The use of a finite mixture distribution model in bottled water characterisation and authentication with stable hydrogen,oxygen and carbon isotopes — Case study from Slovenia     

Mihael Brenčič  Polona Vreča 《Journal of Geochemical Exploration》2010

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The chemistry of bottled mineral and spring waters from Norway,Sweden, Finland and Iceland     

Björn S. Frengstad  Kaj Lax  Timo Tarvainen  Øystein Jæger  Börge J. Wigum 《Journal of Geochemical Exploration》2010

Twenty-two bottled mineral and spring waters from Norway, Sweden, Finland and Iceland have been analysed for 71 inorganic chemical parameters with low detection limits as a subset of a large European survey of bottled groundwater chemistry (N = 884). The Nordic bottled groundwaters comprise mainly Ca–Na–HCO₃–Cl water types, but more distinct Ca–HCO₃, Na HCO₃ and Na–Cl water types are also offered. The distributions for most elements fall between groundwater from Fennoscandian Quaternary unconsolidated aquifers and groundwater from Norwegian crystalline bedrock boreholes. Treated tap waters have slightly lower median values for many parameters, but elements associated with plumbing have significantly higher concentrations in tap waters than in bottled waters. The small dataset is able to show that excessive fluoride and uranium contents are potential drinking water problems in Fennoscandia. Nitrate and arsenic displayed low to moderate concentrations, but the number of samples from Finland and Northern Sweden was too low to detect that elevated concentrations of arsenic occur in bedrock boreholes in some regions. The data shows clearly that water sold in plastic bottles is contaminated with antimony. Antimony is toxic and suspected to be carcinogenic, but the levels are well below the EU drinking water limit. The study does not provide any health-based arguments for buying bottled mineral and spring waters for those who are served with drinking water from public waterworks. Drinking water from crystalline bedrock aquifers should be analysed. In case of elevated concentrations of fluoride, uranium or arsenic, most bottled waters, but not all, will be better alternatives when treatment of the well water is not practicable.  相似文献   

扩散法——EA-IRMS测定天然水体铵态氮同位素实验条件研究   总被引：2，自引：0，他引：2  

胡婧  刘卫国 《矿物岩石地球化学通报》2010,29(1):31-37

稳定氮同位素是研究氮循环和氮污染源示踪的一个有效手段。然而目前国内对水体中铵态氮同位素测定方法研究较少,限制了水体氮循环和污染机理的深入探讨。本文采用改进的扩散法(EA-IRMS)测定水中铵态氮同位素,探讨了样品制备过程中扩散溶液的体积、浓度和扩散时间对回收率及氮同位素测定值的影响。实验得出最佳扩散条件为:1.50 mg/L氯化铵溶液400 mL扩散14天,回收率大于95%,且不会产生氮同位素分馏。本研究为高精度测定天然水体中铵态氮同位素提供了更可靠的实验条件。  相似文献   

Egg production rates of two common copepods in the Barents Sea in summer     

《Polar Science》2014,8(3):298-305

Small copepod species play important roles in the pelagic food webs of the Arctic Ocean, linking primary producers to higher trophic levels. The egg production rates (EPs) and weight-specific egg production rates (SEPs) of two common copepods, Acartia longiremis and Temora longicornis, were studied under experimental conditions in Dalnezelenetskaya Bay (southern Barents Sea) during summer. The average EP and SEP at 5–10 °C were 4.7 ± 0.4 eggs female⁻¹ day⁻¹ and 0.025 ± 0.002 day⁻¹, respectively, for A. longiremis and 13.1 ± 0.9 eggs female⁻¹ day⁻¹ and 0.075 ± 0.006 day⁻¹, respectively, for T. longicornis. EP and SEP were significantly higher at 10°C than at 5°C for both species. The mean egg diameter correlated positively and significantly with female prosome length (PL) in each species. SEP of T. longicornis correlated negatively and significantly with PL. Daily EP and SEP were similar to rates recorded for other Acartia and Temora species in temperate and warm regions. The influence of environmental factors (temperature, salinity, and phytoplankton concentration) on EP of both species is discussed. We conclude that temperature is the main factor determining the reproduction rate and timing in A. longiremis and T. longicornis in the Barents Sea.  相似文献   

中国北部黄海近岸水体周丛硅藻的群落群集动态特征的研究     

Liu Yuanyuan  Zhang Wei  Xu Henglong 《海洋学报(英文版)》2014,33(9):160-165

The colonization features of periphytic diatoms were studied in coastal waters of the Yellow Sea, northern China from May to June 2010, using glass slides as an artificial substratum. Samples were collected at a time interval of 1, 3, 7, 10, 14, 21 and 28 d from two depths of 1 and 3 m. The dynamics of diatom colonization process had a similar pattern in community structure and fitted the logistic model in growth curve at both depths. The maximum abundance and the time for reaching 50% maximum abundance （10 d） showed no significant differences （P〉0.05） between two depths 1 and 3 m. Although the diatom communities repre- sented similar taxonomic composition, they differed in the temporal pattern of structural parameters and in succession dynamics of dominant species between the two layers. The species richness showed significantly higher values during the colonization period more than 14 d, while the species diversity and evenness rep- resented a higher variability with significantly different values （P〈0.05） at a depth of 1 m than at a deeper layer. The results suggest that the diatom colonization follows the logistic model growth curve and differs in colonization features between different depths in the coastal waters, and that the sampling strategy at i m is more effective to detect the ecological features for bioassessment in marine ecosystems.  相似文献   

基于PSR 模型的厦门湾中华白海豚资源评价     

肖理  胡文佳  杨圣云  李雯  谢雯瑜  杨璐  陈明茹 《海洋科学》2014,38(1):57-64

中华白海豚(Sousa chinensis Osbeck,1765)为国家Ⅰ级重点野生保护动物,厦门湾作为其在中国的主要分布区之一,自20世纪80年代以来,海岸带开发活动和环境污染程度均不断加大,导致此海域中华白海豚的生存环境不断恶化,种群数量日趋减少,资源状况面临严重威胁。作者采用PSR(压力-状态-响应)模型框架,对厦门湾中华白海豚资源面临的主要环境压力、当前的资源状态以及采取的保护响应措施进行了一个较全面的评价,评价结果认为:围填海工程、船只交通、水下爆破作业和陆源排污等人类活动给厦门湾中华白海豚带来了生境缩小、身体伤害、环境污染和饵料短缺等严重影响,厦门市已采取的保护政策响应包括就地保护、迁地保护和公共管理等方面,目前种群资源数量稳定在80头左右并有潜力扩大。基于评价结果,作者提出了加强保护的建议和策略,可为厦门以外海区的中华白海豚保护工作提供参考。  相似文献   

平潭近岸海域浮子漂移轨迹及其数值模拟     

郭民权  曾银东  李雪丁  任在常  张春桂 《台湾海峡》2014,(4):449-454

平潭近岸海域岸线曲折,周边岛礁众多,海底地形复杂,是福建省海难事故的高发区.本研究建立了平潭近岸海域海上目标物漂移轨迹的预测系统,该系统通过风场和流场的数值模型获取海面动力环境信息,采用拉格朗日算法实现对海上目标物漂移轨迹的预测追踪.其中海流模型采用ROMS（regional ocean modeling system）模型构建,模型水平方向上最高分辨率为100m,垂向上分为16层,并考虑干湿边界,以体现复杂海岸线和水深地形.通过验证分析,潮位、流速和流向的模拟平均绝对误差分别为0.20 m、0.12 m/s和26°.通过平潭近岸2个浮子实验,结果表明,浮子漂移过程中受潮流和局地地形的影响明显,对漂移模型在平潭近岸海域的适用性进行初步验证,浮子模拟轨迹与实际漂移过程基本吻合,模拟时段内最大偏差距离为2.8km,系统可以为平潭近岸海域海上突发事故应急决策提供参考.  相似文献   

九龙江-河口表层水体营养盐含量的时空变化及潜在富营养化评价   总被引：1，自引：0，他引：1  

候丽媛  ;胡安谊  ;于昌平 《台湾海峡》2014,(3):369-378

分别于2012年9月、2013年1、6月,对九龙江两大支流北溪、西溪及河口区开展了3个航次的营养盐监测.研究结果表明,河口区表层水体溶解无机氮（DIN）、总磷（TP）和活性磷酸盐（PO4-P）质量浓度范围分别为0.13-17.35、0.14-1.00和0.00-0.38 mg/dm3,受上游输入和海水稀释作用,营养盐浓度由淡水端至海水端逐渐降低.北溪表层水体的DIN、TP和活性磷酸盐质量浓度范围分别为1.99-24.92、0.12-1.47和0.04-0.68 mg/dm3,受龙岩地区工农业生产及城市进程影响,由上游至下游逐渐降低.西溪表层水体的DIN、TP和活性磷酸盐质量浓度范围分别为2.74-20.61、0.14-0.92和0.02-0.37 mg/dm3,受上游农业生产和下游漳州地区人类活动影响,上下游的DIN质量浓度较高.此外,九龙江沿岸的人类活动可能影响了该地区水体中的溶解无机氮形态组成：北溪和西溪上游的NH4-N和NO3-N占比分别较高.水期分析表明,2013年1月的DIN浓度显著高于其他水期,而不同区域TP和活性磷酸盐的水期波动不尽相同.营养盐结构分析表明,九龙江总体处于磷限制状态,但在河口及北溪部分站位,CDIN/CPO4-P比值已达到适合浮游生物生长繁殖的水平.潜在富营养化程度评价表明,九龙江河口多数站位均处于N或P限制的富营养化级别,但由于N、P营养盐的绝对浓度较高,具有水华暴发的潜在风险.  相似文献   

DISSOLVED AND PARTICULATE ORGANIC CARBON IN YANTAI SISHILI BAY AQUICULTURE WATERS   总被引：2，自引：0，他引：2  

赵卫红王江涛  焦念志赵增霞 《中国海洋湖沼学报》2001,19(2):178-185

Investigation of dissolved organic carbon (DOC) and particulate organic carbon (POC) at 12 stations in Yantal Sishili Bay in May, August, and November of 1997 and March and May of 1998 showed that DOC concentrations varied from 1.14 mg/L to 5.35 mg/L; that the average values at all staticrLs ineach entise varied from 1.52 mg/L to 2.12 mg/L; that POC concentrafions varied from 0.049 mg/L to 1.411mg/L; and averaged 0.159 mg/L to 0.631 mg/L in each cruise. Horizontal distribution of DOC was influ-enced by factors such as continental input, organism activity, temperature, aquieulture environment, etc. The higher POC concentration occurred along the coast. The vertical distribution of DOC and POC changed obviously in spring and summer, but not obviously in autumn and winter. DOC concentration was highest in summer and POC in spring; both were lowest in winter. The seasonal change of DOC was con-sistent with primary productivity seasonal variation, and that of POC was consistent with ehlorophyll-a sea-sanal variation. The seasonal change trend of the C/N ratio of dissolved organic matter was obvious, but the C/N ratio of particulate organic matter had no such trend.  相似文献   

Monitoring of percolation water to discriminate surficial inputs in a karst aquifer     

S. Covelli  F. Cucchi  R. Mosca 《Environmental Geology》1998,36(3-4):296-304

 A long-term study on the chemistry of percolating waters in a very large touristic karst cave (Grotta Gigante, northern Italy) was carried out in order to define recharge zones, flowpaths, and possible anthropogenic contamination from the neighboring area. On the basis of a multivaried analysis of the chemical parameters, a discrimination of the dripping points was attempted. Percolation waters whose recharge zone is in the northernmost sector of the cave appeared permanently affected by the anthropic settlements and agricultural activity on the ground surface. Received: 28 April 1997 · Accepted: 3 February 1998  相似文献