。  相似文献   

The complex one-sided integrals of Cauchy and Hadamard and application to boundary element method     

S. G. Mogilevskaya 《国际地质力学数值与分析法杂志》1998,22(12):947-968

The definitions of complex integrals of Cauchy and Hadamard with the singular point coinciding with the end point of the integration curve are proposed. It is shown that the new integrals satisfy most of the properties of the regular ones, including the change of variables. It is also shown that the Cauchy principal value (CPV) and Hadamard finite-part (HFP) integrals can be considered as a sum of the new type integrals. The application to numerical solution by the boundary element method (BEM) and the complex hypersingular integral equation (CHSIE) for the multiregions of interacting elastic bodies and bodies with cracks and holes is discussed. The different ways to place the collocation points are considered. The numerical results for the problems of circular hole and circular elastic inclusion in infinite plate indicated that the appropriate choice of the approximating functions leads to a high accuracy of the calculation. Applications of the new technique to geomechanics problems are discussed. © 1998 John Wiley & Sons, Ltd.  相似文献   

A continuum model of layered rock masses with non-associative joint plasticity     

D. P. Adhikary  A. V. Dyskin 《国际地质力学数值与分析法杂志》1998,22(4):245-261

Layered rock masses can be modelled either as standard, orthotropic continua if the layer bending can be neglected or as Cosserat continua if the influence of layer bending is essential. This paper presents a finite element smeared joint model based on the Cosserat theory. The layers are assumed to be elastic with equal thickness and equal mechanical properties. All the cosserat parameters are expressed through the elastic properties of layers, layer thickness and joint stiffness. Plastic-slip as well as tensile-opening of layer interface (joint) are accounted for in a manner similar to the conventional non-associative plasticity theory. As an application, the behaviour of an excavation in a layered rock mass is examined. The displacement and stress fields given by smeared joint models based on the Cosserat continuum and the conventional anisotropic continuum approaches are compared with those obtained from the discrete joint model. The conventional anisotropic continuum model is found to break-down completely when the effective shear modulus in the direction parallel to layering is low in comparison to the shear modulus of the intact layer, whereas the Cosserat model is found to be capable of accurately reproducing complex load–deflection patterns irrespective of the differences in shear moduli. © 1998 John Wiley & Sons, Ltd.  相似文献   

四川盆地西南缘龙马溪组泥岩地球化学特征及物源区和构造背景分析   总被引：1，自引：0，他引：1  

张茜  肖渊甫  王晓飞  余谦  王剑  赵安坤  门玉澎  周业鑫 《地质论评》2020,66(5):1393-1410

本文对川西南荥经地区龙马溪组泥岩的岩石学、矿物学及元素地球化学开展了研究,探讨了龙马溪组沉积环境、物源区属性及构造背景。结果表明,研究区龙马溪组泥岩砂质、钙质含量较高,指示其沉积水体较浅。稀土元素特征及及A—CN—K图解说明龙马溪组泥岩组成较少受成岩及交代作用影响,样品较完整地保存了物源和风化作用信息。K2O、Rb、Al2O3 /TiO2含量较高及Eu负异常指示其母岩为偏酸性的长英质岩、花岗岩类,推测主要来自康滇古陆新元古代早期地台盖层。ICV值大于1,CIA平均值为66,Th/U与地壳UCC值相近,Rb/Sr值明显低于PAAS,指示其物源为近源初次旋回的快速沉积产物,受化学风化作用较小,沉积环境为干燥、寒冷环境。La/Yb、LREE/HREE及Sc/Cr等值均与被动大陆边缘值相近,结合Sc/Cr—La/Y等判别图解,说明研究区沉积构造背景主要为被动大陆边缘。  相似文献   

辽宁瓦房店金刚石矿床50号岩管地质特征及找矿预测     

刘礼广  吴大天 《中国地质调查》2020,7(5):33-41

以辽宁瓦房店金刚石矿床50号岩管为例,系统分析了该矿床的地质特征。通过对斑状富金云母金伯利岩、含围岩角砾斑状金伯利岩和金伯利凝灰角砾岩进行岩石地球化学分析发现: 碳酸盐化金伯利凝灰角砾岩超基性成分较少,滑石化、蛇纹石化及碳酸盐化混合金伯利凝灰角砾岩超基性成分较多; 铬、镍、钛在金伯利凝灰角砾岩中的含量较低,在含围岩角砾斑状金云母金伯利岩中的含量略高,在斑状富金云母金伯利岩和斑状金伯利岩中的含量最高。该矿床主要为含围岩角砾斑状金伯利岩和斑状富金云母金伯利岩,其次为金伯利凝灰角砾岩、含围岩角砾斑状金云母金伯利岩和含金伯利物质角砾岩。含铬镁铝榴石、铬铁矿和碳硅石是金刚石的伴生矿物。水平方向上,金伯利岩含矿品位西部较富,东部较贫; 垂直方向上,金伯利岩含矿品位变化较小。通过三维建模,推测50号岩管不是根部相,而是受EW向推覆构造作用影响发生的断层错位,在其东侧600 m深处存在50-1号金伯利岩体。  相似文献   

不透水地基上均质土坝渗流自由面的有限元计算     

牛文杰  叶为民 《岩土力学》2007,28(Z1):375-378

为了保证土坝安全,水利工程中需要对土坝进行渗流计算,首先需要确定自由面。根据达西定律和渗流连续方程,以及水头和流量边界条件,建立了不透水地基上的均质土坝渗流的计算模型。利用Geoslope软件,采用有限元离散的方法计算了土坝的渗流自由面,并分析了土坝在不同的渗透系数情况下的自由面位置的差异。最后,解析解计算的自由面结果验证了有限元计算自由面方法是正确的。  相似文献   

CALCULATING THE DYNAMIC STIFFNESS MATRIX OF 2-D FOUNDATIONS BY DISCRETE WAVE NUMBER INDIRECT BOUNDARY ELEMENT METHODS     

J. X. ZHAO  A. J. CARR  P. J. MOSS 《地震工程与结构动力学》1997,26(1):115-133

Apart from some special cases, calculating the dynamic stiffness matrix of foundations on a layered half-space, especially for embedded foundations, is computationally expensive. An efficient method for two-dimensional foundations in a horizontally layered soil media is presented in this paper. This method is based on indirect boundary element methods and uses discrete wave number solution methods for calculating Green's functions for displacements and analytical methods for the integrations over the boundary. For surface foundations, the present method applies at all frequencies. For embedded foundations or for constructing energy transmitting boundaries, because the free-field part is modelled by boundary elements and the excavated part is modelled by finite elements, the present method applies only at low frequencies for the spring coefficients (the real parts of the dynamic stiffness matrix) but applies at all frequencies for the damping coefficients (the imaginary part of the dynamic stiffness matrix) for undamped sites. The novelty of the method can be used for three-dimensional foundations. © 1997 by John Wiley & Sons, Ltd.  相似文献   

Elastoplastic deformation around underground openings under biaxial initial stress field     

Yuzo Obara  Katsuhiko Sugawara 《国际地质力学数值与分析法杂志》1997,21(10):721-737

Estimation of elastoplastic deformation around an underground opening induced by the excavation of it, especially displacement and strain field in plastic region, is presented in this paper, as well as the formulation for calculating the displacement and strain in the plastic region around the underground opening by the coupled Boundary Element Method - Characteristics Method (BEM-CM). In this method, the non-associated flow rule is adopted to calculate the displacement and strain field in the plastic region, which is determined by the integration of the displacement along characteristics lines under the boundary condition of the elastic displacement on an elastoplastic interface analysed. It is shown that this method is one of the accurate and effective methods for estimating not only the shape and extent of the plastic region but also the state of the displacement and strain in the plastic region around the underground opening, comparing the theoretical solution with numerical results by this method for a circular opening under hydrostatic initial stress condition. Furthermore, this method is applied to rectangular and horse-shoe shaped openings and the characteristics of the strain field in the plastic region are discussed. © 1997 by John Wiley & Sons, Ltd.  相似文献