Iron colloids/organic matter associated transport of major and trace elements in small boreal rivers and their estuaries (NW Russia)     

O. S. Pokrovsky  J. Schott 《Chemical Geology》2002,190(1-4):141-179

The chemical status of major and trace elements (TE) in various boreal small rivers and watershed has been investigated along a 1500-km transect of NW Russia. Samples were filtered in the field through a progressively decreasing pore size (5, 0.8 and 0.22 μm; 100, 10, and 1 kD) using a frontal filtration technique. All major and trace elements and organic carbon (OC) were measured in filtrates and ultrafiltrates. Most rivers exhibit high concentration of dissolved iron (0.2–4 mg/l), OC (10–30 mg/l) and significant amounts of trace elements usually considered as immobile in weathering processes (Ti, Zr, Th, Al, Ga, Y, REE, V, Pb). In (ultra)filtrates, Fe and OC are poorly correlated: iron concentration gradually decreases upon filtration from 5 μm to 1 kD whereas the major part of OC is concentrated in the <1–10 kD fraction. This reveals the presence of two pools of colloids composed of organic-rich and Fe-rich particles. According to their behavior during filtration and association with these two types of colloids, three groups of elements can be distinguished: (i) species that are not affected by ultrafiltration and are present in the form of true dissolved inorganic species (Ca, Mg, Li, Na, K, Sr, Ba, Rb, Cs, Si, B, As, Sb, Mo) or weak organic complexes (Ca, Mg, Sr, Ba), (ii) elements present in the fraction smaller than 1–10 kD prone to form inorganic or organic complexes (Mn, Co, Ni, Zn, Cu, Cd, and, for some rivers, Pb, Cr, Y, HREE, U), and (iii) elements strongly associated with colloidal iron in all ultrafiltrates (P, Al, Ga, REE, Pb, V, Cr, W, Ti, Ge, Zr, Th, U). Based on size fractionation results and taking into account the nominal pore size for membranes, an estimation of the effective surface area of Fe colloids was performed. Although the total amount of available surface sites on iron colloids (i.e., 1–10 μM) is enough to accommodate the nanomolar concentrations of dissolved trace elements, very poor correlation between TE and surface sites concentrations was observed in filtrates and ultrafiltrates. This strongly suggests a preferential transport of TE as coprecipitates with iron oxy(hydr)oxides. These colloids can be formed on redox boundaries by precipitation of Fe(III) from inflowing Fe(II)/TE-rich anoxic ground waters when they meet well-oxygenated surface waters. Dissolved organic matter stabilizes these colloids and prevents their aggregation and coagulation. Estuarine behavior of several trace elements was studied for two small iron- and organic-rich rivers. While Si, Sr, Ba, Rb, and Cs show a clear conservative behavior during mixing of freshwaters with the White sea, Al, Pb and REE are scavenged with iron during coagulation of Fe hydroxide colloids.  相似文献   

软基上高速铁路路桥过渡段的技术措施研究   总被引：2，自引：0，他引：2       下载免费PDF全文

杨广庆  彭华  刘建坤 《探矿工程》2002,(5):13-15

通过对高速铁路路基与桥梁过渡段动力特性分析，指出结构物沉降差是导致轨面不平顺的主要因素。分析了沉降差产生的原因，提出了软基上路桥过渡段的结构设计方案，并对其施工方法及质量检测标准进行了探索。  相似文献   

桥梁隔震体系振动台试验研究(III)——测试结果分析     

张俊平  周福霖  廖蜀樵 《地震工程与工程振动》2002,(2)

根据前文所述的测试结果 ,本文主要分析了隔震构造、橡胶支座水平刚度、地震输入频谱特性、地震烈度、输入方向、桥墩高度、桥墩嵌固程度等因素对隔震效果的影响 ,揭示了隔震体系耗散地震能量输入的机理 ,所得出的结论对工程实践具有指导意义。  相似文献   

桥梁隔震体系振动台试验研究(IV)——隔震桥梁的设计方法探讨     

张俊平  周福霖  廖蜀樵  顾玉龙 《地震工程与工程振动》2002,(3)

在前文模型试验的基础上 ,本文总结归纳了隔震桥梁的设计方法与设计流程 ,着重论述探讨了隔震桥梁的概念设计与细部构造设计应注意的问题  相似文献   

A cellular model of Holocene upland river basin and alluvial fan evolution   总被引：1，自引：0，他引：1  

T. J. Coulthard  M. G. Macklin  M. J. Kirkby 《地球表面变化过程与地形》2002,27(3):269-288

The CAESAR (Cellular Automaton Evolutionary Slope And River) model is used to simulate the Holocene development of a small upland catchment (4·2 km²) and the alluvial fan at its base. The model operates at a 3 m grid scale and simulates every flood over the last 9200 years, using a rainfall record reconstructed from peat bog wetness indices and land cover history derived from palynological sources. Model results show that the simulated catchment sediment discharge above the alluvial fan closely follows the climate signal, but with an increase in the amplitude of response after deforestation. The important effects of sediment storage and remobilization are shown, and findings suggest that soil creep rates may be an important control on long term (>1000 years) temperate catchment sediment yield. The simulated alluvial fan shows a complex and episodic behaviour, with frequent avulsions across the fan surface. However, there appears to be no clear link between fan response and climate or land use changes suggesting that Holocene alluvial fan dynamics may be the result of phases of sediment storage and remobilization, or instabilities and thresholds within the fan itself. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

A model of equilibrium bed topography for meander bends with erodible banks     

Stephen E. Darby  Ivana Delbono 《地球表面变化过程与地形》2002,27(10):1057-1085

Channel curvature produces secondary currents and a transverse sloping channel bed, along which the depth increases towards the outer bank. As a result deep pools tend to form adjacent to the outer bank, promoting bank collapse. The interaction of sediment grains with the primary and secondary flow and the transverse sloping bed also causes meanders to move different grain sizes in different proportions and directions, resulting in a consistent sorting pattern. Several models have been developed to describe this process, but they all have the potential to over‐predict pool depth because they cannot account for the influence of erodible banks. In reality, bank collapse might lead to the development of a wider, shallower cross‐section and any resulting flow depth discrepancy can bias associated predictions of flow, sediment transport, and grain‐size sorting. While bed topography, sediment transport and grain sorting in bends will partly be controlled by the sedimentary characteristics of the bank materials, the magnitude of this effect has not previously been explored. This paper reports the development of a model of flow, sediment transport, grain‐size sorting, and bed topography for river bends with erodible banks. The model is tested via intercomparison of predicted and observed bed topography in one low‐energy (5·3 W m^?2 specific stream power) and one high‐energy (43·4 W m^?2) study reach, namely the River South Esk in Scotland and Goodwin Creek in Mississippi, respectively. Model predictions of bed topography are found to be satisfactory, at least close to the apices of bends. Finally, the model is used in sensitivity analyses that provide insight into the influence of bank erodibility on equilibrium meander morphology and associated patterns of grain‐size sorting. The sensitivity of meander response to bank cohesion is found to increase as a function of the available stream power within the two study bends. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

液化场地桩-土-桥梁结构动力相互作用振动台试验研究进展   总被引：20，自引：3，他引：20  

凌贤长  王东升 《地震工程与工程振动》2002,22(4):53-59

本文在全面归纳与总结液化场地桩－土－桥梁结构动力相互作用振动台试验及与之相关领域的国内外研究进展基础上，直接针对我国桥梁工程中的主要震害问题，提出在我国开展液化场地桩－土－桥梁结构动力相互作用振动台试验研究的必要性，并阐述作者对液化场地桩－土－张桥梁结构动力相互作用振动台试验中若干问题的认识。  相似文献   

挡块对斜拉桥抗震性能的影响   总被引：1，自引：0，他引：1  

余建星  王新岐 《地震工程与工程振动》2002,22(4):114-119

本文基于现有永和斜拉桥挡块设施的严重破损，引入非线性挡块元，采用有限元计算分析挡块对斜拉桥抗震性能的影响。结果表明，斜拉桥塔根挡块的调协对减震效果影响不大，但挡块具有减小塔顶残余变形的有利作用。鉴于此，对永和斜拉桥挡块进行修复是必要的。  相似文献   

基于DEM的分布式水文模型构建方法   总被引：52，自引：4，他引：52  

王中根  刘昌明  左其亭  刘青娥 《地理科学进展》2002,21(5):430-439

基于 DEM的分布式水文模型是现代水文学同高科技 (如计算机技术、 3S技术等 )相结合的产物 ,是研究变化环境下水文循环与水资源演化规律的理想工具 ,代表了水文模型的最新发展方向。从 DEM的特性出发 ,本文探讨并总结了分布式水文模型的特点、建模思路和模型基本结构框图。在流域离散化方面 ,重点介绍了分布式水文模型常用的三种单元划分方法 ;最后 ,针对分布式水文模型构建问题 ,从“输入模块”、“单元水文模型”、“河网汇流模型”三方面 ,阐述了分布式水文模型微结构构建方法。  相似文献   

3S一体化技术支持下的西南地区冬小麦估产——以安宁河谷四县为例   总被引：4，自引：2，他引：4  

江晓波  李爱农  周万村 《地理研究》2002,21(5):585-592

农作物遥感估产已经是广泛应用的技术 ,但由于西南地区复杂的地貌类型以及遥感信息源等因素的限制 ,农作物估产方面的研究起步较晚 ,因而研究山区的农作物遥感估产对西南地区有重要的理论价值和现实意义。安宁河谷为一南北走向的山间盆地 ,是四川省第二大粮食生产基地。本文运用遥感 (RemoteSensing)、地理信息系统 (GIS)和全球定位系统(GPS)———简称 3S ,采取全数字式判读方式提取冬小麦的播种面积 ,进行野外点、线采样 ,并利用数理统计方法 ,建立了该地区的冬小麦估产模型  相似文献